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A systematic investigation on the bactericidal transient species generated by photo-sensitization of natural organic matter (NOM) during solar and photo-Fenton disinfection of surface waters
, Article Applied Catalysis B: Environmental ; Volume 244 , 2019 , Pages 983-995 ; 09263373 (ISSN) ; Giannakis, S ; Gholami, M. R ; Feng, L ; Pulgarin, C ; Sharif University of Technology
Elsevier B.V
2019
Abstract
In this work, the role of dissolved oxygen in the solar and the photo-Fenton-mediated E. coli inactivation process was put under scrutiny. The effect of transient species that were produced in the presence of various natural organic matter isolates (NOM), namely Suwannee River (SR) NOM, Nordic Reservoir (NR) NOM, SR Humic acid (SRHA), and SR Fulvic acid (SRFA) was studied in detail. The role of 1 O2 in this reaction was systematically evaluated by modifying the O2 concentration (N2/O2 purging) and the matrix composition (10, 50, and 100% deuterium oxide (D2O) v/v). In the presence of NOM, 1 O2 was generated and the enhancement of E. coli inactivation rate due to charge transfer from triplet...
A novel low power architecture for DLL-based frequency synthesizers
, Article Circuits, Systems, and Signal Processing ; Volume 32, Issue 2 , 2013 , Pages 781-801 ; 0278081X (ISSN) ; Sharif University of Technology
2013
Abstract
This paper presents a novel DLL-based frequency synthesizer architecture to generate fractional multiples of reference frequency and reduce the power consumption of the frequency synthesis block. The architecture is adopted for French VHF application as an example. The DLL architecture allows for minimal area, while consuming low power. The proposed circuit can operate at a substantially low supply voltage. The circuit level and system level designs are presented. It was shown that for the mentioned standard, a mere 27 delay stages for VCDL are sufficient to cover French VHF band. Simulation results confirm the analytical predictions. The proposed DLL-based frequency synthesizer is...
A joint exprimental and theoretical study on ZnO nanocomposites synthesised by a liquid deposition method
, Article Progress in Reaction Kinetics and Mechanism ; Volume 40, Issue 3 , July , 2015 , Pages 261-278 ; 14686783 (ISSN) ; Zeidabadi Nejad, L ; Tasviri, M ; Dehestani, M ; Haqgu, M ; Gholami, M. R ; Sharif University of Technology
Science Reviews 2000 Ltd
2015
Abstract
ZnO was grown on mordenite zeolite, activated carbon and alumina substrates by a liquid deposition method. The photocatalytic activity of the synthesised samples was elucidated using the photodegradation of Acid Blue 92 (AB92) dyes as a test pollutant under UV light irradiation. Supports play a key role in AB92 photodegradation and significantly improve the photocatalytic activity of ZnO. Different supports form additional transport channels and provide an effective pathway for the charge carriers. The supports effectively construct porous structures with more active sites. Hence, the higher photocatalytic activity of supported catalysts is attributed to the large surface area and charge...
Determinants of Free Trade Agreements Based on Limited Dependent Variable Models: ECO countries and their major trading partners
, M.Sc. Thesis Sharif University of Technology ; Abedini, Javad (Supervisor)
Abstract
Establishing an efficient free trade agreement (FTA) requires some conditions in both trading partners. The median voter approach insists on the direction of general interests (identified by the utility of a median voter) to explain how two countries may agree to sign an FTA. At the other side, lobbying approach emphasizes on the role of interest groups (groups with a large influence on the public decisions) in forming FTAs. Taking into account the theoretically based and empirically robust foundation of the median voter approach, we rely on it to investigate the major determinants of free trade agreements in the case of ECO countries besides all their main trade partners. The database...
Environmental and Economical Assessment of Green Building Compared with Conventional Buildings in Iran (A Case study in the city of Karaj)
, M.Sc. Thesis Sharif University of Technology ; Erhami, Mohammad (Supervisor)
Abstract
This thesis studied the definition of a green building and the elements associated with the construction of a green residential apartment in comparison with traditional buildings with respect to condition of Karaj city. The first step in green construction is preparing a guideline. For this, LEED (Leadership in Energy and Environmental Design) the most well-known code for green buildings is used and Adapted with Iran’s National Building Regulations. Creating a checklist to rate buildings is one of the most important parts of Green Building Regulations. To achieve the points, US LEED certification is analyzed in both qualitative and quantitative perspectives. A questioner is applied in...
Development a Numerical Algorithm for Differential Relay for Transformer Protection
, M.Sc. Thesis Sharif University of Technology ; Vakilian, Mehdi (Supervisor)
Abstract
The goal of this master thesis is to develop a new accurate numerical algorithm for digital differential relay to protect a power transformer. This work employs specially developed software to simplify its input signal processing task which helps to quickly and accurately detect and clear the transformer internal faults. The available commercial transformer digital differential relays lack the required sensitivity to detect turn to turn faults when a few numbers of turns (less than 10% of the winding) are involved. This work presents a new equivalent circuit for transformer when a turn to turn fault occurs on either winding. This equivalent circuit helped to develop an accurate algorithm for...
Effect of Masterbatch Carrier Type on Rheological, Thermal and Mechanical Properties of Bimodal Polyethylene Compounds with Different Short Chain Branching Distribution
, M.Sc. Thesis Sharif University of Technology ; Pircheraghi, Gholamreza (Supervisor)
Abstract
Polyethylene is one of the most widely used industrial materials for producing water and gas pipes due to low pricing and mechanical properties and high corrosion resistance. Various parameters such as molecular weight and the short chain branches distribution strongly affect the mechanical properties of these materials. PE100 grade of this material has been introduced with bimodal molecular weight distribution, has excellent mechanical properties and especially high creep resistance and today is used for pipe production in water distribution systems. In the first part of this study, the effect of 1-butene comonomers on different properties of three PE100 and two PE80 resins produced in...
The Dynamic Effects of Oil Price Shock and Basemetals Price Shock on Tehran Stock Exchange Return and Commodity-based Industries Returns
, M.Sc. Thesis Sharif University of Technology ; Barakchian, Mahdi (Supervisor)
Abstract
This study investigates the effect of commodity price shock, including oil and base metals prices, on Tehran exchange and industries stock returns. These industries have the largest market share in Tehran exchange and may heavily depend on global prices. Using weekly data from 1387 to 1396, Multifactor and VAR models are performed to analyze the variance decomposition and impulse response function of each industry to 1% price shock. In addition to global prices, some macroeconomic factors that are likely to affect stock returns are considered. The results show that commodities price shocks have dynamic and significant effects on stock returns
Antibody consumption reduction in lateral flow immunoassays within porous media
, Article Chemical Engineering and Processing - Process Intensification ; Volume 147 , 2020 ; Shamloo, A ; Sharif University of Technology
Elsevier B.V
2020
Abstract
In this study, the effect of the geometrical parameters of the Lateral Flow Immunoassay (LFI) membrane on the performance of the pregnancy kits is investigated. Consequently, a new geometry for LFI membrane is proposed based on some theoretical, numerical and experimental observations in order to improve the performance of the related kits. A pregnancy kit (for the detection of hCG in urine samples) is developed and the effect of the relocation of the test and the control lines over the membrane was studied based on the variation of the sample fluid velocity. Using Lattice-Boltzmann simulation of the lateral flow within the porous media and the experimental results, the fluid flow within the...
Vibration Analysis of Screw Compressor
, M.Sc. Thesis Sharif University of Technology ; Behzad, Mehdi (Supervisor)
Abstract
Screw compressors are rotary positive displacement compressors that utilize a pair of helical lobed rotors in a casing. Part 3 of ISO 10816 does not include Positive displacement compressors. VDI 3836 has more vibration amplitude limitations for this compressor than industrial machines under ISO 10816-3. The screw compressor has no valves; therefore, the location of the suction and discharge ports determines the compressor cycle. This study focuses on the condition monitoring through vibration analysis of screw compressors. The purpose of this study is to investigate the reason for excluding of screw compressors by ISO standard and also to explain the vibration dependence of these...
Evaluation of Anisotropic Hydraulic Conductivity of as Compacted and Vegetated Soils with a Cube Triaxial Permeameter
, M.Sc. Thesis Sharif University of Technology ; Sadeghi, Hamed (Supervisor)
Abstract
Vegetation can be used as a research solution at the cutting edge of knowledge, cost-effective, aesthetic, pleasing, and environmentally friendly in natural hazards. Understanding the hydraulic properties, including the permeability of vegetated soils, is very important for various environmental applications. Different and sometimes conflicting behaviors have been observed in literature. There has been no general consensus in the literature regarding permeability due to the influence of several factors. In addition, there are many uncertainties about the effect of plant cultivation and root system effects on anisotropic soil permeability. It is essential to address this issue because of the...
Sustainable release of vancomycin from silk fibroin nanoparticles for treating severe bone infection in rat tibia osteomyelitis model
, Article ACS Applied Materials and Interfaces ; Volume 9, Issue 6 , 2017 , Pages 5128-5138 ; 19448244 (ISSN) ; Mottaghitalab, F ; Eslami, M ; Gholami, M ; Kundu, S. C ; Kaplan, D. L ; Farokhi, M ; Sharif University of Technology
American Chemical Society
2017
Abstract
The successful treatment of bone infections is a major challenge in the field of orthopedics. There are some common methods for treating bone infections, including systemic antibiotic administration, local nondegradable drug vehicles, and surgical debridement, and each of these approaches has advantages and disadvantages. In the present study, the antibiotic vancomycin (VANCO) was loaded in silk fibroin nanoparticles (SFNPs) and the complexes were then entrapped in silk scaffolds to form sustained drug delivery systems. The release kinetics of VANCO from SFNPs alone and when the SFNPs were entrapped in silk scaffolds were assessed at two different pH values, 4.5 and 7.4, that affected the...
Strategies for improving MDA-based development processes
, Article SMS 2010 - UKSim/AMSS 1st International Conference on Intelligent Systems, Modelling and Simulation, 27 January 2010 through 29 January 2010, Liverpool ; 2010 , Pages 152-157 ; 9780769539737 (ISBN) ; Ramsin, R ; Sharif University of Technology
2010
Abstract
The Model Driven Architecture (MDA) is meant to facilitate system development by using models for representing both the "problem" and its "solution". In its ideal form, software development based on MDA would follow a development process that begins by producing models of the problem domain at a high level of abstraction, and then proceeds by gradually and automatically transforming them into executable code with the help of tools. However, MDA-based development has encountered several setbacks, the mitigation of which requires detailed scrutiny and analysis. In this research, MDA-based development is analyzed through applying SWOT (Strengths, Weaknesses, Opportunities, and Threats) analysis...
Investigation and Controlling of Sludge Bulking in Wastewater Treatment Plant with Synthetic Wastewater
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaleddin (Supervisor)
Abstract
Biological treatment is an essential part of wastewater treatment. One of the major problems of the biological treatment systems is a solid separation. Filamentous bulking is a type of solid separation problem that settled sludge volume and the turbidity of the effluent will be increase in bulking condition. The presence of excessive Filamentous bacteria causes filamentous bulking. In this thesis, filamentous bulking were studied to understand this phenomena better and tried to control that with the different methods. This research was conducted in laboratory scale Sequencing Batch Reactor (SBR), conventional activated sludge and conventional activated sludge with anaerobic selector with...
Ontology-Based Android Malware Forensics
, M.Sc. Thesis Sharif University of Technology ; Amini, Morteza (Supervisor)
Abstract
Today, smart devices have become an integral part of everyday life. The Android operating system is also the most popular operating system of these devices, and as a result, various malwares are produced and distributed for this operating system every day. This makes it especially important to investigate these malwares. This includes finding people involved in the development and distribution of malware, as well as discovering other malwares created by them. Discovering other involved entities, such as social media accounts, websites, Android store accounts, and taking steps to prevent malware from being distributed by them is another aspect of this story. In order to deal with organized...
Gas-phase kinetics and mechanism of diallyl sulfide thermal decomposition
, Article Journal of Physical Organic Chemistry ; Volume 16, Issue 3 , 2003 , Pages 153-157 ; 08943230 (ISSN) ; Izadyar, M ; Sharif University of Technology
2003
Abstract
The gas-phase kinetics of diallyl sulfide pyrolysis were studied experimentally and theoretically in a static system over the temperature range 433-463 K and a total pressure of 80 Torr in a glass vessel with the free radical inhibitor cyclohexene. The experimental results show that this reaction is homogeneous, unimolecular and follows a first-order rate law. Theoretical studies at the B3LYP/6-31G* computational level indicate that the elimination reaction proceeds through a six-centered cyclic transition state and the reaction mechanism is concerted and non-synchronous. Copyright © 2003 John Wiley & Sons, Ltd
A joint experimental and computational study on the kinetic and mechanism of diallyl disulfide pyrolysis in the gas phase
, Article Chemical Physics ; Volume 301, Issue 1 , 2004 , Pages 45-51 ; 03010104 (ISSN) ; Izadyar, M ; Sharif University of Technology
2004
Abstract
A combined theoretical and experimental kinetic and mechanism of diallyl disulfide pyrolysis reaction in the gas phase was studied in a static system over the temperature range of 586.7-621.2 K and a total pressure of 72 Torr in the presence of cyclohexene as radicals inhibitor. The experimental results show that the reaction is homogeneous, unimolecular and proceeds through a radical mechanism. Theoretical calculations at the B3LYP level using the 6-31G*, 6-31++G* and 6-311++G* basis sets confirm the radical mechanism for the diallyl disulfide pyrolysis. The calculated kinetic and activation parameters especially at the B3LYP/6-31G* level are in good agreement with the experimental data. ©...
Gas phase kinetics and mechanism of 2,2-dimethyl but-3-enal and 1-methyl-6-methylenecyclohexa-2,4-diene-1-carbaldehyde retro-cheletropic ene reaction
, Article Journal of Molecular Structure: THEOCHEM ; Volume 672, Issue 1-3 , 2004 , Pages 61-66 ; 01661280 (ISSN) ; Izadyar, M ; Sharif University of Technology
Elsevier
2004
Abstract
Structural and kinetic aspects of the retro-cheletropic ene reactions of 2,2-dimethyl but-3-enal, 1-methyl-6-methylenecyclohexa-2,4-diene-1-carbaldehyde and their deuterated derivatives were investigated using a variety of computational methods. Theoretical calculations were carried out with ab initio and DFT methods at the RHF, MP2 and B3LYP levels of the theory, using the 6-31G* basis set. Vibrational frequency analysis confirmed the stationary states including the transition state (TSs) structures. Intrinsic reaction coordinate calculations show the localized TSs connect with the corresponding minima associated with the reactants and the products. The mechanistic studies on the...
Solvatochromic Parameters Effects Study on Kinetics of Aromatic Nucleophilic substitution reaction in mixture of Ionic liquid and alcoholic solvents
, M.Sc. Thesis Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor)
Abstract
Solute-solvent and solvent-solvent interactions were investigated in mixtures of 2-hydroxy ethylammonium formate with methanol, ethylene glycol and glycerol. Solvatochromic parameters, including normalized polarity ( ), dipolarity/polarizability (π*), hydrogen-bond donor (α), and hydrogen-bond acceptor (β) abilities, were determined in these mixtures. parameters showed synergetic effects in mixtures of ionic liquid and alcohols due to the preferential solvation. Experimental data were handled in Redlich-Kister model and demonstrated a fair correlation with predicted data. Solvent effects on reaction kinetics were studied in aromatic nucleophilic substitution reaction of 2-Chloro-3,5-...
Synthesis of TiO2 Nanoparticles Modified by Several Transition Metals and Investigation of their Effects on Degradation Kinetics of Dye
, M.Sc. Thesis Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor)
Abstract
In this project, TiO2 nanoparticles were prepared by the sol gel method. The band gap of TiO2 was modified with transition metal ions Pt, Pd, Ni. The kinetics and photocatalytic degradation of AB92 investigated. The effect of some parameters such as pH and amount of photocatalysis and calcination tempreture were examined. Also effect of transition metal increase on surface morphology and photocatalytic activity were investigated by XRD, BET, SEM, DRS and FT-IR Techniques. Dyes are an abundant class of colored organic compounds that represent and increasing environmental danger. Azo dyes are well-known carcinogenic organic substances. Advanced oxidation processes (AOPs) have been proposed as...