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Synthesis and analysis of the properties of ferro-fluids
, Article ICONN 2010 - Proceedings of the 2010 International Conference on Nanoscience and Nanotechnology, 22 February 2010 through 26 February 2010, Sydney, NSW ; 2010 , Pages 91-93 ; 9781424452620 (ISBN) ; Ghane Motlagh, B ; Ghane Golmohamadi, F ; Ghane Motlagh, R ; Rouhani, S ; Sharif University of Technology
2010
Abstract
We report the rheological properties of ferro-fluid (FF) containing iron oxide nano-particles. At first, a FF was synthesized by using chemical co-precipitaton[1]. The microstructure study using SEM revealed that the FF contained nano-particles with the mean particle size of 35nm. The XRD study revealed that we have well crystallized structures of magnetite; they appeared to be approximately single crystalline structures. The rheological results proved that the FF has non Newtonian behavior, it is a shear thinning fluid in all magnetic fields, Moreover, the magnetic field increases the viscosity in a definite shear rate due to the nano-particles agglomerations and formation of chain-like...
Development of a continuous kinetic model for prediction of coke formation in hydroconversion of Marlim crude oil in a slurry-phase reactor
, Article Petroleum and Coal ; Vol. 56, issue. 3 , 2014 , p. 249-256 ; Khorasheh, F ; Sharif University of Technology
2014
Abstract
A Continuous model was developed to describe the kinetics of hydroconversion of Marlim crude oil in a slurry-phase reactor. The model was able to accurately predict the liquid product distributions as well as coke formation. The model contained one temperature-independent and six temperature-dependent parameters.The model parameters were obtained by an optimization procedure using experimental data available in the open literature for reaction temperatures of 440-460°C, hydrogen pressure of 14.7 MPa, liquid hourly space velocity (LHSV) of 0.5 h-1, and a hydrogen to oil ratio of 100 to 1 ft3/bbl. Comparison between experimental and predicted product distributions and coke yields indicated a...
Synthesis of the Graphitic Carbon Nitride/Iron Oxide Nanocomposite
, M.Sc. Thesis Sharif University of Technology ; Sadrnezhad, Khatiboleslam (Supervisor)
Abstract
The g-C3N4/Fe2O3 nanocomposite was produced by the combustion synthesis. The product was characterized by x-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller study (BET), Ultraviolet-visible analysis (UV-vis) and photoluminescence measurement (PL). Effect of iron nitrate on stability and photocurrent density under simulated visible-light irradiation was determined. The highest photocurrent density obtained (4.25 μA/Cm2) was twelve times the pure g-C3N4. This improvement was due to a bandgap decrease, the specific surface area increase, reduction of the electron-hole recombination, and...
Improving Performance and Power Consumption of Optical CMPs Using Inter-core Communication Prediction
, M.Sc. Thesis Sharif University of Technology ; Sarbazi Azad, Hamid (Supervisor)
Abstract
Studying data flows in conventional applications of Multi-Processor System-on-Chips (MPSoCs) denotes that most of these flows are the ones that transfer huge volume of data in inter-core communications. Previous works try to present architecture for interconnection network which some paths with low power and latency are reserved (statically or dynamically). However all of the presented methods are based on subnetworks or mechanism of transferring control messages (to establish a path and tear it down after transmission of data). Optical connections with low cost, low power and high bandwidth are good candidates to reduce power consumption of Network-on-Chips (NoCs). Therefore, using optical...
Fabrication of Monolithic Dye Sensitized Solar Cell Based on Composite Cathode with Platinum Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Taghavinia, Nima (Supervisor)
Abstract
Increasing of human demanding for energy and limiting of fossil fuels and bio-logical problems, it seems necessary to access new and clean source of ener-gy. For instance, one of these sources of energy is sun. If we can impart from this infinite energy source so health and natural life can be pictured for human. Nanostructure dye sensitized solar cells in compare with other photovoltaic cells are more economical and practical as a result of lower material cost and simpler manufacturing process. In general, a typical dye sensitized solar cell is a sandwich structure based on two transparent conducting oxide (FTO) glasses. The FTO glass substrates are expensive and account for most of...
An opto-electrical NoC with traffic flow prediction in chip multiprocessors
, Article Proceedings - 2014 22nd Euromicro International Conference on Parallel, Distributed, and Network-Based Processing, PDP 2014 ; 2014 , Pages 440-443 ; Arjomand, M ; Sarbazi Azad, H ; Sharif University of Technology
2014
Abstract
Network-on-Chip (NoC) paradigm has emerged as a revolutionary methodology to integrate numerous IP blocks on a single chip. The achievable performance of adopting NoCs is constrained by the performance limitation mainly imposed by the metal wires that are the physical realization of communication channels. According to the International Technology Roadmap for Semiconductors (ITRS) report, new interconnect paradigms providing huge bandwidth is in need for future products. The current wired channels have limited bandwidth, and consequently, they limit the performance enhancements that NoC architectures can provide. Optical interconnects are capable of achieving better performance via...
Kinetic Modeling of Slurry Phase Residue Hydroconversion
, M.Sc. Thesis Sharif University of Technology ; Khorashe, Farhad (Supervisor) ; Kazemeini, Mohammad (Supervisor)
Abstract
Existing processes to improve the quality of heavy oil cuts catalytic converter hydroconversion can be mentioned in the slurry phase. This process is usually done in the temperature 440˚C to 470˚C be a heavy craking led to the production of light weight thermal feed can be more. With more products light, adverse reaction can also lead to the formation of coke be. Coke formation of secondary radical reactions can be feed from cracking of heavy compounds. Coke production is to eliminate or limit the ability of homogeneous catalysts (eg sulfide Molybdium) about 600-1000 ppm disposable food adds to be used. The main role of catalyst in the stable radicals fail thermal compound feed is heavy. The...
Combustion synthesis of g-C3N4/Fe2O3 nanocomposite for superior photoelectrochemical catalytic performance
, Article Applied Surface Science ; Volume 534 , 2020 ; Sadrnezhaad, S. K ; Hosseini H., S. M ; Sharif University of Technology
Elsevier B.V
2020
Abstract
The g-C3N4/Fe2O3 nanocomposite was produced by the solution combustion synthesis (SCS) of iron-nitrate/g-C3N4 mixtures of varying concentration ratios and using urea as a fuel. The following methods did characterization of the products: X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller investigation (BET), ultraviolet–visible light analysis (UV–vis) and photoluminescence measurement (PL). Effect of iron nitrate on stability and photocurrent density under simulated visible-light irradiation was determined. The...
One-pot microwave synthesis of hierarchical C-doped CuO dandelions/g-C3N4 nanocomposite with enhanced photostability for photoelectrochemical water splitting
, Article Applied Surface Science ; Volume 530 , 2020 ; Siavash Moakhar, R ; Soleimani, F ; Sadrnezhaad, S. K ; Masudy Panah, S ; Katal, R ; Seza, A ; Ghane, N ; Ramakrishna, S ; Sharif University of Technology
Elsevier B.V
2020
Abstract
Cupric oxide (CuO) is a semiconductor of choice for photocathode in photoelectrochemical (PEC) applications due to its great sunlight absorption capability. However, photocorrosion is the main drawback of CuO. Herein, CuO/graphitic carbon nitride (g-C3N4) with a unique microstructure, enhanced PEC performance, and considerable photostability is synthesized under microwave irradiation. A facile, one-pot method is utilized to directly deposit the nanocomposite onto fluorine-doped tin oxide from a solution containing copper precursor and urea. Possible mechanism of CuO/g-C3N4 formation through this novel method is investigated. It is elucidated that controlled amounts of urea critically...