Sharif Digital Repository

This study investigates the effect of commodity price shock, including oil and base metals prices, on Tehran exchange and industries stock returns. These industries have the largest market share in Tehran exchange and may heavily depend on global prices. Using weekly data from 1387 to 1396, Multifactor and VAR models are performed to analyze the variance decomposition and impulse response function of each industry to 1% price shock. In addition to global prices, some macroeconomic factors that are likely to affect stock returns are considered. The results show that commodities price shocks have dynamic and significant effects on stock returns  

Electrical arc discharge in ambient air, vacuum, reactive gas and other environment is an appropriate method for synthesis of different nanostructures. This method can provide stable and ultra pure nanostructures with diverse applications. In this research we focus on synthesis and analysis of titanium nitride nanoparticles in liquid nitrogen(lack of oxygen)by Electrical arc discharge . At the beginning a reactor for the electrical arc discharge process designed and implemented. Titanium nanoparticles have synthesis by this method analyzed. Several characterization techniques such as X-ray diffraction (XRD), dynamic light scattering (DLS), X-ray photo electron spectroscopy (XPS), scanning... 

The integration of radar and communication functionalities into a unified Joint Radar-Communication (JRC) system offers enhanced spectral efficiency and reduced hardware complexity. Recognized as a key enabler for next-generation wireless networks, JRC systems require a careful balance between radar and communication demands, where waveform design plays a pivotal role in achieving this equilibrium. Although waveform design has been extensively studied separately in radar and communication domains, the requirements of modern networks necessitate a unified approach that simultaneously addresses the needs of both systems. This thesis advances waveform design methodologies for JRC systems,... 

This thesis studied the definition of a green building and the elements associated with the construction of a green residential apartment in comparison with traditional buildings with respect to condition of Karaj city. The first step in green construction is preparing a guideline. For this, LEED (Leadership in Energy and Environmental Design) the most well-known code for green buildings is used and Adapted with Iran’s National Building Regulations. Creating a checklist to rate buildings is one of the most important parts of Green Building Regulations. To achieve the points, US LEED certification is analyzed in both qualitative and quantitative perspectives. A questioner is applied in... 

In this dissertation, the application of frequency and space diversities in radar target parameter estimation are investigated. On this basis, multi-frequency signal is used to improve the range resolution, array structure is used to increase the angle estimation accuracy and the merger of the multi-frequency signal and array structure are used to increase the maximum number of targets that can be uniquely identified.Considering the desirable properties of multi-frequency signals such as high bandwidth efficiency, high range resolution achievement without chip length decrease and …, there has been increased interest in the vast area of research on the design of such signals that has... 

Target recognition techniques based on micro Doppler phenomenon are popular because they are applicable even on low resolution radars, in contrast to other techniques such as High Resolution Range Profile (HRRP) which need high resolution in range or angle. Usually, main purpose of such techniques is generating robust features against target initial state, velocity, aspect angle, etc. rather than features which exactly identify a target. Main approaches in the literature are based on time-frequency transforms (TFT) such as spectrogram in order to generate features to classify targets, but in this thesis, we propose a totally different method using Recurrence Plot for generating features... 

In this research with Finite Element Methods in ABAQUS, numerical modeling has done in three-dimensions, which can be used to determine the effect of different factors on the surface settlement. Also, various factors such as geotechnical conditions, tunnel diameter,tunnel depth, the impact of the thickness of the segments and the amount of eccentricity of the structure relative to the longitudinal axis of the tunnel considered in this study. Face Pressure Supports, and Grout Injection Pressures are taken into account, too.Tunnel drilling causes a change in the displacement area and creates a changing zone around the tunnel. In this regard, not only adjacent buildings will be affected by... 

Proton precession magnetometers are one of the most sensitive scalar magnetic sensors. Their function is based on Zeeman effect and also nuclear magnetic resonance phenomena. In this project we have designed and implemented needed coils, swithching and signal detection circuits. Because of extremely high sensitivity of this sensor to induced noises and also gradient of earth’s magnetic fileld, detection of precession signal needs design of low noise electronic circuits with special EMC considerations. The implemented system in this project contains different blocks, such as switching circuit and its related control unit, amplifier, filter and frequency meter. Using this system, the obtained... 

Effective field theory is a practical method for model building and explaining experimental/observational data. These theories are constructed based on knowing low energy degrees of freedom and symmetries (accidental or fundamental). By construction, these theories are applicable up to a cut-off scale and their predictions beyond that are not reliable. For applications to higher energies a UV completion is needed through which modifications are applied or new heavy degrees of freedom are introduced. In order to complete a theory in a Wilsonian approach, scattering amplitudes must satisfy some constraints. These constraints are derived from basic assumptions like Lorentz invariance,... 

Nanosized CdS coupled TiO2 nanocrystals were prepared by a microemulsion-mediated Hydrothermal method at relatively low temperatures. Modification of this nanocomposite with Tyrosine,Phenylalanine,Glysine and Glutamate ,especially Tyrosine resulted in enhanced photocatalytic degradation rate of Nitrobenzene( NB ) compared to using CdS-TiO2 under visible light irradiation. The prepared samples were characterized by BET,SEM, XRD, UV–Vis spectroscopy ,FTIR .It was found which have high surface area about 470 m2 g−1 and mesoporous character with the average pore diameter of 2.8 nm.The results showed this nanocomposite consisted of uniform anatase TiO2 with highly dispersed cubic phase CdS... 

Solute-solvent and solvent-solvent interactions were investigated in mixtures of ethylammonium propionate with methanol, ethanol, isopropanol and propanol. Solvatochromic parameters, including normalized polarity ( ), polarity/dipolarizability (p*), hydrogen-bond donor (a), and hydrogen-bond acceptor (ß) abilities, were determined in these mixtures. Parameters showed synergetic effects in mixtures of ionic liquid and alcohols due to the preferential solvation. General polarity shows an ideal behavior in all mixtures, polarity/dipolarizability exhibit increasing profile in all mixtures preferential salvation caused nonideal behavior for hydrogen-bond acceptor parameter Solvent... 

Computational chemistry is used to study solvent and substituent effects on kinetics and mechanism of some organic reactions. It also is used to study enzyme reactions and enzyme structures. Organic reactions were studied by ab initio quantum mechanics and Monte Carlo simulations. The enzyme studies were done by QM/MM and MD methods in Lund University. The studied organic reactions are 1) Reactions of hydroxylamine and aminoxide anion with methyl iodide. 2) Rearrangement of allyl p-tolyl ether. 3) Reactions of 1,4-Benzoquinone with Cyclopentadiene and Cyclohexadiene derivatives and reaction of cyclopentadiene and vinyl acetate. In the enzyme studies the catalytic reaction of Glyoxalase... 

In this thesis, Fe3O4 magnetic nanoparticles were produced using co-precipitation method. The surface of these magnetic nanoparticles is modified by ionic-liquid groups, and then coated with Cu, Au and Ag metals. These nanoparticles were unstable before their surface modification, so that they were easily agglomerated. However, after their surface is modified with ionic-liquid, they become very stable and are easily solved in polar and non-polar solvents. This solubility depends on the alkyls groups connected to the ionic-liquid. Magnetic nano composites Fe3O4/X (X=Ag, Cu, Au) modified by ionic-liquid are prepared by absorbing Cu(NO3)2, HAuClO4 and AgNO3 salts on the surface of modified... 

Selective oxidation of cyclohexene and styrene were investigated using molecular oxygen under mild conditions. Au/TiO2 and Au/Al2O3 surfaces were impregnated with three different Ionic Liquids. Supported Ionic Liquids gold nanocatalysts are particularly versatile catalysts for oxidation reaction with exceptionally high efficiency and significant selectivity.
Selective oxidation of alkenes by hexadecyl-trimethyl-ammonium bromide-stabilized gold nanorods and gold nanosphere were investigated using molecular oxygen in aqueous solution under mild conditions. Colloidal gold nanoparticles are particularly versatile catalysts for oxidation reaction with exceptionally high efficiency and... 

The value added service industry as in emergent and profitable industry has gained mane attentions by corporate owners especially in the segment of telecommunication and information technology. For launching value added services, communication infrastructure must combined with attractive and high quality contents. For this purpose, mobile network operators have collaborated with content providers to launch services, cooperative advertisements and shared the earned revenue. Interaction between operators and content providers has many complex stages that starts before contract assignment and ends at the revenue sharing stage. For analysis this problem, first, we investigated this interactions... 

Thermodynamic, structural and transport properties of ester-functionalized ionic liquids (ILs), also kwon as biodegradable ILs, were extensively investigated using molecular dynamic simulation. Thermodynamics features of this class of ILs were computed from 1.5 ns simulations. Nanoscale organization of these ILs was evaluated by computing several structural properties. The formations of micelle-like nanostructures were disclosed from the achieved results of structural properties. The obtained results were also confirmed by calculating transport traits. These results suggest that the incorporation of an ester group into the alkyl side chain of the cation promotes the cation–anion interionic... 

In this work, butyl methylimidazolium tetrafluoroborate and butyl methylimidazolium hexafluorophosphate are used as ionic liquid and lithium perchlorate and lithium hexafluorophosphate as lithium salt. Dimethyl carbonate and propylene carbonate are used as solvent to prepare diffrent kinds of organic - ionic liquids solvent for lithium ion batterries. In preliminary expriment it was distinguished that in the mixture of organic solvent lithium hexaflourophosphat has more conductivity in comparison with lithium perchlorate. There for,in this work, all organic-ionic liquid solvent electrolytes are considered based on lithium hexaflourophosphat salt. Different compositions of organic-ionic... 

In this project the RGO/Ag2O/g-C3N4 nanocomposite was synthesized, and characterized by different technique such as SEM, XRD, and FT-IR. Then its photocatalytic activity was investigated. The degradation percent for Acid-Blue 92 by this photocatalyst was estimated 81 in 45 minutes. Afterward, the photocatalyst activity was determined in different pH including 4, 7, 10. The best result was for pH=7. Then, the increasing concentration of dye were investigated and the results show that by increasing the concentration of 10 to 30 ppm, the photocatlytic activity decreased. Photocatalytic degradation process of AB92 were also carried out at different amount of photocatalyst. The mechanism of... 

Coral reef waters are called rainforest. The importance of coral reef waters is related to their diversity and millions species. According to incremental development of Kish Island, specially the west part of this island contributed to Tourism industry which is affected by dredging, sediment discharge in coastal area, constructing waterfront, the flows close to the beach due to breakwater and eutrophication. This Island includes marine resources and many biodiversity .So the management of marine environment is needed to be considered. Iran as a rich country due to coral reefs is considered as a most valuable marine environment in Persian Gulf. The process of polluting Persian Gulf is...