Sharif Digital Repository

In this study, the values of the surface tension for a number of single aqueous electrolyte solutions were measured at various temperatures and electrolyte concentrations using the well-known and computer-aided pendant-drop method. In order to conduct the experimental measurements, a high-pressure IFT-700 apparatus, equipped with a view cell and a data acquisition system, was used. The systems studied in this study were aqueous solutions of KCl, NaCl, CaCl 2, and Na 2SO 4. The pooled standard deviation and the confidence limit of the surface-tension data for a 95 % confidence level were determined to be 0.17mN · m -1 and σ̄ ± 0.19, respectively. It should be noted that while the surface... 

In this work, PC-SAFT, an equation of state based on perturbation theory, is applied to predict the reservoir fluids phase behavior. PC-SAFT parameters for pure components have previously been assessed, but they cannot be determined for petroleum fractions with unspecified components and composition. In order to remove this difficulty and making use of PC-SAFT model in the reservoir fluids simulations, a new approach is studied which leads to appearing generalized correlations for the estimation of PC-SAFT parameters for petroleum cuts and plus fractions using only their molecular weight and specific gravity, without the essential need for the characterization of petroleum fractions in... 

Experimental values for surface tension of single and mixed electrolyte solutions were correlated using the models based on the perturbation theory. The Mean Spherical Approximation (MSA) model, coupled with the Ghotbi-Vera (GV) and the Mansoori et al. (BMCSL) equations of state, were used to correlate the experimental values of the surface tension. The results showed that the models can favourably correlate the experimental values for single electrolyte solutions. However, it was observed that the GV-MSA model can more accurately predict the surface tension for single electrolytes, especially at higher concentrations. Two different expressions for concentration dependency of cation hydrated... 

The results of the minimum miscibility pressure (MMP) determination for miscible injection of CO2 and an associated gas of one of Iranian gas reservoirs into two different oil samples using a slim tube device are presented. For an effective determination of the MMP cell-to-cell slim tube simulation was performed for each case before performing the slim tube experiment and the results were used to determine the pressure intervals in the slim tube experiment. A comparison between the measured MMP values from the slim tube experiments and those calculated by cell-to-cell simulation revealed that the cell-to-cell simulation can be a substitute to slim tube test in cases where time is a primary... 

The aim of the present work is to evaluate the effect of fractures geometrical properties such as orientation, density, location, and networking on the conventional fire flooding (CFF) process performance through simulation analysis. Combustion parameters of a fractured low-permeable carbonate heavy oil reservoir in Iran called Kuh-E-Mond (KEM); applied for simulation study and simulator has been validated with KEM combustion tube experimental data. The validated model was modified to study CFF in 3D semi-scaled combustion cells. Simulation results confirmed that CFF is more feasible in the case of densely fractured reservoirs such as those in the Middle East  

Toe to heel air injection has been studied on non-fractured sandstone models and is found to be a promising enhanced oil recovery method for certain heavy oil reservoirs, such as those in Canada, but its applicability on fractured reservoirs, such as those in the Middle East, is not investigated yet. The objective of this article is to evaluate the effect of fractures geometrical parameters, such as fracture density, orientation, and location, on the performance of the process in laboratory scale. Simulation results showed that toe-to-heel air injection is more applicable on highly networked fractured reservoirs, such as those that occur in Persian Gulf coast compared to lower density... 

Equations of state based on the statistical associating fluid theory for potentials of variable range (SAFT-VR) and the perturbed chain statistical associating fluid theory (PC-SAFT) have been used to model the PVT behavior of ionic liquids and the solubility of H2S in six imidazolium-based ionic liquids. The studied systems included [bmim][PF6], [hmim][PF6], [bmim][BF4], [hmim][BF4], [bmim][NTF2] and [hmim][NTF2] at various temperatures and pressures.For pure components, parameters of the models have been obtained by fitting the models to experimental data on liquid densities; the average relative deviation between the calculated and experimental densities for ionic liquids is less than... 

The Conventional Fire Flooding (CFF) process application feasibility on fractured carbonated reservoirs remained questionable. In this paper first combustion parameters and reaction kinetics of a naturally fractured low permeability carbonated heavy oil reservoir in Iran called Kuh-E-Mond applied to simulation study. After that, simulator has been validated with Kuh-E-Mond combustion tube experiment. Recovery mechanism in single block matrix is different from one in conventional model since oxygen first flows into the fractures and then diffuses from all sides into the matrix. Combustion of the oil in the fractures produces some water ahead of fracture combustion front which prohibits oxygen... 

Acidizing is one of the most effective techniques to remove the formation damage and restore (or even increase) the permeability of the near wellbore region. Although this technique is widely used to resolve the skin problem, it could initiate new damages itself that hinder the fluid flow and decrease the well production, consequently. Acid-oil emulsion and sludge formation are known as two major induced formation damage and the main reasons for the oil well acid treatment failures. Despite its critical effects, no comprehensive study has been addressed this specific type of formation damages in details. In this study, the acid-oil emulsion and asphaltic sludge formation were evaluated... 

Amine-functionalized MIL-101(Cr) has been synthesized by hydrothermal (MNH2) and post-synthetic modification (MNH2-p) approaches. Pd/MNH2 and Pd/MNH2-p have been tested in CO oxidation reaction as a gas phase reaction to clarify the difference between two synthesis approaches. Their performance has also been compared with that of Pd supported on MIL as a common MOF and CuBTC as a commercial one. The results show the significant difference between Pd/MNH2-p and Pd/MNH2, where CO conversion of 100% was not observed for Pd/MNH2-p, whereas Pd/MNH2 outperformed the others and exhibited the high reaction rate thanks to the active sites created by amorphization during the reduction process because... 

In this work, the Ion Pair Modified Ghotbi-Vera Mean Spherical Approximation (IP-MGV-MSA) model was proposed to correlate the mean ionic activity coefficients (MIAC) for a number of symmetric and asymmetric aqueous electrolyte solutions at 25 °C. The new model is based on the recently proposed MGV-MSA model by Mortazavi-Manesh et al. In the IP-MGV-MSA model, the effects arising from the ion pair formation in the electrolyte solution was taken into account. Also, in the proposed model, while the cation diameter as well as the relative permittivity of water was considered to be dependent on electrolyte concentration, the anion diameter was independent of electrolyte concentration. The results... 

For the first time, the effect of calcination process on characteristics and catalytic performances of Pd supported on different MOFs (MIL-101(Cr), NH2-MIL-101(Cr), and HKUST-1) was evaluated. Besides, the various orders of calcination process and reduction one on Pd/MOF and Pd/calcinated-MOF were studied, and their performances in CO oxidation reaction were presented to find the effect of H2 and O2. Results showed that the effect of calcination and reduction processes on the catalytic activities and characteristics strongly depends on the nature of MOF. Among MIL-based catalysts, the catalyst with no calcination treatment showed the best activity. Among MNH2-based catalysts, high activity... 

In this work a modified form of the Ghotbi-Vera Mean Spherical Approximation model (MGV-MSA) has been used to correlate the mean ionic activity coefficients (MIAC) for a number of symmetric and asymmetric aqueous electrolyte solutions at 25 °C. In the proposed model the hard sphere as well as the electrostatic contributions to the MIAC and the osmotic coefficient of the previously GV-MSA model has been modified. The results of the proposed model for the MIAC of the electrolyte solutions studied in this work are used to directly calculate the values of the osmotic coefficients without introducing any new adjustable parameter. In the MGV-MSA model the cation diameter as well as the relative... 

For the first time, the effect of calcination process on characteristics and catalytic performances of Pd supported on different MOFs (MIL-101(Cr), NH2-MIL-101(Cr), and HKUST-1) was evaluated. Besides, the various orders of calcination process and reduction one on Pd/MOF and Pd/calcinated-MOF were studied, and their performances in CO oxidation reaction were presented to find the effect of H2 and O2. Results showed that the effect of calcination and reduction processes on the catalytic activities and characteristics strongly depends on the nature of MOF. Among MIL-based catalysts, the catalyst with no calcination treatment showed the best activity. Among MNH2-based catalysts, high activity... 

The solubility of CO2 in the systems of CO2 + benzene, CO2 + n-hexane, and CO2 + toluene was meticulously measured at (293.15, 298.15, and 308.15) K and different pressures using a pressure-volume-temperature (PVT) apparatus. Also the effect of pressure on the solubility of CO2 in the organic solvents used in this work was investigated. The Peng-Robinson equation of state (PR EOS) with only one temperature-independent binary interaction parameter was used in correlating the experimental data. The results showed that the PR EOS can accurately correlate the experimental data for the solubility of CO2 in the organic solvents at high pressure. In case of the systems CO2 + benzene and CO2 +... 

In this work the Ghotbi-Vera mean spherical approximation (GV-MSA) model, coupled with two different expressions for the cation-hydrated diameters, was used in predicting the mean ionic activity coefficients (MIAC) of electrolytes for a number of the mixed-solvent and mixed-salt electrolyte solutions at 25 °C. In all cases the cation diameters in solutions changed with concentration of electrolyte while the anion diameters were considered to be constant and equal to the corresponding Pauling diameters. In application of the GV-MSA model to the electrolyte systems, two different expressions were used for concentration dependency of cation-hydrated diameters, i.e., the GV-MSA1 and GV-MSA2... 

In this research work, Friction Theory and Free Volume Theory are applied to live oil characterized based on SARA TEST for viscosity modeling and make a new model in combination with two equation of state (PR and PC-SAFT). Parameters for pseudo-components are obtained by tuning the viscosity at atmospheric pressure and temperatures of 10, 20, and 40 ℃. A new fitting approach is suggested where the number of fitting parameters is 17 and 12 for FT and FVT model, respectively. These parameters are tuned using the Genetic Algorithm and Particle Swarm Optimization and make eight new models. The results show that PC-SAFT provides viscosity predictions for all models with less deviation from... 

In this work, the thermodynamic behavior of aqueous solutions containing the solutes NaCl, glucose, and/or urea is investigated. These substances are vital components for living bodies and further they are main components of blood serum. Osmotic coefficients were determined by cryoscopic measurements in single-solute and multi-solute aqueous solutions containing salts (NaCl, KCl, CaCl2), glucose, and/or urea. The results show that NaCl determines the osmotic coefficients in the urea/glucose/NaCl/water system. Investigation of the effect of different salts on osmotic coefficients revealed ion-specific effects. At physiologically important solute concentrations in typical blood serum... 

Till now, no mathematical model is presented to model the flow under sonic field be applied in fractured reservoirs. This will be more noticeable when we bear in mind that several reservoirs in Middle East region are fractured. In this work the effects of elastic waves on capillary trapping and mobility of Bingham plastic fluids in fractures have been investigated. Eventually, a model for predicting the influence range of the wave in fractured reservoirs is presented. The results of this study clarified that radiation of wave with low frequency and intensity extremely increases the flow rate and decreases the minimum pressure gradient required for flow of Bingham plastic fluids in fractured... 

The kinetic experiments for the reaction of synthesis gas to light olefin over CO/Mn/TiO 2 catalyst were carried out in a micro-fixed-bed reactor. Rate expressions for reactions were selected based on the carbide mechanism. A differential reactor model considering both FTS and WGS kinetic models was used to describe the reaction systems. The simulation estimation of proposed kinetic model was conducted with a generic algorithm. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montréal, Quebec, Canada 8/23-27/2009)