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ghasemi--simin
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Study of the Optical Properties and Structural Fluxionallity of a New Cu(I) Complex Containing Bis(diphenylphosphino)methane and Phthalazine
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
In the current study, the dinuclear copper(I) complex ,[Cu2(μ-phthalazine)(phthalazine)2(μ-dppm)2](PF6)2,(1), has been prepared by the reaction of two equiv of [Cu(CH3CN)4]PF6, three aquiv of phthalazine, and two equiv of bis(diphenylphosphino)methane (dppm). However a mixture of two four coordinated copper(I) complex,1, and a three and four-coordinated copper(I) complex ,[Cu2(μ-phthalazine)(phthalazine)(μ-dppm)2](PF6)2,(2), have been prepared when the reaction has been carried out with equal ratio of the reactants. The structure of 1 and 2 determined using. X-ray crystallography in solid state and the structure of 1, further characterized by multinuclear NMR spectroscopy in solution....
Analysis of generalized optical orthogonal codes in optical wireless local area networks
, Article IEEE Journal on Selected Areas in Communications ; Volume 27, Issue 9, Article number 5342317 , December , 2009 , Pages 1572-1581 ; Pakravan, M. R. (Mohammad Reza) ; Sharif University of Technology
2009
Abstract
In this paper we propose and analyze the application of generalized optical orthogonal codes (GOOC) in the optical wireless local area networks (OWLAN). A system deploying GOOC can support more users and achieve better BER performance. We evaluate the system performance of GOOC noting practical constraints of OWLAN applications. We consider average and peak power limitations of free space infrared sources, arising from eye safety and device non-linearity restriction. We include the impact of various noises including background-light induced noise in system evaluation. Proper system design requires appropriate selection of GOOC code parameters. We analyze the influence of code parameters on...
Analysis of power control for indoor optical wireless CDMA networks using OOK and BPPM
, Article IET Communications ; Volume 4, Issue 16 , November , 2010 , Pages 1919-1933 ; Pakravan, M. R. (Mohammad Reza) ; Gohari, A ; Sharif University of Technology
2010
Abstract
Wireless infrared optical code-division multiple access (W-OCDMA) is a new developing technique with many useful applications. Noting the limitation on power consumption and eye-safety requirements, wireless optical systems are power limited. Therefore control and efficient use of optical power is a key issue in analysis and design of these systems. Also, multi-user interference is the major source of impairment in these systems and power control is required to control and reduce this interference. Power control and the inevitable errors in its algorithms play an important role in design and implementation of these systems. In this article the authors study the uplink performance of W-OCDMA...
Performance analysis of slotted ALOHA random access Packet-Switching optical CDMA networks using generalized optical orthogonal codes and M-ary overlapping PPM signaling
, Article Journal of Optical Communications and Networking ; Volume 3, Issue 7, Article number 5910463 , July , 2011 , Pages 568-576 ; Khazrae, S. (Simin) ; Pakravan, M. R. (Mohammad Reza) ; Sharif University of Technology
2011
Abstract
In this paper we study slotted ALOHA random access optical code division multiple access packet-switching networks with a chip-level receiver structure. We use generalized optical orthogonal codes (GOOCs) and the overlapping pulse position modulation (OPPM) signaling technique to improve system performance. The impact of physical layer parameters such as the GOOC cross-correlation value and the OPPM overlapping index on key performance benchmarks such as network throughput and delay are analyzed. We also study the stability of the network based on the number of backlogged users, using the expected state drift. It has been shown that using GOOC instead of strict optical orthogonal codes...
Parallelized numerical modeling of the interaction of a solid object with immiscible incompressible two-phase fluid flow
, Article Engineering Computations (Swansea, Wales) ; Volume 34, Issue 3 , 2017 , Pages 709-724 ; 02644401 (ISSN) ; Nikbakhti, R ; Ghasemi, A ; Hedayati, F ; Malvandi, A ; Sharif University of Technology
2017
Abstract
Purpose - A numerical method is developed to capture the interaction of solid object with two-phase flow with high density ratios. The current computational tool would be the first step of accurate modeling of wave energy converters in which the immense energy of the ocean can be extracted at low cost. Design/methodology/approach - The full two-dimensional Navier-Stokes equations are discretized on a regular structured grid, and the two-step projection method along with multi-processing (OpenMP) is used to efficiently solve the flow equations. The level set and the immersed boundary methods are used to capture the free surface of a fluid and a solid object, respectively. The full...
Oscillating pipe flow: High-resolution simulation of nonlinear mechanisms
, Article 2006 ASME Joint U.S.- European Fluids Engineering Division Summer Meeting, FEDSM2006, Miami, FL, 17 July 2006 through 20 July 2006 ; Volume 1 SYMPOSIA , 2006 , Pages 1-10 ; 0791847500 (ISBN); 9780791847503 (ISBN) ; Sharif University of Technology
American Society of Mechanical Engineers
2006
Abstract
A new perspective suitable for understanding the details of nonlinear pumping (formation of traveling shocks) inside a pressurized cavity is constructed in this paper. Full compressible axisymmetric three-dimensional Navier-Stokes equations are used as the starting point to cover all complexities of the problem that exceedingly increase for particular ranges of Mach, Reynolds and Prandtl numbers. Then a very high-order numerical method is introduced to preserve the user-defined order of accuracy for practical simulations. For removal of spurious waves, higher-order compact filters are derived. All equations are marched in time using the classical Runge-Kutta algorithm which is appropriate...
An optimized large-stencil approach for capturing near-PI frequencies
, Article 12th AIAA/CEAS Aeroacoustics Conference, Cambridge, MA, 8 May 2006 through 10 May 2006 ; Volume 5 , 2006 , Pages 3010-3022 ; 1563478099 (ISBN); 9781563478093 (ISBN) ; Sharif University of Technology
American Institute of Aeronautics and Astronautics Inc
2006
Abstract
Large-stencil schemes which their spectral properties are acceptable in the vicinity of ω = π are analyzed for the first time. A machine independent model for evaluating the efficiency of generalized time-marching finite-difference algorithms over periodic domains is developed. This model which is based on operation count reveals that for small values of Total Computational Cost(TCC), the previous low-order small-stencil schemes are more efficient while for moderate TCC, the efficiency of optimized large-stencil schemes abruptly increases. This important result is the motivation for developing optimized large-stencil schemes. The current schemes are successfully implemented in a full...
Numerical solution of high-frequency oscillations of a gas column using a modified lax-wendroff scheme
, Article International Conference on Noise and Vibration Engineering 2006, ISMA 2006, Heverlee, 18 September 2006 through 20 September 2006 ; Volume 4 , 2006 , Pages 2191-2199 ; Sharif University of Technology
Katholieke Universiteit Leuven
2006
Abstract
Recently, several high-order accurate methods have been developed for solving nonlinear equations governing in the high-frequency oscillations of a fluid column. If we assume that the value of Reynolds and Prandtl numbers are high enough then it is possible to neglect the effect of Stokes Layer and it has been previously shown that the calculated pressure profile obtained by solving three-dimensional axisymmetric compressible NS (Navier-Stokes) equations is in good agreement with one-dimensional adiabatic model of Ilinskii. For this particular flow which is the typical of engineering flows inside acoustical compressors, it is clear that high-resolution simulation of NS equations in higher...
Oscillating pipe flow: high-resolution simulation of nonlinear mechanisms
, Article 2006 2nd ASME Joint U.S.-European Fluids Engineering Summer Meeting, FEDSM 2006, Miami, FL, 17 July 2006 through 20 July 2006 ; Volume 2006 , 2006 ; 0791837831 (ISBN); 9780791837832 (ISBN) ; Sharif University of Technology
2006
Abstract
A new perspective suitable for understanding the details of nonlinear pumping (formation of traveling shocks) inside a pressurized cavity is constructed in this paper. Full compressible axisymmetric three-dimensional Navier-Stokes equations are used as the starting point to cover all complexities of the problem that exceedingly increase for particular ranges of Mach, Reynolds and Prandtl numbers. Then a very high-order numerical method is introduced to preserve the user-defined order of accuracy for practical simulations. For removal of spurious waves, higher-order compact filters are derived. All equations are marched in time using the classical Runge-Kutta algorithm which is appropriate...
Facile synthesis and simulation of MnO2 nanoflakes on vertically aligned carbon nanotubes, as a high-performance electrode for Li-ion battery and supercapacitor
, Article Electrochimica Acta ; Volume 390 , 2021 ; 00134686 (ISSN) ; Abnavi, A ; Ghasemi, F ; Ghasemi, S ; Sanaee, Z ; Mohajerzadeh, S ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
This study reports the successful fabrication of high-performance flexible binder-free lithium-ion battery anode and supercapacitor based on the synthesis of 3D hierarchical MnO2 nanoflakes (NFs) on vertically aligned carbon nanotubes (VACNTs) grown upon stainless steel (SS). The experimental results revealed that the prepared electrodes were well served as supercapacitors with a tremendous specific capacitance of MnO2 NFs VACNT/SS 1131 F/g at 0.25 A/g in 0.5 mol.L−1 Na2SO4, 518.8% more than VACNT/SS (218 F/g). Compared to other MnO2 NFs/CNT composites, as-fabricated binder-free MnO2 NFs/VACNTs electrode achieves outstanding performance with high initial discharge and charge capacities of...
Facile synthesis and simulation of MnO2 nanoflakes on vertically aligned carbon nanotubes, as a high-performance electrode for Li-ion battery and supercapacitor
, Article Electrochimica Acta ; Volume 390 , 2021 ; 00134686 (ISSN) ; Abnavi, A ; Ghasemi, F ; Ghasemi, S ; Sanaee, Z ; Mohajerzadeh, S ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
This study reports the successful fabrication of high-performance flexible binder-free lithium-ion battery anode and supercapacitor based on the synthesis of 3D hierarchical MnO2 nanoflakes (NFs) on vertically aligned carbon nanotubes (VACNTs) grown upon stainless steel (SS). The experimental results revealed that the prepared electrodes were well served as supercapacitors with a tremendous specific capacitance of MnO2 NFs VACNT/SS 1131 F/g at 0.25 A/g in 0.5 mol.L−1 Na2SO4, 518.8% more than VACNT/SS (218 F/g). Compared to other MnO2 NFs/CNT composites, as-fabricated binder-free MnO2 NFs/VACNTs electrode achieves outstanding performance with high initial discharge and charge capacities of...
Equipment failure rate in electric power distribution networks: An overview of concepts, estimation, and modeling methods
, Article Engineering Failure Analysis ; Volume 145 , 2023 ; 13506307 (ISSN) ; Shahrabi Farahani, E ; Fotuhi Firuzabad, M ; Dehghanian, P ; Ghasemi, A ; Wang, F ; Sharif University of Technology
Elsevier Ltd
2023
Abstract
The evolution of the organizational attitudes regarding strategic management of system physical assets and the emergence of new technologies call for special attention to maintenance and reliability. State-of-the-art literature suggested a number of techniques and strategies for estimating the equipment failure rates; however, paralyzed by lack of real-world data, existing literature mostly relied on simplifications that may bring about unique challenges and result in low-accuracy estimations. This paper reviews the existing literature in estimating and modeling the failure rate of power system equipment. The review includes the existing models and the ongoing research on degradation,...
Optimum waist of localized basis functions in truncated series employed in some optical applications
, Article Applied Optics ; Volume 49, Issue 8 , 2010 , Pages 1210-1218 ; 1559128X (ISSN) ; Mehrany, K ; Sharif University of Technology
2010
Abstract
The waist parameter is a particularly important factor for functional expansion in terms of localized orthogonal basis functions. We present a systematic approach to evaluate an asymptotic trend for the optimum waist parameter in truncated orthogonal localized bases satisfying several general conditions. This asymptotic behavior is fully introduced and verified for Hermite - Gauss and Laguerre-Gauss bases. As a special case of importance, a good estimate for the optimum waist in projection of discontinuous profiles on localized basis functions is proposed. The importance and application of the proposed estimation is demonstrated via several optical applications
Microstructural evolution mechanism during brazing of Hastelloy X superalloy using Ni–Si–B filler metal
, Article Science and Technology of Welding and Joining ; 2017 , Pages 1-7 ; 13621718 (ISSN) ; Pouranvari, M ; Sharif University of Technology
2017
Abstract
The paper aims at understanding solidification phenomena and solid state precipitations during diffusion brazing of Hastelloy X nickel base superalloy using a ternary Ni–4.5Si–3.2 B (in wt-%) filler metal. The joint is featured by the formation of Ni-rich solid solution in an isothermal solidification zone, borides/silicide formation during eutectic-type solidification in an athermal solidification zone, on-cooling precipitation of fine nickel silicides in the joint centerline, in situ precipitation of Mo–Cr-rich borides in the diffusion affected zone and grain growth in the heat affected zone. The implication of the phase transformations on the joint properties is discussed. It is shown...
A quantum mechanical approach towards the calculation of transition probabilities between DNA codons
, Article BioSystems ; Volume 184 , 2019 ; 03032647 (ISSN) ; Shafiee, A ; Sharif University of Technology
Elsevier Ireland Ltd
2019
Abstract
The role of quantum tunneling in altering the structure of nucleotides to each other and causing a mutational event in DNA has been a topic of debate for years. Here, we introduce a new quantum mechanical approach for analyzing a typical point-mutation in DNA strands. Assuming each codon as a base state, a superposition of codon states could provide a physical description for a set of codons encoding the same amino acid and there are transition amplitudes between them. We choose the amino acids Phe and Ile as our understudy bio-systems which are encoded by two and three codons, respectively. We treat them as large quantum systems and use double- and triple-well potential models to study the...
A new approach to study the Zeno effect for a macroscopic quantum system under frequent interactions with a harmonic environment
, Article Scientific Reports ; Volume 9, Issue 1 , 2019 ; 20452322 (ISSN) ; Shafiee, A ; Sharif University of Technology
Nature Publishing Group
2019
Abstract
Quantum Zeno and anti-Zeno behaviors of a two-level macroscopic quantum system in interaction with a harmonic environment are studied using the perturbation theory. The system-environment interactions are applied in a successive and step-by-step way. A new expression for the probability of surviving the macrosystem in its initial state, after the Nth interaction step, is derived through a different method of calculation. It is shown that multiple transitions between Zeno and anti-Zeno behaviors can be found in our approach. We have shown that in addition to the environmental parameters like the Ohmicity, the macroscopic trait of the system also has a notable effect on the decay rate Γ(τ)....
Thermal processing strategies enabling boride dissolution and gamma prime precipitation in dissimilar nickel-based superalloys transient liquid phase bond
, Article Materials and Design ; Volume 182 , 2019 ; 02641275 (ISSN) ; Pouranvari, M ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
The microstructure of dissimilar transient liquid phase bond between Hastelloy X and IN792 nickel-based superalloys is featured by lack of sufficient formation of γ′ precipitates in the bond-centerline and extensive in-situ precipitation of boride second phases in the diffusion affected zones (DAZ). This paper investigates the impact of two thermal processing strategies, using standard solution treatment and aging of IN792 (STA strategy) and using solution treatment of IN792 followed by a post-bond heat treatment utilizing solution treatment of Hastelloy X and aging treatment of IN792 (SPTA strategy) on the joint microstructure and mechanical properties. The boride precipitates in the DAZ of...
Fast isothermal solidification during transient liquid phase bonding of a nickel alloy using pure copper filler metal: solubility vs diffusivity
, Article Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science ; Volume 50, Issue 5 , 2019 , Pages 2235-2245 ; 10735623 (ISSN) ; Pouranvari, M ; Sharif University of Technology
Springer Boston
2019
Abstract
This investigation aims at understanding the underlying fundamentals of the isothermal solidification phenomenon during the transient liquid phase (TLP) bonding process. The isothermal solidification is governed by solid-state diffusion of the melting point depressant (MPD) into the base material, which, in turn, is controlled by both kinetic and thermodynamic parameters; however, the latter factor is generally ignored. In this work, the competition between kinetics and thermodynamics of diffusion were considered in TLP bonding of a nickel alloy, Monel 400, using two distinct filler metals including pure copper (Cu) and Ni-Si-B filler metal. The joint generated by Ni-Si-B filler metal...
Intermetallic phase formation during brazing of a nickel alloy using a Ni–Cr–Si–Fe–B quinary filler alloy
, Article Science and Technology of Welding and Joining ; Volume 24, Issue 4 , 2019 , Pages 342-351 ; 13621718 (ISSN) ; Pouranvari, M ; Sharif University of Technology
Taylor and Francis Ltd
2019
Abstract
Fundamental understanding of the intermetallic phase formation is the key for enhancing the robustness and reliability of the brazed joints. The paper addresses the phase transformations during brazing of the Hastelloy X nickel-base superalloy using the quinary Ni–13Cr–4.5Si–4.2Fe–2.8B (wt-%) braze alloy. The mechanisms of intermetallic formation via solidification and solid-state precipitation are discussed. The athermal solidification zone (ASZ) is featured by the formation of brittle and hard borides and boro-silicides that are formed via eutectic reactions. However, in contrast to other commercial B-bearing Ni-based filler alloys, it was identified that the presence of a high-volume...
An investigation into the energy transfer efficiency of a two-pigment photosynthetic system using a macroscopic quantum model
, Article BioSystems ; Volume 197 , 2020 ; Shafiee, A ; Sharif University of Technology
Elsevier Ireland Ltd
2020
Abstract
Despite several different measures of efficiency that are applicable to the photosynthetic systems, a precise degree of efficiency of these systems is not completely determined. Introducing an efficient model for the dynamics of light-harvesting complexes in biological environments is a major purpose in investigating such systems. Here, we investigate the effect of macroscopic quantum behavior of a system of two pigments on the transport phenomena in this system model which interacts with an oscillating environment. We use the second-order perturbation theory to calculate the time-dependent population of excitonic states of a two-dimensional Hamiltonian using a non-master equation approach....