Immobilization of Laccase Using Metal-Organic Framework and its Application in Micropollutant Removal

, M.Sc. Thesis Sharif University of Technology Ghassemi, Raman (Author) ; Yaghmaei, Soheila (Supervisor) ; Ghobadinejad, Zahra (Supervisor)

Abstract

Nowadays, micropollutants present in aquatic environments posses a significant threat to the well-being and health of human beings. Various physicochemical and advanced approaches have been proposed to confront these hazards. In recent years, biological treatment methods have gained great interest for their green approach. One of these biological treatment options is the treatment of polluted waters by enzymes. Enzymatic treatment of micropollutants can be achieved by oxidoreductase enzymes. One of the most important and widely used oxidoreductase enzymes employed for water treatment is Laccase. However, enzyme immobilization is employed to counter the drawbacks of using enzymes, such as...

The Selection of Appropriate Method for the Degradation of Microplastics

, M.Sc. Thesis Sharif University of Technology Pourjafar Biazar, Fatemeh (Author) ; Yaghmaei, Soheila (Supervisor) ; Ghobadinejad, Zahra (Supervisor)

Abstract

Microplastics are pollutants that are very resistant to natural decomposition and have become a threat to human health by entering the food chain and accumulating in the body. In this research, the second stage of the two-stage treatment of light density polyethylene microplastics was carried out to investigate the effect of pre-treatment on the removal efficiency of this pollutant. For this purpose, the microplastic samples, which were subjected to a pre-treatment stage with advanced oxidation processes, were again subjected to biological degradation by a bacterial consortium for 2 months. The pretreatment processes used were Fenton and Feredfenton reactions, and the bacterial consortium...

Enhancing Biological Removal Yield of Microplastics Using Advanced Oxidation Processes (AOPs)

, M.Sc. Thesis Sharif University of Technology Shamsi, Zahra (Author) ; Ghasemian, Saloumeh (Supervisor) ; Yaghmaei, Soheila (Supervisor) ; Ghobadinejad, Zahra (Supervisor)

Abstract

Statistics show that plastic production in the world is increasing, with 335 million tonnes in 2016 reaching 367 million tonnes in 2020. Since the presence of plastics in the dimensions of micro and nano, especially in aquatic environments can have adverse effects on human health and other living organisms, it has raised major environmental concerns. Therefore, it is necessary to think of measures to remove them and develop efficient methods for eliminating and decomposing microplastics. Recently, the advanced oxidation processes have attracted much attention because of the ability to eliminate recalcitrant compounds. In this study, electrochemical techniques and Fenton-based techniques for...

Application of Advanced Oxidation Processes and Biological Methods to Degrade Levofloxacin

, M.Sc. Thesis Sharif University of Technology Solouki, Melika (Author) ; Yaghmaei, Soheila (Supervisor) ; Ghasemian, Saloumeh (Supervisor) ; Ghobadinejad, Zahra (Supervisor)

Abstract

Levofloxacin has been widely used in recent years as an antibiotic in the treatment of various bacterial infections. This drug compound is known as a newly emerging contaminant. In this study, the degradation of this pollutant has been investigated using advanced oxidation processes, biological process, and a combination of advanced oxidation-biological processes. In order to evaluate the degradation of levofloxacin with advanced oxidation processes, an electrochemical process was used. Advanced oxidation processes were carried out to optimize initial concentration parameters of the contaminant (5-15 milligrams per liter), electrolyte concentration (2.5-10 grams per liter), and current...

Application of Combination of Biological and Chemical based on Oxidation Methods to Treat Emerging Contaminants

, M.Sc. Thesis Sharif University of Technology Najmi, Mohammad (Author) ; Yaghmaei, Soheila (Supervisor) ; Ghasemian, Saloumeh (Supervisor) ; Ghobadinejad, Zahra (Co-Supervisor)

Abstract

Industrial wastewater is laden with various hazardous organic and inorganic pollutants, the release of which into the environment without treatment processes poses potential risks. In recent years, water pollution by emerging contaminants such as pharmaceuticals and personal care products has garnered significant attention. This study investigates the removal of four hard-to-degrade pharmaceutical pollutants, namely metronidazole, tetracycline, ciprofloxacin, and carbamazepine, classified as emerging contaminants, using advanced oxidation and biological treatment methods both separately and in combination. Electrochemical oxidation was employed as a reliable method for the pretreatment and...

Removal of Micropollutants from Wastewater Using an Electrochemical Biomembrane Reactor

, M.Sc. Thesis Sharif University of Technology Abbasi, Pezhman (Author) ; Ghasemian, Saloumeh (Supervisor) ; Ghobadinejad, Zahra (Co-Supervisor) ; Hamzehlouyan, Tayebeh (Co-Supervisor)

Abstract

One of the major environmental problems in recent years is the presence of micropollutants that cause many problems for the environment and living organisms. Diclofenac is one of the micropollutants and endocrine disruptors. Conventional treatment methods do not have the ability to effectively remove pharmaceutical pollutants and micro-pollutants, and finding a suitable approach to remove these pollutants is of great importance. In recent years, biological methods such as the use of enzymes and molds have received attention, but due to the relative removal of pollutants, these methods have been combined with membrane technology to improve the level of pollutant removal and increase the...

Heavy metal tolerance of fungi

, Article Scientia Iranica ; Volume 18, Issue 3 C , 2011 , Pages 502-508 ; 10263098 (ISSN) Anahid, S ; Yaghmaei, S ; Ghobadinejad, Z ; Sharif University of Technology

2011

Abstract

This study was focused on the heavy metal (Ni, Co, Mo, V, Mn, Fe, W and Zn) tolerance of fungi strains Aspergillus niger, Aspergillus foetidus and Penicillium simplicissimum. Aspergillus niger was exposed to a mixture of Mo, V and Mn at a mass ratio of 1:2:6 as approximately present in the spent refinery processing catalyst. This study highlights the adaptation of fungi strains to Tungsten and Vanadium to high concentration. The effect of different metals and metal concentration on different strains of fungi was evaluated. Results showed that Ni was one of the most toxic metals for strains of Aspergillus and Penicillium. Aspergillus foetidus was the least tolerant, in particular for Ni, Co...

Production of extracellular protease and determination of optimise condition by bacillus licheniformis BBRC 100053

, Article Chemical Engineering Transactions ; Volume 21 , 2010 , Pages 1447-1452 ; 19749791 (ISSN) ; 9788895608051 (ISBN) Ghobadinejad, Z ; Yaghmaei, S ; Haji Hosseini, R ; Sharif University of Technology

2010

Abstract

The production of protease by Bacillus licheniformis BBRC 100053 was studied. The most appropriate medium for the growth and protease production is composed of: lactose 1 %, yeast extract 0.5 %, peptone 0.5 %, KH 2PO4 0.1%, MgSO4.7H2O 0.02 %. Enzyme production corresponded with growth and reached a maximums level (589 U/ml) during the stationary phase at 35 °C, pH equivalent to 10 and with 150 rpm after 73 hours. Protease activity was highest at pH 8 and 45 °C. The best carbon sources are respectively lactose and maltose and the best nitrogen source is peptone The protease was highly active and stable from pH 7.0 to 11.0 with an optimum at pH 7-8.Thermo stability of the enzyme was considered...

Mesoporous silica nanoparticles (MCM-41) coated PEGylated chitosan as a pH-Responsive nanocarrier for triggered release of erythromycin [electronic resource]

, Article International Journal of Polymeric Materials and Polymeric Biomaterials ; 2014, Volume 63, Issue 13, Pages 692-697 Pourjavadi, A. (Ali) ; Mazaheri Tehrani, Zahra ; Sharif University of Technology

Abstract

A pH-responsive drug delivery system based on core shell structure of mesoporous silica nanoparticle (MSN) and chitosan-PEG copolymer was prepared and characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and high-resolution transmission microscope (HR-TEM) techniques. In order to improve compatibility MSN and drug, mesoporous nanosilica was modified by 3-aminopropyl triethoxysilane. The release of erythromycin (a macrolide antibiotic) as a model drug was investigated in two pHs, 7.4 and 5.5

Theoretical and Computational Investigation of Quantum Plasmonic Properties of Nanocluster Dimers

, M.Sc. Thesis Sharif University of Technology Mahmoudi, Erfan (Author) ; Jamshidi, Zahra (Supervisor)

Abstract

In today's era, metal nanoparticles play an important role in technologies emerging from different sciences, such as chemistry, physics, optics, material science, due to their unique characteristics. In the development of nanooptics science, it can be said that metal nanoparticles play an important role. The ability of conductive electrons collective oscillation causes surface charge density fluctuations in nanoparticles, this phenomenon is known as surface plasmons. Surface plasmons are surprisingly coupled with light and cause the significant increase in the intensity of optical fields induced in nanoparticles. Therefore, with the presence of localized surface plasmons or plasmon...

Theoretical Investigation of Ab-initio MD Approach to Increase the Efficiency and Accuracy of VCD Spectrum Calculation

, M.Sc. Thesis Sharif University of Technology Hadi, Hossein (Author) ; Jamshidi, Zahra (Supervisor)

Abstract

Understanding of the Molecules is the main purpose of the chemistry. Ab-initio molecular dynamics (AIMD) as a branch of the computational chemistry, tries to give us a deep comprehension of the molecule, and its chemical, physical and optical activities. This comprehension, relies on the accuracy of quantum mechanics, in addition to the speed of the classical mechanics. The mixing of the quantum mechanics and the classical mechanics could simulate activities of the atoms in the time-domain, provided the mixing is done with precaution. This, in turn, helps us to forecast the response of a molecule in different situations, and also translating the macroscopic phenomena in a nanoscopic...

Investigation of Plasmonic Excitation in Carbonic Nanostructures Within Near-IR

, M.Sc. Thesis Sharif University of Technology Madadi, Mahkam (Author) ; Jamshidi, Zahra (Supervisor)

Abstract

To date, the plasmonic properties of many metallic and semi-conducting materials have been investigated and used in various industries. One of the plasmonic material categories that have always been considered is polycyclic aromatic hydrocarbon or PAH, whose plasmonic resonance energy depends on the charge state of the molecule. In this regard, it is easy to change the plasmonic resonance energy via changing the induced charge, which is a unique feature of the mentioned materials. In addition, plasmonic structures with excitations in the infrared region are able to enhance the vibration intensity of absorbed molecules by increasing the electric field around themselves. Therefore, they have...

Using Nonlinear Effects of Light for Optical Signal Processing

, M.Sc. Thesis Sharif University of Technology Shatery, Farshid (Author) ; Kavehvash, Zahra (Supervisor)

Abstract

Ultrafast signal processing in time-domain with high resolution and reconfigura-bility is a challenging task. This paper, for the first time, introduces a time-varying metasurface consisting of graphene microribbon array for implementing time-lens in the terahertz domain. Given that the surface conductivity of graphene is proportional to the Fermi energy level in the THz regime, it is possible to change the phase property of the incident electromagnetic pulse by changing the Fermi level while the Fermi level itself is a function of voltage. Upon this fact, a quadratic temporal phase modulator, namely time-lens has been realized. This phase modulation is applied to the impinging signal in the...

Using Simulation-Optimization Approach for Fire Station Location and Vehicle Assignment Problem: a Case Study in Tehran, Iran

, M.Sc. Thesis Sharif University of Technology Pirmohammadi, Ali (Author) ; Amini, Zahra (Supervisor)

Abstract

In this research, the problem of locating fire stations and allocating equipment has been studied and a simulation-optimization approach has been presented to solve the problem. The mathematical models of this research were developed based on the idea of the randomness of the covered demand and the maximum expected coverage model. In these models, the issue of non-availability of equipment to cover accidents, the random nature of accidents, various fire incidents and the equipment needed to cover them are considered. Two mathematical models with deterministic and non-deterministic approach with different scenarios for demand are proposed. The non-deterministic model is developed with the aim...

Introducing An Integrated Framework For Solving The Fleet Planning Problem Using A Simulation-Optimization Approach

, M.Sc. Thesis Sharif University of Technology Sahebi, Armin (Author) ; Amini, Zahra (Supervisor)

Abstract

One of the main concerns of industrial companies’ managers is providing an efficient logistics system. To achieve an efficient logistics system, the fleet planning problem is studied by many researchers in recent years. This problem consists of multiple sub-problems at three levels: operational, tactical, and strategic. These sub-problems are closely related to each other and need to be studied and addressed in an integrated manner. In this research, an attempt is made to provide an integrated framework to solve the vehicle routing problem (operational), outsourcing problem (tactical), and fleet composition problem (strategic). These problems have various uncertainties, including customer...

Analytical Modelling and Optimization of Disk Type, Slot Less Resolver

, M.Sc. Thesis Sharif University of Technology Moheyseni, Atefeh (Author) ; Nasiri Gheidari, Zahra (Supervisor)

Abstract

Resolvers, due to their robust structure, are widely used in automation systems. Among the types of resolvers, the accuracy of the Wound Rotor (WR) resolver in the occurrence of common mechanical errors is higher than other types of resolvers. therefore, in this thesis, an AFWRR is studied to improve the performance. Increasing the number of poles in WR resolvers is a good solution for increasing the accuracy of these electromagnetic position sensors. However, high-speed WR resolvers due to employing fractional slot windings suffer from rich sub-harmonics in the induced voltages. A common solution for suppressing the undesirable sub-harmonics is using multi-layer winding with appropriate...

A Survey on Searchable Symmetric Encryption Schemes

, M.Sc. Thesis Sharif University of Technology Sajadieh, Zahra Sadat (Author) ; Khazaei, Shahram (Supervisor)

Abstract

Using “Searchable Encryption” enables us to encrypt the data, while preserving the possibility of running search queries. One of the most important applications of the mentioned is in Cloud Storage. As users do not trust the Cloud space, they are not inclined to store their data on the Could. The solution to this problem is of course, Cryptography. However, ordinary Cryptography methods, eliminate the data’s searchability. Hence, we need encryption schemes that code the data while retaining their searchability. So far, various schemes has been proposed that differ in their performance, security level, and usage. In this thesis, we aim to discuss and analyze these methods

Time Domain Optical Signal Processing Based on the Duality Between Dispersion and Diffraction

, M.Sc. Thesis Sharif University of Technology Eksiri, Fatemeh (Author) ; Kavehvash, Zahra (Supervisor)

Abstract

In the last decades, due to the growing demand of transferring information with high transmission rates, the complexity and development of telecommunication and optical systems is remarkable. Researchers around the world attempt to explore extraordinary potential of light to process information. In the mid-19th century, scientists discovered a mathematical symmetry between the spatial and temporal optics fields, which originated from the similarity of equations governing the paraxial diffraction of beams and the dispersion of narrow-band pulses known as space– time duality in scientific texts. This new approach provides more advanced and potent methods to temporal processing and...

Improving the Stability of an Urban Traffic Network with Limited Data by Using Percolation Theory and Dynamic Clustering

, M.Sc. Thesis Sharif University of Technology Hassanzadeh, Ehsan (Author) ; Amini, Zahra (Supervisor)

Abstract

One of the most vital aspects of understanding the traffic phenomenon is scrutinizing the traffic transition status, such as the transition from free flow to congestion. The Percolation Theory is a renowned theory focusing on analyzing various network types to detect the critical zones, which are the zones including links that are important to control to improve stability. By calculating the quality indices of network links, the Percolation Theory can simulate the traffic percolation propagation in the network and determine possible critical zones for further analysis. Most studies in this field assume access to data of several traffic parameters for the entire transportation network, such...

Temporal Depth Imaging Based on Dispersion

, M.Sc. Thesis Sharif University of Technology Behzadfar, Shiva (Author) ; Kavehvash, Zahra (Supervisor)

Abstract

In this thesis, the aim is designing an optical temporal imaging system. In recent years, due to many applications, including the receipt of high-rate data by slow receivers and compensation of dispersion in telecommunication systems, researchers have considered the topic of temporal imaging. This field of research is based on dispersion, electro-optical modulators or time lenses and space-time theory. By modeling dispersion properties as a depth dimension and taking ideas from three-dimensional spatial imaging systems we intended to increase the temporal resolution and depth of focus of the structure. We also present a novel technique for multiplexing and demultiplexing telecommunication...