Sharif Digital Repository

Nanophotocatalysts containing metal oxides and oxy-acids based on the nanoporous materials such as graphene, metal-organic-frameworks and carbon nano tubes were synthesized. The photocatalytic properties of the prepared samples were evaluated by the photodegradation of different pollutants in the suspension and emulsion photocatalytic systems. This study demonstrates a new kind of photocatalytic system via utilization of the superior specific properties inherent in Pickering emulsion. We designed the new photocatalytic system using a photocatalytic active component and hydrophobic conducting nanostructures to form the stabilized Pickering emulsion (Pe-bp system). The results revealed that... 

In the preceding years, hydroxyapatite (HA)-based coatings and scaffolds have been known as the best biomaterials for dental and orthopedics applications. Biocompatible and bioactive hydroxyapatite-based Coatings on metallic implants is one of the best methods for reaching both suitable mechanical properties and appropriate bioactivity, leading to better osseointegration and osteoblast proliferation. The ultimate goal of this project is characterization as well as mechanical and electrochemical behavior investigation of Hydroxyapatite- Chitosan nanocomposite coating by electrophoretic deposition (EPD) method on Plasma Electrolyte Oxidation (PEO) treated titanium substrates and Magnesium (Mg)... 

Titanium anodes activated by noble metal oxides under the trade name of dimensionally stable anodes (DSAs) are widely used in the electrolytic industry, particularly in chlor – alkali electrolysis. Over 20 years of use, the fundamental aspects of their long – lasting performance are not fully understand and the corrosion mechanisms are still the subject of many investigations. RuO2 – TiO2 coatings on titanium substrate, due to proper electrochemical characteristics and good corrosion resistance, is most applicable as an anode in chlor – alkali systems. In the present investigation, the first layer of Pt – Ir coating is applied via electrodeposition method on the pretreated titanium substrate... 

In control engineering we want to set dynamic behavior of the system to a desired one and having a model that simulate systems behavior is necessary . System identification is a branch of chemical engineering that provide us this model , which divided into different branches itself . In this project we use object oriented programming to design and implement a software that support black box models such as Neural networks in addition to Mechanistic models (Which was implemented in previous project ) for identification . We use UML and C++ language in C++ Borland Builder in this project  

Let G be a graph with adjacency matrix A and Δ be a diagonal matrix whose diagonal entries are the degree sequence of G. Then the matrices L = Δ− A and Q = Δ+A are called Laplacian matrix and signless Laplacian matrix of G, respectively. The eigenvalues of A, L, and Q are arranged decreasingly and denoted by λ1 ≥ · · · ≥ λn, μ1 ≥ · · · ≥ μn ≥ 0, and q1 ≥ · · · ≥ qn ≥ 0, respectively. The energy of a graph G is defined as E(G) :=
n
i=1
|λi|.
Furthermore, the incidence energy, the signed incidence energy, and the H¨uckel energy of G are
defined as
IE(G) :=
n
i=1
√
qi, LE(G) :=
n
i=1
√
μi, HE(G) :=

2
r
i=1 λi, n=... 

Composite coatings including self-lubricant particles such as graphite, MoS2, Al2O3 and SiC are extensively used to decrease the coefficient of friction of tribo-surfaces. Adding lubricant particles to an appropriate metallic matrix like copper, nickel, lead and their alloys is a suitable option in severe condition –for instance high temperature and low pressure- which liquid lubricants will be failed. Bronze can give various properties such as wear resistance, corrosion and oxidation protection, However cyanide solutions for electroplating process have environmentally limited for plating of Cu-Sn. In this research, a chloride electrolyte for bronze electroplating was developed and effect of... 

Main aim of this work was to obtain the harder zinc coating and increasing the anti corrosive properties by mean of adding SiO2 particles by electrophoretic method.
The coating was applied on the substrate surface by mean of electro co-deposition technique in three different electrolytes ethanol, methanol and water. The morphology of the coating in each electrolyte studied by scanning electron microscope (SEM).For the Zn/SiO2 coatings achieved in ethanol solvent the polarization and EIS tests was took place and found that for the Zn/SiO2 coating contain less than 10% SiO2 the corrosion rate decreased but for the coatings contains more than 10% SiO2 the paradox occurred because of the... 

In nanometer technologies, the effect of process variation is observed in Multi-Processor System on Chip (MPSoC) in terms of variation in processors‟ frequency and leakage power. Traditionally, only worst case values of the system parameters were concerned and a worst-case optimization algorithm was employed for an application under design. As previous researches have shown these algorithms are not optimal in terms of parametric yield compared with newly employed statistical optimization algorithms. In this project, we have considered the problem of simultaneously selecting MPSoC architecture (which includes type and number of processors and the communication media) and task and... 

Ni-SiC composite coatings are widely used in industry (equipment high wear resistance coatings, corrosion resistant coatings, ship and boiler coatings, . . . ). Its unique properties in high wear resistance, corrosion resistance and tribological properties, researchers tend to investigate this coating. This study covers Ni-SiC composite coating under pulsed current using a rotating disk electrode to achieve optimal conditions in synthsis process, increaseing hardness and resistance to corrosion in coatings.waats' bath established for electrodeposition in this research. Bath parameters, current parameters and hydrodynamic of solution is examined. Changing of current type from direct current... 

At the first stage, chitosan-hydroxyapatite-multiwalled carbon nanotube (CH-HA-MWCNT) composite coatings were synthesized by electrophoretic deposition technique (EPD) on Ti6Al4V and 316L stainless steel substrates at different levels of pH and characterized by X-ray diffraction (XRD), Raman spectroscopy, FTIR and field emission scanning electron microscopy (FESEM). A smooth distribution of HA and MWCNT particles in a chitosan matrix with strong interfacial bonding was obtained. At the second stage, effect of pH and MWCNT content of the suspension on corrosion behavior and mechanism of deposition were studied. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS)... 

This thesis is concerned with the synthesis and characterization of high porous Ti based on thin films and the effect of polymer agents on their photocatalytic properties. Ti films can demonstrate different properties like self -cleaning and treatment of broad range of aqueous pollutants when it is exposed to light of wavelength less than 400 nm. This is due to photocatalytic reaction occurring on film surface which results in film superhydrophilicity and the active oxygen species production. This active sites and radicals will cause oxidize organic pollutants and microbe adherent to the material surface.
In this study Ti thin films have been prepared by the sol-gel method from... 

In this thesis, optimal station keeping of spacecraft on the closed-orbits near the Earth-Moon Lagrange points has been investigated. Lagrange points L1 and L2 are unstable equilibrium points of the circular restricted three-body problem (CRTBP), and periodic orbits near them are the destination of modern missions. However, perturbations resulting from the gravitational forces of the Sun and the planets and the eccentricity of the orbit of the Moon around the Earth make the Lagrange point unstable, even L4 and L5, which are stable in CRTBP. The most suitable choice for spacecraft mission near the collinear Lagrange points is the Halo and other closed-orbits around them, which need... 

Improving the photocatalytic activity of titania nanoparticles and Cognition the mechanisms governing this property, has received more attention in the recent few years. One of the main strategies for improving the photocatalytic activity and modifying the bandgap structure of titania nanoparticles, is incorporation different metallic and nonmetallic ions in the titania lattice. In this study, 1%Fe, 1%Gd and 2%P (molar ratio) doped titania nanoparticles were successfully prepared by a modified sol-gel method in room temperature. The products were characterized with various spectroscopic and analytical techniques to determine their structural, morphological, physicochemical and... 

Corrosion is caused through chemical interactions between metal and gases in the surrounding environment. Conductive polymers are used for corrosion protection, polyaniline is the most environmentally stable out of all the conductive polymers, the most studied of this materials, is highly stable, synthesized easily, highly conducting, and readily converted between its various oxidation states.
In this study we prepared nanoporous polyaniline coating on carbon steel to corrosion protection. Coating was included nanopouros polyaniline with doping molybdate (PANI-MoO_4^(-2)). To increase adhesion between steel and PANI-MoO_4^(-2) layer, oxalic acid was used. Polystyrene nanoparticle layer... 

Titania is one of the photocatalytic materials , but low quantum yield and relatively high band gap of TiO2 limited its applications.There are several ways to improve the photocatalytic properties of this material relied on narrowing the band gap,by doping TiO2 with other metals and oxides or increasing its specific surface area.In this work ,TiO2-SiO2-Ni coating have been made by sol-gel process and deposited on quartz substrate by using of dip-coating method .Effect of increasing Nickel content in nanocomposite and primary sol on crystalline structure,morphol ogy, photocatalytic properties and specific surface area have been investigated by means of X-Ray diffraction method, FT-IR, SEM,... 

Keyword spotting with high speed and accuracy is an important subject whithin speech processing domain especially when we are dealing with various transmission channels. In this research discriminative keyword spotting methods are compared with HMM-based approaches. We have employed the discriminative approaches as our baseline methods due to their higher accuracy. The drawback of the conventional discriminative methods is their high computation cost and long execution time. The discriminative approach consists of two steps: feature extraction and classification. We have proposed four ideas to improve the performance of the baseline method. To improve the speed of the process, in feature... 

The synthesis and usage of TiO2/ZnO nanocomposite thin film in antibacterial activity against E-coli were experimented through a systematic research. TiO2/ZnO nanocomposite films can demonstrate different properties like gas sensing, self cleaning and treatment of the broad range of aqueous pollutants when it is exposed to light with wavelengths less than 400 nm. This phenomenon happens because of the photocatalytic reactions in the nanocomposite thin film which cause active species production on the surface of the thin film. The nanocomposite synthesis was based on sol-gel process in atmospheric pressure. In this study titanium dioxide is prepared by sol gel method from titanium... 

In recent decade, photocatalystic properties of titania nanotube and its mechanisms has been considered greatly in many researches. One of the major ways to increase photocatalystic properties and extending the usage of TNTs is doping them with various elements and modifying their band structure. In present research doped TNTs were prepared by doping of Molybdenum, Nitrogen, and Carbon elements by anodizing method in about of 35 degrees of centigrade and constant voltage of 20V on the surface of titanium sheet. Structural and photocatalystic properties of as-prepared TNTs were studied using field emission scanning electron microscope (FESEM), x-ray diffraction (XRD), energy dispersive... 

In this study, ternary metal oxide coating consisting of Ti, Ru, Ir were prepared by sol-gel method. In order to achieve optimal conditions, the effect of number of layers, temperature and velocity of the heat treatment, the amount of ruthenium and iridium, polymeric additive on the coating and also, comparisons of binary and ternary oxide coatings were studied. The corrosion behavior was examined by anodic polarization and cyclic voltammetry tests and accelerated stability test (AST), the morphology of coatings was studied by field emission scanning electron microscopy (FESEM), phase and elemental analysis was performed using X-ray diffraction (XRD) and energy dispersive spectroscopy... 

In recent years, magnesium and its alloys have been considered as biodegradable implants, but they corrode in the body before natural process of damaged organs recovery is completed. In this investigation PEO operation was used for corrosion control and effect of different parameter such as number of operation steps, electrolyte type, time and operation voltage on coating properties was studied. Scanning electron microscopy was used for investigating of morphology of coats and to determine chemical composition and phase of coats EDS analysis and X-ray diffraction were used. The corrosion resistance of samples were evaluated by potentiodynamic polarization and electrochemical impedance (EIS)...