Sharif Digital Repository

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

A stochastic real time optimization (SRTO) which has an efficient result has been implemented on the Tennessee Eastman (TE) challenging problem. In this article a novel stochastic optimization method, the so-called heuristic random optimization (HRO) proposed by Li & Rhinehart is used which attempts to rationally combine features of both deterministic and random (stochastic) methods. Further, an on-line nonlinear identifier via extended Kalman filter (EKF) is used to supply the plant model for model-based optimization algorithm. Using the information obtained from EKF an on-line HRO is accomplished by a random search method whose search directions and steps are considerably reduced by some... 

In this paper real-time optimization of the Tennessee Eastman challenge process is accomplished in a fuzzy environment. This study focuses on violation of TE constraints in fuzzy environment and also violation of some additional constraints originated from operating mode of the plant. Furthermore the objective function is treated in fuzzy form. Results show a great reduction of operating cost, which is selected as the objective function of this study. The theory of fuzzy optimization, which is the main contribution of this paper, is to reformulate the fuzzy constraints and fuzzy objective function into a crisp programming problem and to solve it by a conventional method of optimization. The... 

On-line optimization for the base case of the Tennessee Eastman (TE) challenge problem is presented; furthermore, an interesting operating condition near base case has been obtained, which results in a lower cost function. The proposed method is based on the estimation of the internal states and the time varying parameters of the process model based on an Extended Kalman filter. The sequential quadratic programming method has been used to accomplish the non-linear programming (NLP) task. The objective function is the operational cost while the constraints are the reactor mass balance, safe operation of the process equipment, and the conditions that satisfy the product quality and flow. The... 

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

A Real-Time Optimization (RTO) strategy incorporating the fuzzy sets theory is developed, where the problem constraints obtained from process considerations are treated in fuzzy environment. Furthermore, the objective function is penalized by a fuzzified form of the key process constraints. To enable using conventional optimization techniques, the resulting fuzzy optimization problem is then reformulated into a crisp programming problem. The crisp programming problem is solved using both Sequential Quadratic Programming (SQP) and Heuristic Random Optimization (HRO) techniques for comparison purposes. The proposed fuzzy RTO strategy is demonstrated via the Tennessee Eastman benchmark process,... 

Introduction: Due to the importance of laser light penetration and propagation in biological tissues, many researchers have proposed several numerical methods such as Monte Carlo, finite element and green function methods. Among them, the Monte Carlo method is an accurate method which can be applied for different tissues. However, because of its statistical nature, Monte Carlo simulation requires a large number of photon pockets to be traced, so it is computationally expensive and time-consuming. Although other numerical methods based on the diffusion method are fast, they have two important limitations: first, they are not valid near the bounder of sample and source, and second, their...