Sharif Digital Repository

In the current study, the dinuclear copper(I) complex ,[Cu2(μ-phthalazine)(phthalazine)2(μ-dppm)2](PF6)2,(1), has been prepared by the reaction of two equiv of [Cu(CH3CN)4]PF6, three aquiv of phthalazine, and two equiv of bis(diphenylphosphino)methane (dppm). However a mixture of two four coordinated copper(I) complex,1, and a three and four-coordinated copper(I) complex ,[Cu2(μ-phthalazine)(phthalazine)(μ-dppm)2](PF6)2,(2), have been prepared when the reaction has been carried out with equal ratio of the reactants. The structure of 1 and 2 determined using. X-ray crystallography in solid state and the structure of 1, further characterized by multinuclear NMR spectroscopy in solution.... 

The country's increasing demand for water makes effective dam management essential. Beyond environmental concerns, constructing new dams and their components involves relatively high costs. One of the most critical components of a dam is its spillway, which accounts for a significant portion of the total construction costs and plays a vital role in water resource management. To reduce spillway construction costs, a specific type of spillway that combines a stepped spillway with cascading basins can be employed. Designing this type of spillway can be considered as an optimization problem, requiring the use of optimization methods. Metaheuristic algorithms, which have gained significant... 

The increasing rate of population and agricultural development over the past few decades has led to a significant rise in the pollution of surface and groundwater. The application of animal and synthetic fertilizers containing phosphorus, which increases the levels of this element in the soil, can be considered one of the factors endangering the environment, especially the quality of surface waters. The transport of phosphorus, which is one of the pollutants in agricultural runoff, can lead to the degradation of aquatic ecosystems and reduce the quality and usability of water resources. Accordingly, various numerical models have been developed to simulate phosphorus loss from the soil. They... 

Enormous amounts of water and energy are lost by scrubber utilization for furnace exhaust gas washing during direct iron reduction process. Hence, the aim of the current research is design and construction of a system which could be employed instead of scrubber within direct iron reduction process considering the equipment size constraints.To this end, the substitute system was manufactured after dimensional analysis and simulation of lab model compared to the prototype regarding the implementation limitations. The model has been tested in different operating conditions and empirical relations have been extracted for general analysis of direct iron reduction process. The case study here is... 

The main purpose of this study is to evaluate the linkage between two constructs about teamwork activities. One of them is "self-leadership in teamwork", the extent to which a person could control and manage his thoughts and activities in teamwork. The other is "shared leadership orientation", which is about orientation of people to contribute in leadership processes. This linkage evaluated with consideration of "self-efficacy in shared leadership" as a moderator.
Questionnaires of self-leadership in teamwork and self-efficacy in shared leadership elicited from literature with a little change and shared leadership questionnaire developed in another study by the author.Questionnaires... 

Women are going to play more important roles in the economy of most countries including Iran. Hence, since the number of entrepreneurs among women is increasing, identifying characteristics and other factors that cause these group to be successful, is a critical issue. Studies show that entrepreneurs, especially women entrepreneurs, face numerous problems in their career. These problems are especially more demanding in societies with unique cultural attributes. Therefore, applying personal and managerial solutions in order to overcome these problems are necessary. On the other hand, researchers believe that one of the most effective and beneficial concepts helping entrepreneurs in their... 

The present study was performed aiming to identify the ethical dilemmas human resource managers confront with in Iranian project-based organizations as well as to trace out the underlying causes. “Ethical dilemma” refers to a decision making situation in which ethical considerations render all the alternatives inapt, thence making the decision making process ethically complex. First of all, a theoretical framework was developed based on the preceding research; then, the study was further conducted utilizing a qualitative research method with an exploratory approach. The data were collected using in-depth interviews and analysed using the theme analysis method. The corresponding interviewees... 

Using Distributed leadership framework while studying the leadership phenomena in teams, especially in educational environment, has received more attention by scholars in these years. Although the results of these researches indicated positive consequences mostly, the need for exploratory studies to identify situational and contextual factors in distributed leadership effectiveness has been mentioned. In other words, it has been suggested that the effectiveness of distributed leadership in teams may be affected by situational and contextual factors. In the current multiple case study, after the initial study of leadership and its functions in some schools of Sharif University of Technology,... 

The influence mechanisms of executive/non-executive board compostion on board’s attribution style have been explored. In two case studies, I have examined boards’ causal interpretation about a critical incident which had a significant impact on firm performance. A qualitative research approach has been taken in the case studies. Data was gathered through semi-structured interviews with all board members and was analyzied with the theme analysis method. According to the results, board of directors’ collective attribution formation process can be devided into three stages of members’ expression of information and facts at board meetings, forming the individual judgements of members and at... 

Career Orientations or career choices, can be affected by internal and external factors. External factors are the environmental conditions that the reward and the attractiveness of selecting a career choice are dependent to them. Internal factors include the needs of oneself from his/her job, his/her beliefs and his/her skills and competencies about the job. In this research the internal antecedents of managerial and technical orientations between programmers have been identified. On the other hand the perception of people about the compensation system as an external factor which can affect the mentioned relationships, have been analyzed. It seems that this is the first research which career... 

Voluntary turnover has direct and indirect expenses for organizations and for this purpose; it has one of the richest literatures in academic works. Due to the especial role of knowledge workers in organizations, these expenses in knowledge-based organizations are more important and more costly than that of other organizations. One of the latest theories in the field of voluntarily turnover was introduced by Lee and Mitchell (1994) that was named “Unfolding Model of Turnover” to describe the process of decision of voluntary turnover. This theory is distinguished from its similar theories from two main aspects: First, they introduced new elements like shock. Second, they introduced... 

The measure of success in a company is determined by a high performing workforce that demonstrates the competencies necessary to drive the business success, while meeting the organization's strategic goals. This is where competency-based human resource management becomes important. The main factor contributing to the above noted area is the identification of core competencies. There has been a lot of research in this area during the past few years. Each research demonstrates an approach for the development of critical human resource competency models in an organization. In order to determine the foregoing competency model, the early studies in this area have been focused on the distinction... 

The goal of this study was to realize how the younger generation's perceptions of the authenticity of senior managers in knowledge-based firms affects the components of their employer brand on social media. For this reason, the perceptions of managers' authenticity from the perspective of the younger generation on Instagram, as an example of social networks, was investigated in the first stage of the study. The mechanisms of effectiveness of the identified components of authenticity are sought in the second step, in shaping the components of the manager's organization's employer brand. To attain the research goal, an exploratory approach was taken conducted, and a qualitative research method... 

This research explores the impacts of the telework initiated by the outbreak of COVID-19, which is being called “emergent telework” in this research, on psychological well-being of teleworkers. As for the nature of emergent telework which is a new and unique phenomenon, a qualitative research is conducted. In order to do so, 15 in-depth interviews were held with employees from product teams of 11 organizations, and the interviews were analyzed using thematic analysis. General conditions of teleworking are identified in two categories named as “not working adjacent to coworkers” and “being away from the physical environment of the workplace”. Emergent telework, alongside the general... 

In this research study, the reciprocal relationship between Emergent States and Team Processes has been analyzed in boards of directors, by using case study method with semi-structured interview as the method of data collection and thematic analysis as the method of data analysis. This research was conducted on the companies which are active in Information Technology industries, their size is in the range of SMEs, and have passed the early startup stage and an external investor has joined the board. After thematic analysis, narrating each case’s story, and theoretical analysis on each case, the obtained results are demonstrated with discussion on both cases, introducing a theoretical model,... 

Computer video games have had a huge growth in recent years, and Dota 2 is one of the most popular video games and e-sports right now. In this research, Dota 2 drafting phase is studied by using stochastic processes and probabilistic models. This phase is modeled as a POMDP (Partially Observable Markov Decision Process) for the first time. Afterwards, the model is solved using data mining methods and machine learning algorithms. A large database of the game's match data is created, and six different machine learning algorithms are used to predict the match outcome based on the drafting stage. The prediction accuracy and power of these algorithms is compared, and finally, a program is... 

The purpose of the present study is to facilitate the implementation of "organizational complex change" that is important in today's organizational competitive environment. To this end, and to increase employees' commitment to change, the study utilized the role of "authentic leadership" and "self-determination theory." In this study, using data from 269 employees involved in an organizational complex change, relationships between variables were tested to finally see how authentic leadership for change can enhance employees' "affective commitment" to change. For this purpose, exploratory factor analysis and multiple regression were conducted on the data and 3 out of 5 hypotheses were... 

The present study aimed to investigate the application of self-leadership strategy by participants in a training course of employment interview through the role playing method to face the relevant challenges. Solving or regulation of the challenges in a training course can result in participants’ learning improvement. This course was taken place as a part of the Human Resource Management Course in 2017 in the graduate school of management and economics at Sharif University of Technology. Initially, background and models were reviewed, and then the research theoretical framework was developed accordingly. In addition, since the subject was rather new, a qualitative research method by... 

Emergency Department (ED) overcrowding is one the most problems and challenges that every Emergency Department all over the world is facing with. This problem leads to some problems like prolonged waiting times and Length of Stay in Emergency Department. “Boarding time” is one of the most important ones, which is the time a patient spend for being transferred from Emergency Department to one of the Hospital Inpatient Wards. One important solution to this problem is “overflowing”, and it means allocating patients to an alternative ward rather than their primary ward. In practice, the overflowing process usually controlled in a myopic manner. Limited number of researches that focus in this...