Sharif Digital Repository

Palladium nanoparticles immobilized on a cross-linked imidazolium-containing polymer were evaluated as a catalyst for Suzuki carbon-carbon cross-coupling reactions using water as the solvent. The nanocatalysts show good catalytic activities for aryl iodides and aryl bromides and moderate activity with aryl chloride substrates. Coupling of sterically hindered substrates could also be achieved in reasonable yields. The heterogeneous catalyst is stable, can be stored without precautions to exclude air or moisture, and can be easily recycled and reused  

A series of cross-linked ionic polymers based on styrene-functionalized imidazolium salts with chloride, hexafluorophosphate, or tetrafluoroborate counter anions have been prepared and characterized using a range of analytical and spectroscopic techniques and electron microscopy. The polymer with the chloride anion is an efficient catalyst for the cycloaddition of carbon dioxide with epoxides to afford cyclic carbonates. The cross-linked polymer is insoluble in organic solvents and is highly stable and therefore can be easily recycled and reused  

In this paper vehicle path-following in the presence of rollover risk is investigated. Vehicles with high centre of mass are prone to roll instability. Untripped rollover risk is increased in high centre of gravity vehicles and high-friction road condition. Researches introduce strategies to handle the short-duration rollover condition. In these researches, however, trajectory tracking is affected and not thoroughly investigated. This paper puts stress on tracking error from rollover prevention. A lower level model predictive front steering controller is adopted to deal with rollover and tracking error as a priority sequence. A brake control is included in lower level controller which... 

High center of mass vehicles are likely to rollover in extreme maneuvers. Available works present control strategies to prevent rollover. In these works, however, other important parameters such as path trajectory tracking are not a main concern. In this paper conflicts between rollover prevention and trajectory tracking is investigated. Model predictive control (MPC) is adopted to predict and avoid rollover while tracking desired trajectory. For this regard a model based future error estimation is introduced. The control framework predicts both rollover and trajectory error simultaneously. It avoids rollover while tries to track the trajectory. Simulation results for two controllers with... 

The wear-out of flash-based Solid-State Drives (SSDs) is a main concern that significantly affects their reliability. One major parameter that accelerates SSD wear-out is the number of write-cycles committed to flash chips. The number of write-cycles in SSD-based disk subsystem is highly dependent on the erasure code implemented in Redundant Array of Independent Disks (RAIDs). In this paper, we investigate the impact of erasure codes and the configuration of storage subsystems (i.e., the number of disks participated in the RAID array and stripe unit size) on the endurance of storage systems. The number of write-cycles is considered as a metric to evaluate the endurance of storage system. We... 

Job scheduling in MapReduce plays a vital role in Hadoop performance. In recent years, many researchers have presented job scheduler algorithms to improve Hadoop performance. Designing a job scheduler that minimizes job execution time with maximum resource utilization is not a straightforward task. The primary purpose of this paper is to investigate agents affecting job scheduler efficiency and present a novel classification for job schedulers based on these factors. We provide a comprehensive overview of existing job schedulers in each group, evaluating their approaches, their effects on Hadoop performance, and comparing their advantages and disadvantages. Finally, we provide... 

Following Gorokhovsky and Lott and using an extension of the b-pseudodifferential calculus of Melrose, we give a formula for the Chern character of the Dirac index class of a longitudinal Dirac type operators on a foliated manifold with boundary. For this purpose we use the Bismut local index formula in the context of noncommutative geometry. This paper uses heavily the methods and technical results developed by E. Leichtnam and P. Piazza  

In this short note we apply methods introduced by B. Hanke and T. Schick to prove the vanishing of (low degree) higher Â-genera for spin manifolds admitting a positive scalar curvature metric. Our aim is to provide a short proof for this beautiful result  

Objective(s): Multiple sclerosis (MS) is considered as a chronic type of an inflammatory disease characterized by loss of myelin of CNS. Recent evidence indicates that Interleukin 17 (IL-17)-producing T helper cells (Th17 cells) population are increased and regulatory T cells (Treg cells) are decreased in MS. Despite extensive research in understanding the mechanism of Th17 and Treg differentiation, the role of microRNAs in MS is not completely understood. Thereby, as a step closer, we analyzed the expression profile of miR-9-5p and miR-106a-5p, and protein level of retinoic acid receptor (RAR)-related orphan receptor C (RORC; Th17 master transcription factor) as direct target of miR-106a-5p... 

Three newly synthesized room temperature ionic liquids containing molybdate anion, [DMIm][MoO 2(NCS) 4], [RPy][MoO 2(NCS) 4] (R = butyl or decyl), and previously reported [BMIm][MoO 2(NCS) 4] were used as catalysts for the reduction of sulfoxides. For facilitating the recyclability of the catalysts, the ionic liquids [RMIm][PF 6] and [RPy][PF 6] (RMIm = 1-n-alkyl-3-methylimidazolium, RPy = 1-n-alkylpyridinium) were applied as ionic solvents and toluene is used as solvent for the organic phase. Molybdenum salts immobilized in RTILs constituted a reusable and efficient heterogeneous catalyst system. A maximum conversion (>99%) was achieved for reduction of diphenyl sulfoxide to diphenyl... 

Two room temperature liquid salts containing molybdenum(VI), [BMIM] 2[MoO2(NCS)4] (1) and [DMIM] 2[MoO2(NCS)4] (2), were immobilized on ionic liquid-modified silica leading to materials which showed notable catalytic activity for the reduction of sulfoxides into sulfides with triphenylphosphine (PPh3). The molybdenum liquid salts immobilized on the supported ionic liquid phase could be reused at least for three catalytic cycles without significant loss of activity  

Some cis-dioxomolybdenum (VI) complexes with tridentate Schiff base ligands derived from salicylaldehyde and aminophenols, aminoalcohol or o-aminobenzenethiol were examined as catalysts for epoxidation of different aliphatic and aromatic olefins, with tert-butyl hydroperoxide as oxidant. All complexes exhibited high activity and selectivity for epoxidation of aliphatic substrates during a short time period (95% conversion of cyclooctene after 30 min). The epoxide yield increased with the nucleophilic character of olefin. The catalysts activation strongly depends on the reaction temperature and nature of the solvent. Epoxidation of olefins by these catalysts is inhibited by ligands or...