Sharif Digital Repository

Satellite remote sensing products of AOD from MODIS along with appropriate meteorological parameters were used to develop statistical models and estimate ground-level PM10. Most of previous studies obtained meteorological data from synoptic weather stations, with rather sparse spatial distribution, and used it along with 10 km AOD product to develop statistical models, applicable for PM variations in regional scale (resolution of ≥10 km). In the current study, meteorological parameters were simulated with 3 km resolution using WRF model and used along with the rather new 3 km AOD product (launched in 2014). The resulting PM statistical models were assessed for a polluted and largely variable... 

In this work, PC-SAFT, an equation of state based on perturbation theory, is applied to predict the reservoir fluids phase behavior. PC-SAFT parameters for pure components have previously been assessed, but they cannot be determined for petroleum fractions with unspecified components and composition. In order to remove this difficulty and making use of PC-SAFT model in the reservoir fluids simulations, a new approach is studied which leads to appearing generalized correlations for the estimation of PC-SAFT parameters for petroleum cuts and plus fractions using only their molecular weight and specific gravity, without the essential need for the characterization of petroleum fractions in... 

Zinc-stearate-layered hydroxide nanohybrid was prepared using stearate anion as an organic guest, and zinc layered hydroxide nitrate, as a layered inorganic host by the ion-exchange method. Powder X-ray diffraction patterns and Fourier transform infrared results indicated that the stearate anion was actually intercalated into the interlayer of zinc layered hydroxide nitrate and confirmed the formation of the host-guest nanohybrid material. Also, surface properties data showed that the intercalation process has changed the porosity for the as-prepared nanohybrid material in comparison with that of the parent material, zinc hydroxide nitrate. The nanohybrid material was heat-treated at 600 °C... 

In this work, a new automatic workflow for accurate optimal pseudo-component generation from gas condensate mixtures with a large number of components is presented. This workflow has a good insight into thermo-physical and critical properties and introduces only a small amount of loss of information and EOS flexibility. In this regard, the fuzzy clustering is used to classify the components in the mixture based on the similarities in the critical properties. The mixing rules are then applied to find group properties. Two different approaches for components association in clustering process are investigated with several numbers of groups. The mathematical validity of the groups is controlled... 

Changes in thermodynamic properties such as pressure, temperature, and composition may result in asphaltene precipitation and deposition in porous media. In addition, asphaltene deposition can cause wettability alteration, permeability reduction, and ultimately a decrease in the productivity of a reservoir. Natural depletion is one of the most common processes of asphaltene deposition in which pressure changes destabilize the dissolved asphaltene in the oil and settle them onto the rock surface. In this work, natural depletion experiments in consolidated core samples were performed under simulated reservoir conditions to obtain reliable data and analyze the asphaltene deposition mechanisms.... 

This work concerns with experimental and analytical investigation of role of ultrasonic wave radiation in relative permeability of both wetting and non-wetting phases in a free gravity drainage process in porous media under the influence of ultrasonic wave. Glass beads ranged from 70 to 100 mesh sizes were packed and used in the tests. The working fluids consist of distilled water, kerosene and Doroud and Paidar crude oils as wetting and air as non-wetting phase. The measured oil recovery data along with Hagoort (1984) backward methodology were used to determine and to compare the relative permeability of wetting phases in presence and absence of ultrasonic radiation. In addition, the... 

The effects of different parameters including membrane type (regenerated cellulose and polysulphone), transmembrane pressure (TMP), the content of oil in the feed, the flow velocity of the feed and pH on the ultrafiltration of an emulsion of kerosene in water were studied. It was found that the important factors affecting ultrafiltration were, in order, membrane type, pressure and oil concentration. The greatest flux at the optimum conditions here of 3 bar, an oil content of 3% (v/v) and with membrane type C30F was predicted as 108 L/(m2 h) that was within the range of the confidence limit of the measured value of 106 L/(m2 h). The normalised FTIR results of the virgin cellulosic membranes... 

A mathematical time-dependent and isothermal model based on the grain model has been developed to simulate the kinetic and thermal behaviors of a porous iron oxide pellet undergoing chemical reactions with a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. Its novelty consists in fact that it can deal with a multi-species reducing gas and oxide pellet. In spite of previous models in which the pure reductant was applied as reducing gas, this model can indicate an actual view of pellet reduction including the effects of reducing gas utility and reducing gas ratio. A finite volume fully implicit technique was applied for solving the governing equations. The model has been... 

Copper-succinate-layered hydroxide (CSLH), a new nanohybrid material, was synthesized as an inorganic-organic nanohybrid, in which organic moiety was intercalated between the layers of a single cation layered material, copper hydroxide nitrate. Microporous scaffold carbon material was obtained by thermal decomposition of the nanohybrid at 500°C under argon atmosphere followed by acid washing process. Furthermore, the heat-treated product of the nanohybrid at 600°C was ultrafine mesoporous metallic copper particles. The results of this study confirmed the great potential of CSLH to produce the carbon material with large surface area (580m2/g) and high pore volume copper powder (2.04cm3/g)  

Undoped and copper doped nanostructured zinc oxides were synthesized by using a series of synthetic layered material, undoped and copper doped zinc hydroxide nitrates at various molar percentages of copper (2-10) within the layers as precursors. The layered materials were heat-treated at 500 °C to produce zinc oxide nanostructures with crystallite sizes in the range of 23-35 nm. Optical studies of the nanostructured copper doped zinc oxides showed the decrease in band gap with increasing content of the doping agent, copper  

Till now, no mathematical model is presented to model the flow under sonic field be applied in fractured reservoirs. This will be more noticeable when we bear in mind that several reservoirs in Middle East region are fractured. In this work the effects of elastic waves on capillary trapping and mobility of Bingham plastic fluids in fractures have been investigated. Eventually, a model for predicting the influence range of the wave in fractured reservoirs is presented. The results of this study clarified that radiation of wave with low frequency and intensity extremely increases the flow rate and decreases the minimum pressure gradient required for flow of Bingham plastic fluids in fractured... 

Acidizing is widely used to remove near-wellbore damage and enhance the inflow performance of the reservoir to boost the well oil production rate. However, when the injected acid exposes to reservoir oil, either asphaltic sludge or emulsion forms as acid-induced damages. Therefore, laboratory compatibility tests are required before every acidizing job to determine both the acid sensitivity of oil samples and the optimal dosage of chemical inhibitors that should be used to prevent sludge and emulsion formation. The lack of knowledge to predict the risk of asphaltic sludge and emulsion damages for different oil and acid systems necessitates expensive and time-consuming compatibility tests... 

Deposition of asphaltenes upon precipitation is a main flow assurance concern, which propelled the development of various experimental and modeling techniques to accurately predict its occurrence. This work develops an integrated approach combining thermodynamic and deposition modules with a multiphase flow simulator to simultaneously model asphaltenes precipitation and deposition in wellbores. The Peng-Robinson equation of state and the modified Miller-Flory-Huggins theory are used to calculate the thermodynamic properties of the oil and asphaltenes precipitation, respectively. The deposition module is based on conservation laws for asphaltenes transport and is linked to the flow simulator... 

Asphaltenes, and their related issues, have been the focus of many literature investigations. However, in-depth analysis of asphaltenes structure and its relation to asphaltenes stability has been considered by fewer studies. In this research, extensive analysis of the structure of asphaltenes extracted from light, medium, and heavy oils is provided, together with analysis of three subfractions of the medium oil asphaltene having the least, intermediate, and highest solubilities. To this end, elemental analysis, EDX, mass spectroscopy, FTIR, NMR, XRD, and SEM results were collected. Higher hydrogen content and hydrogen/carbon atomic ratio, lower aromatic nature and olefinic entities were... 

Gas-oil relative permeability is essential for performance predictions of reservoirs with solutions for gas drive, gas cap expansion, or gas injection. The nature of flow in reservoir is determined by the interplay of relative permeability and viscous, gravity, and capillary forces. Displacement experiments of the gas-oil system are performed on long core scale models by varying the petrophysical properties and flow conditions. Experiments are conducted in situations where capillary, gravity, and viscous forces are comparable. The effect of destabilized front velocity on relative permeability and residual saturation is investigated. The results indicate that the relative permeability varies... 

A number of forced gravity drainage experiments have been conducted using a wide range of the physical and operational parameters, wherein the type, length, and permeability of the porous medium as well as oil viscosity and injection rate were varied. Results indicate that an increase in the Bond number has a positive effect on oil recovery whereas the capillary number has an opposite effect. These trends were observed over a two-order of magnitude change in the value of the dimensionless groups. Furthermore, it was found that use of each number alone is insufficient to obtain a satisfactory correlation with recovery. A combined dimensionless group is proposed, which combines the effect of... 

Wellbore stability is a main concern in drilling operation. Troublesome drilling issues are chemically active formations and/or high-pressure–high-temperature environments. These are mainly responsible for most of wellbore instabilities. Wellbore failure is mostly controlled by the interaction between active shales and drilling fluid in shale formations. The factors influencing this interaction consist of fluid pressure, temperature, composition of drilling fluid, and exposure time. In this paper, a non-linear fully coupled chemo-thermo-poroelasticity model is developed. At first, a fully implicit finite difference model is presented to analyze the problem, and then, it is verified through... 

Asphaltene deposition is a problematic challenge for oil production. Changes in key parameters like pressure and fluid composition during natural depletion and different gas injection scenarios may result in asphaltene precipitation and deposition. In this work, a model is developed by application of mass balance equations, momentum equation, asphaltene deposition and permeability reduction models. An algorithm is developed to perform iterative procedure to solve the numerical equations that contains highly coupled variables. Indeed, an equation is introduced to calculate the saturation of the precipitated asphaltene phase. Model parameters were determined by genetic algorithm which is a... 

A lot of laboratory experiments have been carried out to investigate each aspect of ultrasonic wave s role on fluid flow behavior through porous media. Despite all experimental works, little attention has been paid for modeling the ultrasonic wave influence on capillary imbibition, which is the main mechanism of production in fractured reservoirs. At this work the process of imbibition with and without applying ultrasonic waves is mathematically modeled by modification of piston-like model. In contrast to this model s assumption, in which mobility ratio is assumed to be constant, here permeability variation due to increase in water saturation is considered in numerical solution. To evaluate... 

In this study, water activities for the ternary systems of PEG6000 + sodium citrate (Na3Cit) + H2O and PEG6000 + potassium citrate (K3Cit) + H2O have been measured using an improved isopiestic method over the entire homogeneous mixing range at 298.15 K. From these measurements, values of the vapor pressure of solutions were also determined. The experimental data for the activity of water, collected in this work, were accurately correlated with local composition based models of the NRTL, modified NRTL, Wilson and modified Wilson. The results showed that these models can accurately correlate the water activity data generated in this work. © 2007 Elsevier B.V. All rights reserved