Sharif Digital Repository

Ternary novel BiOI@MIL-88A(Fe)@g-C3N4 nanocomposite with core@shell structure was successfully synthesized by hydrothermal method. fabricated photocatalysts were characterized and results confirmed the formation of MIL-88A(Fe)@g-C3N4 core@shell structure and subsequently BiOI decoration on the surface of MIL-88A(Fe)@g-C3N4. Photocatalytic performances of prepared samples were investigated for degradation of Acid Blue 92 (AB92), Rhodamine B (RhB) and phenol under visible irradiation. It is clearly demonstrated that the as-prepared ternary BiOI@MIL-88A(Fe)@g-C3N4 composites exhibits exceptional visible-light photocatalytic activities for cationic, anionic as well as neutral pollutant molecules... 

Bi-evaporator electricity/cooling cogeneration systems can be a favorable addition to the integrated power plants since the generated cooling load should be addressed for different demands. More consequentially, taking advantage of such an integral set-up operated with highly reliable heat source such as biogas can be appreciable for nowadays industries. Regarding this demand, an innovative bi-evaporator electricity/cooling cogeneration system is introduced at first. Next, the suggested system is integrated with a gas turbine cycle fueled by biogas. In the subsequent part, the plausibility of the introduced integrated power plant is examined from first and second laws of thermodynamics (as... 

An innovative bi-evaporator electricity/cooling cogeneration system fueled by biogas is introduced. The plausibility of the introduced integrated power plant is examined from thermodynamic and economic vantage points. Later, single- and multi-objective optimization of the reckoned system are achieved by selecting appropriate parameters as decision variables and thermal and exergy efficiencies and total unit product cost (TUPC) of the system as objective functions. Four optimum modes of thermal efficiency optimum design (TEOD), exergy efficiency optimum design (EEOD), cost optimum design (COD), and multi-objective optimum design (MOOD) are selected for optimization and the attained results... 

The nanocomposite of g-C 3 N 4 supported by MIL-88A has been prepared via a facile hydrothermal method. The photocatalytic performance of as-prepared composite (MIL-88A/g-C 3 N 4 ) was examined by the degradation of the Methylene Blue (MB) solution under visible light. The characterization test illustrated that the MIL-88A particles were successfully dispersed on the surface of g-C 3 N 4 structure. Photoactivity results demonstrated that the MIL-88A/g-C 3 N 4 /H 2 O 2 exhibited dramatically visible light photocatalytic performance. Hydroxyl radicals ([rad]OH) are generated by dissociation of H 2 O 2 under visible irradiation can remarkably enhance the degradation rate of MB molecules.... 

In this study, we synthesized novel visible light photocatalyst MIL-88A/BiOI using depositing BiOI particles on the surface of a metal–organic framework (MIL-88A). Photocatalytic application of binary composite MIL-88A/BiOI was obtained by discoloration of Methylene Blue (MB) and Acid Blue 92 (AB92) in aqueous solution under visible light source. The photodegradation experiments for treating organic dyes show that the MIL-88A/BiOI heterojunction structure possess a higher rate for decomposition of dyes due to the decreased aggregation of the BiOI nanoparticles, effective charge carrier separation and the synergistic effect between MIL-88A and BiOI samples as a heterojunction. Also, the... 

Despite the fact that humidification-dehumidification (HDH) desalination systems can be driven by various renewable or waste heat energies, many of the available renewable technologies are expensive in some parts of the globe. Hence, proposing and developing high-efficient mechanical-based HDH units can be an encouraging alternative which is more highlighted in recent investigations. In pursuance of this objective, three innovative mechanical-driven HDH units are simulated and the results are compared with each other. The simulated hybrid desalination system consists of a HDH unit and an ethane ejector expander transcritical refrigeration cycle (ethane-EETRC). The simulated hybrid systems... 

Among different types of geothermal processing used in the energy conversion systems, flash-binary geothermal can be the best scenario for high-temperature geothermal sources. Reviewing the available literature it can be found that the flash-binary geothermal power plants have a great potential to be extended to trigeneration systems, nonetheless they have received less attention. In this regard, a new trigeneration system for freshwater, power, and cooling production is devised using a flash-binary geothermal heat source at 170°C. In this devised trigeneration system, a humidification-dehumidification (HDH) unit is used as a binary cycle. Another merit of the devised trigeneration system is... 

Anaerobic fermentation of crop straw/animal dug can be the most appropriate solution for biomass conversion into applicable renewable energy-based fuels. However, due to the imperfection matching between the biogas combustion process and energy conversion system, a painstakingly design procedure is required to devise high-efficient energy system for capturing biogas efficiently. For this aim, a new trigeneration system driven by biogas is devised for electricity, refrigeration, and potable freshwater generation. The devised system encompasses a gas turbine (GT) cycle, a new cooling/electricity cogeneration system based on organic Rankine cycle (ORC) and ejector cooling cycle (ECC), and a... 

In modeling and designing micro combined heat and power cycle most important point is recognition of how the cycle operates based on the first and second laws of thermodynamics simultaneously. Analyzing data obtained from thermodynamic analysis employed to optimize MCHP cycle. The data obtained from prime mover optimization has been used for basic stimulus cycle. Assumptions considered for prime mover optimization has been improved, for example in making optimum operation condition by using genetic algorithms constant pressure combustion chamber was considered. The exact value of downstream and upstream pressure changes in the combustion chamber reaction has been obtained. After extraction... 

Evapotranspiration is one of the main components of water and energy balance. In this study, we compare two ET products, suitable for regional analysis at high spatial resolution: The recent WaPOR product developed by FAO and METRIC algorithm. WaPOR is based on ETLook, which is a two-source model and relies on microwave images. WaPOR is unique as it has no limitation under cloudy days, but METRIC is limited by clouds. METRIC and WaPOR are more sensitive to land surface temperature and soil moisture, respectively. Using two years (2010 and 2014) of data over Lake Urmia basin, we show that in most areas, ET from METRIC is higher than WaPOR and the difference has an ascending trend with the... 

The heterogeneous environmentally friendly catalyst and photocatalyst based on Ag, Pt, Ag–Pt nanoparticles (NPs) loading on the γ-Fe2O3/CuO nanocomposite which was derived from Fe-metal organic framework (Fe-MIL-88B) and Cu-metal organic framework (Cu (tpa)) was introduced. The catalytic and photocatalytic activities of Ag–Pt loading on the γ-Fe2O3/CuO nanocomposite were performed for a reduction process (4-nitrophenol (4-Nip) to 4-aminophenol (4-Amp)), and decomposition organic dyes (AB92, MB) in the LED light. Metal-organic framework (MOFs) composed with inorganic and organic linker which used as suitable precursors to obtain different type of nanostructures for environmental applications.... 

Urmia Lake River Basin (ULRB) is one of the most important habitats in the world and one of the major agricultural regions in Iran. On average, the ratio of irrigation to evapotranspiration in this basin is more than 73%. Investigating the irrigation water requirement pattern changes and the spatial distribution of evapotranspiration during the basin development period on a regional scale play important roles in understanding the basin situation. In this study, the actual evapotranspiration has been estimated by SEBAL model. By estimating the precipitation distribution in the basin, the agricultural irrigation water requirement pattern has been calculated using the land use map in 1995, 2010... 

Herein, a novel quaternary Ag3PO4/BiPO4@MIL-88B(Fe)@g-C3N4 (AB@MIL-88B(Fe)@g-CN) nanocomposite with a core@shell structure is successfully fabricated in two simple steps. The prepared samples are characterized via various techniques. The photocatalytic activity of the prepared samples is evaluated by the degradation of navy Acid Blue 92 (AB92) dye as an organic pollutant under visible light irradiation. Highly enhanced photocatalytic efficiency is observed for the quaternary AB@MIL-88B(Fe)@g-CN nanocomposite compared to that for the other samples. The experimental results indicate that the photocatalytic activity enhancement is mainly attributed to the strong visible light absorption and... 

A highly selective and effective catalyst and photocatalyst based on Ag, Pt, AgPt nanoparticles (NPs) on the surface of γ-Fe2O3 /t-ZrO2 nanocomposite which was derived from Fe-metal organic framework (Fe-MIL-88A) and Zr-metal organic framework (Zr-UiO-66) was developed. A green synthesis method was used for synthesis of binary nanocomposite (M = Ag, Pt, and Ag@Pt NPs)@γ-Fe2O3/t-ZrO2 and a new composite of γ-Fe2O3, t-ZrO2 structures which was made up by annealing under a nitrogen gas flow. The catalytic potential of the as-synthesized samples were considered toward the reduction of 4-nitrophenol (4-Nip) to 4-aminophenol (4-Amp) by NaBH4 solution at 25 °C and different reaction times. For the... 

Introduction: The Coronavirus disease 2019 (COVID-19) pandemic has caused irreparable damage to the world. In order to prevent the spread of pathogenicity, it is necessary to identify infected people for quarantine and treatment. The use of artificial intelligence and data mining approaches can lead to prevention and reduction of treatment costs. The purpose of this study is to create data mining models in order to diagnose people with the disease of COVID-19 through the sound of coughing. Method: In this research, Supervised Learning classification algorithms have been used, which include Support Vector Machine (SVM), random forest, and Artificial Neural Networks, that based on the standard... 

In this research, low density polyethylene (LDPE) and poly ethylene-co-vinyl acetate (EVA) were used as polymeric materials. The methods used to produce LDPE and EVA was Film Blowing and ThermalDry Phase Inversion. The amount of permeability, diffusivity and solubility of O2 and CO2 through above polymers were obtained and also the effect of temperature, pressure and film thickness for LDPE was measured. The Barometric method was considered and measurements were based on ASTM standard. To study film cross-section morphology in EVA, Scanning Electron Microscopy (SEM) was applied. From results we considered that the amount of permeability and solubility were decreased by increasing film...