Loading...
Search for:
gharibi-marzankola--mahsa
0.102 seconds
A Polypropylene-Based Microextraction Method Coupled with HPLC-FD for Determination of Fluoxetine in Human
, M.Sc. Thesis Sharif University of Technology ; Bagheri, Habib (Supervisor)
Abstract
Considering principles of both micro-solid phase extraction (µ-SPE) and stir-bar sorptive extraction (SBSE) techniques, in this study a microextraction technique was developed using a polypropylene sheet as extracting device for isolation of fluoxetine from biological samples. Being rather inexpensive and simple to prepare extracting device, elimination of time consuming sorbent synthesis step and memory effect are some of the advantages of the proposed method. The extraction process was performed using a polypropylene sheet as extracting device. Solvent desorption was performed in a microvial and then extractant was injected into HPLC system. The effect of various parameters including pH,...
On competence of vendor managed inventory in supply chains using basic mathematical inventory models
, Article Scientia Iranica ; Vol. 21, issue. 3 , 2014 , p. 1061-1071 ; Haji, A ; Gharibi, M ; Sharif University of Technology
2014
Abstract
In this study, a two-echelon single-vendor supply chain is selected to do a cost-based comparison between short-term performances of a Vendor Managed Inventory (VMI) and a Retailer Managed Inventory (RMI). While the inventory costs include ordering and storing expenses, the rate of consumption and the price of goods are constant, the rate of production and pace of transportation are infinite and shortage is not allowed. This paper, after a comprehensive literature review, is followed by three cases of single retailer, n-retailer and two-retailer chains. Unlike the second case, in the first case, VMI shows an absolute superiority to RMI, and this is the reason for devising the third case in...
, M.Sc. Thesis Sharif University of Technology ; Parsafar, Gholamabbas (Supervisor)
Abstract
In 2009, a general equation of state (EOS-III) based on an effective near-neighbor pair interaction of an extended Lennard-Jones (3, 6, 12) type has been introduced as : , where is the compressibility factor, p and ρ stand for pressure and molar density , respectively, T is Temperature , and e, f and g are the temperature dependent coefficient of the equation of state . the Z_th and Z_in are the thermal and internal contributions of pressure in the compressibility factor, respectively. this equation of state gives a good description of all types of nano- and bulk –solid and bulk fluid at entire temperature and pressure ranges for which thee is experimental data. Investigation show that...
Investigation of carbon monoxide tolerance of platinum nanoparticles in the presence of optimum ratio of doped polyaniline with para toluene sulfonic acid and their utilization in a real passive direct methanol fuel cell
, Article Electrochimica Acta ; Volume 97 , 2013 , Pages 216-225 ; 00134686 (ISSN) ; Amani, M ; Pahlavanzadeh, H ; Kazemeini, M ; Sharif University of Technology
2013
Abstract
Polyaniline fiber (PANI) was synthesized by chemical interfacial method and doped with para toluene sulfonic acid (PTSA) through a sequential doping-dedoping-redoping process resulting in PANI-PTSA. The doped material was utilized to fabricate Vulcan-polyaniline composite of C-PANI-PTSA. Next, through reduction, Pt particles were deposited on to this composite to produce a Pt/C-PANI-PTSA electrocatalyst. To investigate the PANI-PTSA interaction with the carbon support as well as, to consider its effect upon the catalytic activity of Pt/C-PANI-PTSA, electrocatalysts with different ratios of 10, 15, 20, 25 and 30 wt% were synthesized and their activity was compared with the Pt/C (Electrochem)....
Photoelectrocatalytic Performance of Mesoporous TiO2 Nanostructures Decorated with Cu-Ag-Zn Particles for CO2 Conversion
, M.Sc. Thesis Sharif University of Technology ; Simchi, Abdolreza (Supervisor)
Abstract
The rise in carbon dioxide levels has led to the manifestation of numerous environmental challenges. Currently, the absorption and conversion of carbon dioxide into valuable fuel resources such as synthetic gas, methane, and ethylene are deemed crucial from both environmental and economic standpoints. Despite the presentation of photocatalysts such as titanium oxide and electrocatalysts such as copper, silver, and zinc, their efficiency in CO2 conversion is found to be insufficient. One potential solution to this problem is the utilization of photoelectrocatalytic CO2 recovery. In this study, the aim was to enhance the photoelectrocatalytic reduction of CO2 by designing and manufacturing...
Fabrication of MEA based on sulfonic acid functionalized carbon supported platinum nanoparticles for oxygen reduction reaction in PEMFCs
, Article RSC Advances ; 2015 , Pages 85775-85784 ; 20462069 (ISSN) ; Yasi, F ; Kazemeini, M ; Heydari, A ; Golmohammadi, F ; Sharif University of Technology
Royal Society of Chemistry
2015
Abstract
The Nafion ionomer affects the efficiency of the platinum (Pt) catalyst by blocking the active sites thereby restricting the gas permeability of the catalyst layer; but, there is a limitation in the quantity of Nafion ionomer that needs to be added without affecting the cell performance. Sulfonation of carbon-supported catalysts as mixed electronic and protonic conductors has been reported to be an efficient way to increase the triple-phase boundaries. In order to improve the utilization and activity of cathodic catalysts in the oxygen reduction reaction (ORR), Pt nanoparticles were loaded on a mixture of Vulcan XC-72R and MWCNTs, which were functionalized in a mixture of 96% sulfuric acid...
Evaluation of Base Calling Methods in Next Generation Sequencing
, M.Sc. Thesis Sharif University of Technology ; Hossein Khalaj, Babak (Supervisor) ; Motahhari, Abolfazl (Supervisor)
Abstract
In the mid twentieth century by discovering the existence of genetic strands and understanding their role in diseases and phenotypes of species, research initiated to decipher their content. Sequencing of the first human genome at early twenty-first century paved the way to study and even cure complex human deseases having genetic origin. Next Generation Sequencing (NGS) Technologies have significantly reduced the expenses and the timing complexity of DNA Sequencing and this has an improving trend. In this thesis, we evaluate Base Calling methods, a critical step in analyzing next generation sequencing information and deals with massive sequencing data. Base Calling tries to optimally detect...
Influences of Magnetic Nanoparticles and Magnetic Field on the Performance of the Redox Flow Batteries
, M.Sc. Thesis Sharif University of Technology ; Molaei Dehkordi, Asghar (Supervisor) ; Gharibi, Hossein (Supervisor)
Abstract
The novel concept of using magnetic nanofluidic electrolyte for redox flow batteries (RFBs) is demonstrated for the first time. In this regard, the stable magnetic nanofluidic electrolytes are prepared by dispersing magnetic modified multiwalled carbon nanotubes (MMWCNTs) in the positive electrolyte of a polysulfide-iodide redox flow battery at mass concentrations of less than 0.3 g L−1. The electrochemical behavior of magnetic nanofluidic electrolyte was examined using cyclic voltammetry at different mass concentrations of MMWCNTs with a carbon felt electrode. Higher and stable peak current densities were observed at larger mass concentrations of MMWCNTs. A polysulfide-iodide redox flow...
Novel magnetic flowable electrode for redox flow batteries: A polysulfide/iodide case study
, Article Industrial and Engineering Chemistry Research ; Volume 60, Issue 2 , 2021 , Pages 824-841 ; 08885885 (ISSN) ; Molaei Dehkordi, A ; Gharibi, H ; Roberts, E. P. L ; Sharif University of Technology
American Chemical Society
2021
Abstract
A novel approach named a magnetic flowable electrode (MFE) is proposed for the first time to enable enhancement of redox flow batteries (RFBs) performance. This approach enables the formation of a high active surface area electrode from magnetic nanomaterials, without the need to fabricate a self-supporting three-dimensional electrode structure. To form a simple MFE, magnetic modified carbon nanotubes are dispersed in the electrolyte, and permanent magnets are embedded behind the current feeder to apply a magnetic field across the flow cell channels. With circulating electrolyte, magnetic carbon nanotubes are aggregated on the graphite bipolar plate to form a well-structured nanoscale...
Synthesis and Application of Preformed Viscoelastic Hydrogels in Enhanced Oil Recovery
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor)
Abstract
Preformed particle gels (PPGs) due to its advatantage over commonly used in situ gels has been successfully applied for controlling excess water production in mature oil reservoirs. Field results of using PPGs in oil fields shows that commonly used PPGs are highly sensitive to hard reservoir conditions such as high temperature and salinity and can not effectively block fractures and high permeability layers.Objects of this study are synthesis and evaluating performance of this novel polymer based hydrogel in oil reservoirs with high temperature and salinity. Central composite design ( which is a experiment design approach) was used for synthesizing thirteen gel samples and optimal sample was...
Coating of Sewage Pipes with Appropriate Nanomaterials Aimed at Preventing Biological Growth (Algae+Biofilm)
, M.Sc. Thesis Sharif University of Technology ; Borghei, Mehdi (Supervisor) ; Ghasemi, Shahnaz (Co-Supervisor)
Abstract
Biological layers are one of the main problems related to water transfer with pipe lines which are formed through time in the inner surface of the pipes by the water nutrients. Hence, the inner surfaces in the pipe lines and water refineries should be made in order not to let these biological layers to be made. The reason is that when the biofilm is formed on these surfaces, the traversing water is polluted. Dredging of these pipes is not only necessary in most of the countries in the world and needs huge amounts of water but is also very complex and expensive.In this research, nanomaterials, namely ZnO, T〖iO〗_2،S〖iO〗_2 have been used to cover the surface of concrete and steel pipes (The...
Design and Manufacture of Polymeric Nanocomposite in Order to Control the Production and Migration of Sand in Reservoirs
, Ph.D. Dissertation Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor)
Abstract
Sand production from oil reservoirs leads to various problems, such as well productivity reduction, operating equipment corrosion, and increased production costs. Therefore, controlling sand production in unconsolidated reservoirs is crucial for operating companies. Chemical injection into the formation in order to strengthen and reduce sand production is one of the most important methods of sand control. In this study, a hydrogel nanocomposite was designed and its effectiveness in sand control was investigated. Various tests were carried out to define and assess its efficacy, as follows: Morphological tests demonstrated the creation of a dense, homogeneous, and porous structure. Structural...
Performance Evaluation of Rhamnolipid & Sophorolipid Biosurfactants Capable of Wettability Change and Oil Recovery Increase
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor) ; Mokhtarani, Babak (Co-Supervisor)
Abstract
As fossil fuels are still the world's most important source of energy, as well as the maturity of most of the world's oil reservoirs, there is a need for enhanced oil recovery methods to meet the world's increasing oil demands. MEOR methods are new and promising methods that are still in the research and development stage. One of the MEOR methods is the use of biosurfactants, which increase the oil recovery by two mechanisms: 1) reducing the interfacial tension between water and oil and 2) changing the wettability of the rock. In this study, the performance of two glycolipid biosurfactants, rhamnolipid and sophorolipid, in increasing oil recovery has been investigated. Initially, surface...
Investigation of the Effect of Asphaltene on the Stability of Water-oil Emulsion
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor) ; Masihi, Mohsen (Supervisor)
Abstract
During the production of crude oil from reservoirs, the production of quantities of formation water along with this oil, causes the crude oil does not have the necessary indicators for transportation, refining and ultimately export. The presence of water and salt along with crude oil causes corrosion of refinery and transmission equipment and makes oil unfavorable in terms of economic efficiency (both for domestic use and for export). water and salt produce stable emulsion with oil that can be stable for a long time and can not be easily separated from crude oil. Therefore, separation of water and salt from crude oil is one of the most important issues in the oil industry. Breaking this...
Butanol Production from Bagasse Sugarcane Black Liquor by Native Strain and Clostridium Acetobutylicum Species
,
M.Sc. Thesis
Sharif University of Technology
;
Shayegan, Jalaleddin
(Supervisor)
;
Vossoughi, Manouchehr
(Supervisor)
;
Sedighi, Mahsa
(Co-Supervisor)
Abstract
Considering the limitations of fossil fuels in recent years, as well as increasing demand for biofuels, it is anticipated that future attention to biofuels will increase further. Among biofuels, due to some disadvantages of bioethanol and biodiesel fuel, there is a tendency to use biobutanol, which does not have the disadvantages of the mentioned fuels. The cost of chemical production of butanol also led researchers to use biotechnology production of butanol. According to studies, butanol production can be achieved by fermenting some sugars such as glucose, xylose, and ... by anaerobic microorganism, but the cost of using these sugars has resulted in the use of natural sources of these...
Providing A New Solution to Enhance Oil Recovery (Eor) by Using Properties of Imidazolium Ionic Liquids and Synthesis of Microgels
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor) ; Mokhtarani, Babak (Co-Supervisor)
Abstract
The methods of Enhanced Oil Recovery (EOR) from reservoirs have been taken into consideration recently due to the decline in oil reserves and the rise in energy demand. Studies and investigations indicate the tremendous potential of chemical approaches based on injecting ionic liquids into the porous media with the goal of improving oil recovery. Additionally, hydrogels and polymers, which are two of the process' primary materials, are thought to be good alternatives. In the current study, a hydrogel based on carboxymethyl cellulose was first created and synthesized. Ionic liquids based on imidazolium and triflate anion were then added, and their effectiveness in enhancing the properties...
Evaluation of the Surface Activity of Novel Ionic Liquids and Their Application in the Enhanced Oil Recovery Process
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Mokhtarani, Babak (Supervisor) ; Baghban Salehi, Mahsa (Co-Supervisor)
Abstract
The following dissertation discusses Ionic Liquids (ILs) as an alternative to commercial surfactants for use in the Enhanced Oil Recovery process. Ionic Liquids came to researchers’ attention due to their environmental nature and their tolerance for high temperatures and salinity. In this work, firstly, an extensive literature review is carried out, and then, experiments are designed and performed to evaluate ILs’ surface activity and performance in a lab-scale EOR set-up. The Ionic Liquids used in this work consist of three types of methylimidazolium nitrate, [MIM]+[NO3]-, with three different alkyl chain lengths. This combination, and specifically the effect of nitrate anions on EOR and...
The potential therapeutic effects of Galbanic acid on cancer
, Article Pathology Research and Practice ; Volume 248 , 2023 ; 03440338 (ISSN) ; Vahedian, V ; Golshanrad, P ; Nahavandi, R ; Behshood, P ; Soltani, N ; Gharibi, M ; Rashidi, M ; Maroufi, N. F ; Sharif University of Technology
Elsevier GmbH
2023
Abstract
Galbanic acid (GBA), as a natural compound has potential anticancer properties. It has been documented that GBA shows promising therapeutic potential against various types of cancer, including breast, lung, colon, liver, and prostate cancer. Several mechanisms involve im anti-tumor effects of GBA include apoptosis induction, cell cycle arrest, inhibition of angiogenesis, suppression of metastasis, and modulation of immune responses. Furthermore, the synergistic effects of GBA along with chemotherapeutic agents led to has enhancing efficiency with reduction in toxicity. Moreover, GBA through antioxidant and anti-inflammatory properties possess indirect anti-tumor effects. In this review, we...