Sharif Digital Repository

Ternary novel BiOI@MIL-88A(Fe)@g-C3N4 nanocomposite with core@shell structure was successfully synthesized by hydrothermal method. fabricated photocatalysts were characterized and results confirmed the formation of MIL-88A(Fe)@g-C3N4 core@shell structure and subsequently BiOI decoration on the surface of MIL-88A(Fe)@g-C3N4. Photocatalytic performances of prepared samples were investigated for degradation of Acid Blue 92 (AB92), Rhodamine B (RhB) and phenol under visible irradiation. It is clearly demonstrated that the as-prepared ternary BiOI@MIL-88A(Fe)@g-C3N4 composites exhibits exceptional visible-light photocatalytic activities for cationic, anionic as well as neutral pollutant molecules... 

Bi-evaporator electricity/cooling cogeneration systems can be a favorable addition to the integrated power plants since the generated cooling load should be addressed for different demands. More consequentially, taking advantage of such an integral set-up operated with highly reliable heat source such as biogas can be appreciable for nowadays industries. Regarding this demand, an innovative bi-evaporator electricity/cooling cogeneration system is introduced at first. Next, the suggested system is integrated with a gas turbine cycle fueled by biogas. In the subsequent part, the plausibility of the introduced integrated power plant is examined from first and second laws of thermodynamics (as... 

An innovative bi-evaporator electricity/cooling cogeneration system fueled by biogas is introduced. The plausibility of the introduced integrated power plant is examined from thermodynamic and economic vantage points. Later, single- and multi-objective optimization of the reckoned system are achieved by selecting appropriate parameters as decision variables and thermal and exergy efficiencies and total unit product cost (TUPC) of the system as objective functions. Four optimum modes of thermal efficiency optimum design (TEOD), exergy efficiency optimum design (EEOD), cost optimum design (COD), and multi-objective optimum design (MOOD) are selected for optimization and the attained results... 

The nanocomposite of g-C 3 N 4 supported by MIL-88A has been prepared via a facile hydrothermal method. The photocatalytic performance of as-prepared composite (MIL-88A/g-C 3 N 4 ) was examined by the degradation of the Methylene Blue (MB) solution under visible light. The characterization test illustrated that the MIL-88A particles were successfully dispersed on the surface of g-C 3 N 4 structure. Photoactivity results demonstrated that the MIL-88A/g-C 3 N 4 /H 2 O 2 exhibited dramatically visible light photocatalytic performance. Hydroxyl radicals ([rad]OH) are generated by dissociation of H 2 O 2 under visible irradiation can remarkably enhance the degradation rate of MB molecules.... 

In this study, we synthesized novel visible light photocatalyst MIL-88A/BiOI using depositing BiOI particles on the surface of a metal–organic framework (MIL-88A). Photocatalytic application of binary composite MIL-88A/BiOI was obtained by discoloration of Methylene Blue (MB) and Acid Blue 92 (AB92) in aqueous solution under visible light source. The photodegradation experiments for treating organic dyes show that the MIL-88A/BiOI heterojunction structure possess a higher rate for decomposition of dyes due to the decreased aggregation of the BiOI nanoparticles, effective charge carrier separation and the synergistic effect between MIL-88A and BiOI samples as a heterojunction. Also, the... 

Despite the fact that humidification-dehumidification (HDH) desalination systems can be driven by various renewable or waste heat energies, many of the available renewable technologies are expensive in some parts of the globe. Hence, proposing and developing high-efficient mechanical-based HDH units can be an encouraging alternative which is more highlighted in recent investigations. In pursuance of this objective, three innovative mechanical-driven HDH units are simulated and the results are compared with each other. The simulated hybrid desalination system consists of a HDH unit and an ethane ejector expander transcritical refrigeration cycle (ethane-EETRC). The simulated hybrid systems... 

Among different types of geothermal processing used in the energy conversion systems, flash-binary geothermal can be the best scenario for high-temperature geothermal sources. Reviewing the available literature it can be found that the flash-binary geothermal power plants have a great potential to be extended to trigeneration systems, nonetheless they have received less attention. In this regard, a new trigeneration system for freshwater, power, and cooling production is devised using a flash-binary geothermal heat source at 170°C. In this devised trigeneration system, a humidification-dehumidification (HDH) unit is used as a binary cycle. Another merit of the devised trigeneration system is... 

Anaerobic fermentation of crop straw/animal dug can be the most appropriate solution for biomass conversion into applicable renewable energy-based fuels. However, due to the imperfection matching between the biogas combustion process and energy conversion system, a painstakingly design procedure is required to devise high-efficient energy system for capturing biogas efficiently. For this aim, a new trigeneration system driven by biogas is devised for electricity, refrigeration, and potable freshwater generation. The devised system encompasses a gas turbine (GT) cycle, a new cooling/electricity cogeneration system based on organic Rankine cycle (ORC) and ejector cooling cycle (ECC), and a... 

In this research, low density polyethylene (LDPE) and poly ethylene-co-vinyl acetate (EVA) were used as polymeric materials. The methods used to produce LDPE and EVA was Film Blowing and ThermalDry Phase Inversion. The amount of permeability, diffusivity and solubility of O2 and CO2 through above polymers were obtained and also the effect of temperature, pressure and film thickness for LDPE was measured. The Barometric method was considered and measurements were based on ASTM standard. To study film cross-section morphology in EVA, Scanning Electron Microscopy (SEM) was applied. From results we considered that the amount of permeability and solubility were decreased by increasing film... 

One of the most conventional and energy efficient methods to improve the engineering properties of concrete is the utilization of waste materials and by-products. Among agricultural wastes, rice husk ash (RHA) has exhibited the greatest potential to enhance the characteristics of cement mixtures. However, the investigations on the properties and performance of RHA are slim compared to its potential advantages and few systematic studies can be found in the literature regarding parameters influencing the chemo-physical and microstructural characteristics of RHA along with its performance in cement mixtures. In this study, the effect of retention time of rice husk is systematically... 

Caspian Sea is currently a subject of one of the world's most intractable disputes, involving five coastal states of Azerbaijan, Iran, Kazakhstan, Russia, and Turkmenistan. The conflict over the legal status of this multinational water body emerged after the collapse of the Soviet Union. Since then the parties have been negotiating without reaching an agreement on the ownerships of waters, and the oil and natural gas beneath them. Although different division methods have been suggested so far for sharing the Caspian Sea, the gains of the countries from sea area and valuable resources remain unclear as the proposed methods are either focused on the areal shares or on the oil and gas shares.... 

An environmentally friendly heterogeneous ternary carbon dots (CDs)/MIL-88B (Fe)/Bi2S3 nanocomposite was synthesized by a multistep method. In this study, we have studied low-temperature calcination with relatively inexpensive reactants. The sufficient CD arrays were generated by loading the glucose molecules into the pores of an as-obtained metal-organic framework (MOF), i.e. MIL-88B (Fe)), by heating to 200 °C. Fabricated nanocomposite structures were characterized by FT-IR, XRD, EIS, SEM, TEM, BET, and TGA techniques, demonstrating the decoration of the Bi2S3 on the CDs/MIL-88B (Fe) nanocomposite surface. MOF templating has been chosen as a systemic method for limited size CD formation... 

In this research, low density polyethylene (LDPE) and poly(ethylene-co-vinyl acetate) (EVA) were used as polymeric materials. The methods used to produce LDPE and EVA was film blowing and thermal-dry phase inversion. The amount of permeability, diffusivity and solubility of O2 and CO2 through above polymers were obtained and also the effect of temperature, pressure and film thickness for LDPE was measured. To study film cross-section morphology in EVA, scanning electron microscopy (SEM) was applied. The results showed that the amount of permeability and solubility were decreased by increasing film thickness but diffusivity was increased. However, by increasing temperature, permeability,...