Sharif Digital Repository

In 2009, a general equation of state (EOS-III) based on an effective near-neighbor pair interaction of an extended Lennard-Jones (3, 6, 12) type has been introduced as : , where is the compressibility factor, p and ρ stand for pressure and molar density , respectively, T is Temperature , and e, f and g are the temperature dependent coefficient of the equation of state . the Z_th and Z_in are the thermal and internal contributions of pressure in the compressibility factor, respectively. this equation of state gives a good description of all types of nano- and bulk –solid and bulk fluid at entire temperature and pressure ranges for which thee is experimental data. Investigation show that... 

The rise in carbon dioxide levels has led to the manifestation of numerous environmental challenges. Currently, the absorption and conversion of carbon dioxide into valuable fuel resources such as synthetic gas, methane, and ethylene are deemed crucial from both environmental and economic standpoints. Despite the presentation of photocatalysts such as titanium oxide and electrocatalysts such as copper, silver, and zinc, their efficiency in CO2 conversion is found to be insufficient. One potential solution to this problem is the utilization of photoelectrocatalytic CO2 recovery. In this study, the aim was to enhance the photoelectrocatalytic reduction of CO2 by designing and manufacturing... 

Preformed particle gels (PPGs) due to its advatantage over commonly used in situ gels has been successfully applied for controlling excess water production in mature oil reservoirs. Field results of using PPGs in oil fields shows that commonly used PPGs are highly sensitive to hard reservoir conditions such as high temperature and salinity and can not effectively block fractures and high permeability layers.Objects of this study are synthesis and evaluating performance of this novel polymer based hydrogel in oil reservoirs with high temperature and salinity. Central composite design ( which is a experiment design approach) was used for synthesizing thirteen gel samples and optimal sample was... 

Biological layers are one of the main problems related to water transfer with pipe lines which are formed through time in the inner surface of the pipes by the water nutrients. Hence, the inner surfaces in the pipe lines and water refineries should be made in order not to let these biological layers to be made. The reason is that when the biofilm is formed on these surfaces, the traversing water is polluted. Dredging of these pipes is not only necessary in most of the countries in the world and needs huge amounts of water but is also very complex and expensive.In this research, nanomaterials, namely ZnO, T〖iO〗_2،S〖iO〗_2 have been used to cover the surface of concrete and steel pipes (The... 

Sand production from oil reservoirs leads to various problems, such as well productivity reduction, operating equipment corrosion, and increased production costs. Therefore, controlling sand production in unconsolidated reservoirs is crucial for operating companies. Chemical injection into the formation in order to strengthen and reduce sand production is one of the most important methods of sand control. In this study, a hydrogel nanocomposite was designed and its effectiveness in sand control was investigated. Various tests were carried out to define and assess its efficacy, as follows: Morphological tests demonstrated the creation of a dense, homogeneous, and porous structure. Structural... 

As fossil fuels are still the world's most important source of energy, as well as the maturity of most of the world's oil reservoirs, there is a need for enhanced oil recovery methods to meet the world's increasing oil demands. MEOR methods are new and promising methods that are still in the research and development stage. One of the MEOR methods is the use of biosurfactants, which increase the oil recovery by two mechanisms: 1) reducing the interfacial tension between water and oil and 2) changing the wettability of the rock. In this study, the performance of two glycolipid biosurfactants, rhamnolipid and sophorolipid, in increasing oil recovery has been investigated. Initially, surface... 

During the production of crude oil from reservoirs, the production of quantities of formation water along with this oil, causes the crude oil does not have the necessary indicators for transportation, refining and ultimately export. The presence of water and salt along with crude oil causes corrosion of refinery and transmission equipment and makes oil unfavorable in terms of economic efficiency (both for domestic use and for export). water and salt produce stable emulsion with oil that can be stable for a long time and can not be easily separated from crude oil. Therefore, separation of water and salt from crude oil is one of the most important issues in the oil industry. Breaking this... 

Considering the limitations of fossil fuels in recent years, as well as increasing demand for biofuels, it is anticipated that future attention to biofuels will increase further. Among biofuels, due to some disadvantages of bioethanol and biodiesel fuel, there is a tendency to use biobutanol, which does not have the disadvantages of the mentioned fuels. The cost of chemical production of butanol also led researchers to use biotechnology production of butanol. According to studies, butanol production can be achieved by fermenting some sugars such as glucose, xylose, and ... by anaerobic microorganism, but the cost of using these sugars has resulted in the use of natural sources of these... 

The methods of Enhanced Oil Recovery (EOR) from reservoirs have been taken into consideration recently due to the decline in oil reserves and the rise in energy demand. Studies and investigations indicate the tremendous potential of chemical approaches based on injecting ionic liquids into the porous media with the goal of improving oil recovery. Additionally, hydrogels and polymers, which are two of the process' primary materials, are thought to be good alternatives. In the current study, a hydrogel based on carboxymethyl cellulose was first created and synthesized. Ionic liquids based on imidazolium and triflate anion were then added, and their effectiveness in enhancing the properties... 

Establishing an efficient free trade agreement (FTA) requires some conditions in both trading partners. The median voter approach insists on the direction of general interests (identified by the utility of a median voter) to explain how two countries may agree to sign an FTA. At the other side, lobbying approach emphasizes on the role of interest groups (groups with a large influence on the public decisions) in forming FTAs. Taking into account the theoretically based and empirically robust foundation of the median voter approach, we rely on it to investigate the major determinants of free trade agreements in the case of ECO countries besides all their main trade partners. The database... 

The goal of this master thesis is to develop a new accurate numerical algorithm for digital differential relay to protect a power transformer. This work employs specially developed software to simplify its input signal processing task which helps to quickly and accurately detect and clear the transformer internal faults. The available commercial transformer digital differential relays lack the required sensitivity to detect turn to turn faults when a few numbers of turns (less than 10% of the winding) are involved. This work presents a new equivalent circuit for transformer when a turn to turn fault occurs on either winding. This equivalent circuit helped to develop an accurate algorithm for... 

This thesis studied the definition of a green building and the elements associated with the construction of a green residential apartment in comparison with traditional buildings with respect to condition of Karaj city. The first step in green construction is preparing a guideline. For this, LEED (Leadership in Energy and Environmental Design) the most well-known code for green buildings is used and Adapted with Iran’s National Building Regulations. Creating a checklist to rate buildings is one of the most important parts of Green Building Regulations. To achieve the points, US LEED certification is analyzed in both qualitative and quantitative perspectives. A questioner is applied in... 

This study investigates the effect of commodity price shock, including oil and base metals prices, on Tehran exchange and industries stock returns. These industries have the largest market share in Tehran exchange and may heavily depend on global prices. Using weekly data from 1387 to 1396, Multifactor and VAR models are performed to analyze the variance decomposition and impulse response function of each industry to 1% price shock. In addition to global prices, some macroeconomic factors that are likely to affect stock returns are considered. The results show that commodities price shocks have dynamic and significant effects on stock returns  

Screw compressors are rotary positive displacement compressors that utilize a pair of helical lobed rotors in a casing. Part 3 of ISO 10816 does not include Positive displacement compressors. VDI 3836 has more vibration amplitude limitations for this compressor than industrial machines under ISO 10816-3. The screw compressor has no valves; therefore, the location of the suction and discharge ports determines the compressor cycle. This study focuses on the condition monitoring through vibration analysis of screw compressors. The purpose of this study is to investigate the reason for excluding of screw compressors by ISO standard and also to explain the vibration dependence of these... 

Polyethylene is one of the most widely used industrial materials for producing water and gas pipes due to low pricing and mechanical properties and high corrosion resistance. Various parameters such as molecular weight and the short chain branches distribution strongly affect the mechanical properties of these materials. PE100 grade of this material has been introduced with bimodal molecular weight distribution, has excellent mechanical properties and especially high creep resistance and today is used for pipe production in water distribution systems. In the first part of this study, the effect of 1-butene comonomers on different properties of three PE100 and two PE80 resins produced in... 

Vegetation can be used as a research solution at the cutting edge of knowledge, cost-effective, aesthetic, pleasing, and environmentally friendly in natural hazards. Understanding the hydraulic properties, including the permeability of vegetated soils, is very important for various environmental applications. Different and sometimes conflicting behaviors have been observed in literature. There has been no general consensus in the literature regarding permeability due to the influence of several factors. In addition, there are many uncertainties about the effect of plant cultivation and root system effects on anisotropic soil permeability. It is essential to address this issue because of the...