Sharif Digital Repository

Unsymmetrical Dimethyl hydrazine (UDMH) is used as stabilizer, fuel promoter, chemical in photography, and liquid fuel for fighter jet engines. Catalytic liquid phase hydrogenation of nitrosodimethylamine (NDMA) is one of the most efficient methods for the production of UDMH. Hydrogenation of NDMA to UDMH using a commercial 5% Pd/C catalyst in aqueous solution of NDMA was studied under constant temperature at 40°-70°C, ≤ 15 bar, and NDMA concentrations of 40-70 wt %. The effects of temperature, pressure, and NDMA concentration on NDMA conversion and yield of UDMH product in presence of undesired Dimethylamine (DMA) were studied. At NDMA concentration of > 50 wt %, the UDMH yield was < 0.89,... 

The Unsymmetrical dimethyl hydrazine (UDMH) apart from its use as a versatile rocket fuel, finds numerous industrial applications. Interest in UDMH for various applications in the missile and rocket industry has prompted the study of this member of hydrazine family to greater extent. It can be prepared in several ways but one of the most efficient ones which results in higher yields is the catalytic hydrogenation of Nitroso Dimethylamine (NDMA). In this work the kinetic of NDMA to UDMH hydrogenation on a 5% Pd/C in aqueous solution of NDMA was studied experimentally and optimum conditions of the reaction for maximum yield of UDMH in the presence of undesired dimethyl amine (DMA) product was... 

Unsymmetrical dimethyl hydrazine (UDMH) is a strong propellant, which due to its very good physical properties and high power of repellency has been utilized as a liquid fuel for fighter jet engines for so many years. There are different methods for production of this material. One of the more efficient ones which results in higher yields compared to others is the catalytic hydrogenation of Nitroso Dimethylamine (NDMA). In this work hydrogenation of NDMA to UDMH on a 5% Pd/C in aqueous solution of NDMA was studied experimentally. Experiments were carried out in a Semi-batch three phase STR reactor under constant pressure and temperature in the range of 40 to 70°C, pressures of up to 15 bar... 

We investigate the underlying physics of degradation/recovery of a metal/n-CdTe Schottcky junction under reverse or forward bias stressing conditions. We used Sah-Noyce-Shockley (SNS) theory to investigate if the swept of Fermi level pinning at different levels (under forward/reverse bias) is the origin of change in current-voltage characteristics of the device. This theory is based on Shockley-Read-Hall recombination within the depletion width and takes into account the interface defect levels. Fermi Level Pinning theory was primarily introduced by Ponpon and developed to thin film solar cells by Dharmadasa's group in Sheffield University-UK. The theory suggests that Fermi level pinning at... 

Multiphase impeller stirred tank reactors enhance mixing of reacting species used in a variety of chemical industries. These reactors have been studied based on Computational Fluid Dynamics (CFD) that can be used in the analysis, design and scale up of these reactors. Most of the researches done in this area are limited to single phase reactors, and a few remaining two phase flow investigations have been done based on MRF (Multi Reference Frame) and Snapshot approach. However, the MRF and snapshot approaches cannot be used in rigorous simulation of unsteady state problems. In order to simulate the unsteady state behavior of the multiphase stirred tank reactors we have used sliding mesh... 

Multiphase impeller stirred tank reactors enhance mixing of reacting species used in a variety of chemical industries. Gas-liquid mixing and mass transfer between these phases is an important application in reactor design. One such an example is hydrogenation reaction of aqueous NDMA (Nitroso dimethyl amine) solution in which one of the parameters having a significant effect on the reaction rate is mass transfer. This parameter in turn is a function of impeller shape and rotational speed, gas flow rate and reactor scale. Computational Fluid Dynamics (CFD) is a useful tool in the analysis, design and scale up of stirred tank reactors via investigating hydrodynamics of gas and liquid flow,... 

In this study, the boundary layer velocity profile on the upper surface of a supercritical airfoil in a forced sinusoidal pitching motion was measured and experimentally investigated. Measurements were performed using a boundary layer rake, including total pressure tubes positioned at 25 % of the chord far from the leading edge on the upper surface. For static measurements, the effects of the angle of attack between −3° and 14° and free-stream velocity between 40 m/s and 70 m/s were investigated; for dynamic measurements, the effects of oscillation amplitude variation between ±3° and ±10°, reduced frequency from 0.007 to 0.0313, and mean angle of attack between −3° and 6° were studied during... 

This paper investigates numerically the problem of unsteady magnetohydrodynamic nanofluid flow and heat transfer between parallel plates due to the normal motion of the porous upper plate. The governing equations are solved via the fourth-order Runge-Kutta method. Different kind of nanoparticles is examined. The effects of kind of nanoparticle, nanofluid volume fraction, expansion ratio, Hartmann number, Reynolds number on velocity and temperature profiles are considered. Also effect of different types of nanoparticles is examined. Results indicate that velocity decreases with increase of Hartmann number due to effect of Lorentz forces. Rate of heat transfer increase with increase of... 

In this paper we developed a new mathematical model for the flow inside cascade impactors and via this simplified model, we determined the particle size distribution by a fast and low cost computational method. Using cascade impactors for determining the particle size distribution, one can use comprehensive CFD methods to fully simulate the particle traces. Although the results from those CFD analyses can be very accurate, usually that is not a time and cost efficient routine. In contrast, we showed that by using our proposed calculation we can estimate the particle size distribution very fast and yet with the slight error -comparing to the results from CFD method. Cascade impactors are... 

We proposed a modeling procedure to calculate the impact of temperature on the detection efficiency in photodetectors based on CdTe materials. Temperature increase impacts on the electrical properties of the materials such as carrier mobility and carrier recombination lifetime. This impact which can be effective in some cases has been normally ignored in the modeling approaches presented in the literature. Here we show that increasing the temperature from 190 K to 300 K not reduces the mobility of both electrons and holes but also significantly reduces the carrier lifetime. The result will impact on electric-field within the depletion width of the device, drift and diffusion lengths which... 

We proposed two different time-dependent modeling approaches for variation of device characteristics of perovskite solar cells under stress conditions. The first approach follows Sah-Noyce-Shockley (SNS) model based on Shockley–Read–Hall recombination/generation across the depletion width of pn junction and the second approach is based on thermionic emission model for Schottky diodes. The connecting point of these approaches to time variation is the time-dependent defect generation in depletion width (W) of the junction. We have fitted the two models with experimental data reported in the literature to perovskite solar cell and found out that each model has a superior explanation for... 

This work focuses on transient thermal behavior of radial fins of rectangular, triangular and hyperbolic profiles with temperature-dependent properties. A hybrid numerical algorithm which combines differential transformation (DTM) and finite difference (FDM) methods is utilized to theoretically study the present problem. DTM and FDM are applied to the time and space domains of the problem, respectively. The accuracy of this method solution is checked against the numerical solution. Then, the effects of some applicable parameters were studied comparatively. Since a broad range of governing parameters are investigated, the results could be useful in a number of industrial and engineering... 

We introduce a new third generation of solar cell structure which inserts different-sized quantum dots in the active region of a pin structure. Generating an intermediate band in the bandgap of the host material makes a good overlap with a part of solar spectrum. The effect of the recombination mechanisms on efficiency and currentvoltage characteristics of this intermediate band solar cell is calculated. We deduce that the increase in recombination lifetime of the excited carriers can improve the characteristics of this structure. This result can be a route which helps us to take the effect on solar cell characteristics into consideration  

In this study, a novel inorganic/organic hybrid pigment based on zinc cations/Ferula Asafoetida leaves extract (Zn-FALE) was synthesized, and its corrosion protection properties were investigated in a saline solution and an organic coating. Interactions of components between Zn2+ cations and FALE were assessed by thermo-gravimetric analysis (TGA) and ultraviolet-visible (UV–visible) spectroscopy. Corrosion inhibitive performance of FALE and Zn-FALE pigments in the solution phase and coating phase was studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). TGA and UV–visible results revealed the proper chelation between inorganic and organic components of...