Sharif Digital Repository

The heteronuclear complexes [MePt(bhq)(μ-dppy)Au(PPh3)]PF6, 2, [MePt(bhq)(dppy)Tl]PF6, 3 and [Me2Pt2(bhq)2(dppy)2Tl]PF6, 4 in which bhq=benzo{h}quinoline and dppy=2-diphenylphosphinopyridine, were prepared by reaction of the mononuclear complex [MePt(bhq)(dppy)] 1 with 1 equivAuCl(PPh3), 1equiv TlPF6 and 1/2 equiv TlPF6 respectively. All the complexes were fully characterized using multinuclear NMR spectroscopy and ESI-MS spectrometry. In addition molecular structures of complexes 2 and 3 in solid state have been determined by X-ray crystallography that shown strong dative bonds between platinum and gold or thallium atoms. As shown by ESI-MS spectrometry, the Pt-Au bond in complex 2... 

The use of polymers is increasing day by day due to low density, reasonable price and ability to produce different products. On the other hand, the accumulation of polymer wastes in nature is one of the environmental concerns in today's world, which is mainly due to the widespread use of polymers in the packaging industry and disposable applications. In order to solve this problem, recycling is recommended as the most appropriate and economical solution. Because in addition to consuming polymer waste, it also saves energy and reduces carbon footprint.Polyethylene terephthalate (PET) is one of the polymeric materials which; It has a special place in the packaging industry and is widely used... 

The improved properties of nanocomposites are not achievable with conventional composites. Scale effect is one the most important parameters in the physical and mechanical properties of polymeric nanocomposites. One of the physical phenomena, which can be related to the scale effect, is the very large interface between the nanoparticles and the polymeric matrices. Motional behavior and conformation of polymeric chains change near the nanoparticles surfaces. Due to high interface of the nanoparticles with the polymeric matrices the amount of these types of changes in the polymeric chains are so large that can change the physical and mechanical properties of polymeric nanocomposites. In this... 

Drug-eluting bone implant coatings is a new era that has gained a lot of attention in recent years. In this matter, drug is loaded in the coating and local and targeted release of the drug results in preventing the side effects of implantation and increasing the healing process of the patient. The aim of this project was to synthesis the antibiotic eluting chitosan-based composite using electrophoretic deposition for bone implant coating. By using electrophoretic deposition chitosan and chitosan-bioglass composite coatings were synthesized. Then the probability of loading of drug into coating by using electrophoretic deposition was evaluated and by using this process chitosan and... 

The behavior of boundary layer under the effect of the sweep angle is considered. The measurements were performed by a pitot tube rake. Three models with various sweep angels at angles of attack -2, 0 and 2 degree were tested. Both tip and root of all wings were closed by flat plates in order to prevent the flow to roll-up. However the flow field on the wing was still three-dimensional because of the sweep angle. The velocity on the wing has two components; longitudinal and lateral. The cross flow emerges due to the non-equilibrium of pressure and centrifugal forces. The velocity profiles showed that the magnitude of cross flow was stronger near the leading edge of the wing. The cross flow... 

In the field of high-pressure material science, diverse carbon systems under pressure have been intensively studied with interest in synthesizing new phases. A variety of these synthetic phases which have met various applications in today technology are called the amorphous diamond. The pressure-induced structural transition of carbonaceous material to amorphous diamond is realized by shock compression and rapid quenching. The shock compression and rapid quenching generate the high pressure (several GPa) and the temperature (several hundred K) in a fraction of a microsecond.Since the mechanical and electrical properties of the synthetic diamond are severely sensitive to the atomic structure,... 

The numerical solution of differential equations in high dimensions has always been a challenge and has been associated with various computational difficulties. These equations appear naturally in a variety of problems such as financial mathematics, control, and physics, and their optimal solution with high accuracy and speed can open new windows on new applications. Conventional methods such as Finite element and finite difference method in high dimensions lose their efficiency, which is a barrier to fast and accurate calculation of these equations. In this dissertation first, we review some theoretical and practical aspects of deep neural networks and then we try to examine the recent... 

DNA is the most important biological molecule which contains all the genetic information of living organisms. The mechanical behavior of this molecule has a significant role on its functions. In this study, we introduce a model to for DNA nanomechanics. This model is called rigid base-pair chain in which every base pair is considered as a rigid object. The base-pairs only interact with their nearest neighbors via a harmonic potential. We have used this model to study the nanomechanical behavior of the DNA such as its bending, twisting, and stretching elasticity. Also the model was successful to predict the structure of DNA minicircles with extra amount of twist. After that we used the model... 

Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related... 

Hydroxyapatite is the most substantial inorganic constituent of bone tissue which displays splendid biocompability and bioactivity. Nevertheless, its mechanical properties is not utmost appropriate for a bone substitutes. Therefore, it is used to improve the mechanical properties of polymer matrix composite scaffolds. In the present work polycaprolactone as a polymeric matrix was employed to fabricate hydroxyapatite-polycaprolactone biocomposite scaffolds via in situ route. Solvothermal method was employed to synthesize in situ hydroxyapatite in polymer matrix. Porous scaffolds were fabricated via freeze-drying/porogen leaching. Physical, mechanical (compressive module and compressive... 

The effects of biosurfactants on sandstone rocks are known in the literature. However, there are few examples of experimental works in Iranian carbonate reservoirs dealing with the effects of biosurfactants under reservoir conditions. This thesis discusses the effect of an efficient biosurfactant produced from Pseudomonas aeroginosa MRo1, a bacterial strain isolated from oil excavation areas in southern Iran, on the recovery of residual oil trapped within carbonate rocks was investigated. The MRO1 could reduce surface tension from 72 to 28 dyne/cm. It also could reduce Interfacial tension from 18.382 to 5.646 dyne/cm.
In a core holder set-up bearing four limestone- and... 

Secure routing is a major key to service maintenance in wireless ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. Wormhole attack is one of the most severe active attacks to mobile ad hoc networks. Noting the resource limitations in such networks, nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a... 

Fluid flow simulation in heterogeneous, full field porous media, like hydrocarbon reservoirs and underground aquifers usually requires multimillion block models, demanding unpractical computation times. Massive researches have been conducted to upscale these fine grid models to coarse models with manageable block numbers. Many upscaling methods have been proposed. These methods differs regarding their gridding techniques (uniform/ structured or disordered), general applicability (process dependency), maximum coursing level achievable, accuracy of the method and their speed-up factor and extend from simple arithmetic averaging to complicated numerical methods. Applying a very powerful...