Sharif Digital Repository

Modeling the structure formation in the universe, we extend the spherical-collapse model in the context of modified Newtonian dynamics (MOND) starting with the linear Newtonian structure formation followed by the MONDian evolution. In MOND, the formation of structures speeds up without a need for dark matter. Starting with the top-hat overdense distribution of the matter, the structures virialize with a power-law profile of the distribution of matter. We show that the virialization process takes place gradually from the center of the structure to the outer layers. In this scenario, the smaller structures enter the MONDian regime earlier and evolve faster, hence they are older than larger... 

Sol-gel based solid-phase microextraction fibers supported by a stainless steel wire were fabricated and employed for GC-MS determination of oxadiargyl in real samples. The fibers were based on four compounds with different polarity: polar and non-polar (end-capped) poly(dimethylsiloxane) (PDMS), polyethylene glycol (PEG), and poly(ethylene-propyleneglycol)-monobutyl ether (UCON). For this purpose, the surface of the stainless steel was initially modified by (3-mercaptopropyl) trimethoxysilane. The results of the modification procedure were evaluated by cyclic voltammetry and energy dispersive X-ray (EDX) spectroscopy. After the modification, four different sol-gel based SPME fibers with... 

A novel solid-phase microextraction(SPME) fiber was prepared using sol-gel technology with ethoxylated nonylphenol as a fiber coating material. The fiber was employed to develop a headspace SPME-GC-MS method suitable for quantification of 13 polycyclic aromatic hydrocarbons (PAHs) in water samples. Surface characteristics of the fibers were inspected by energy dispersive X-ray (EDX) spectroscopy as well as by scanning electron microscopy (SEM). The SEM measurements showed the presence of highly porous nano-sized particles in the coating. Important parameters affecting the extraction efficiency such as extraction temperature and time, desorption conditions as well as ionic strength have been... 

A method based on solid-phase microextraction (SPME) followed by on-fiber derivatization and gas chromatography-mass spectrometry detection (GC-MS) for determination of phenol in air was developed. Three different types of SPME fibers, polar and non-polar poly(dimethylsiloxane) (PDMS) and polyethylene glycol (PEG) were synthesized using sol-gel technology and their feasibility to the sampling of phenol were investigated. Different derivatization reagents for post on-fiber derivatization of phenol were studied. Important parameters influencing the extraction and derivatization process such as type of fiber coating, type and volume of derivatizing reagent, derivatization time and temperature,... 

Sol composition and ripening conditions are two important parameters in silica fiber production through the conventional sol-gel process. In the current study, silica nanofibers were successfully obtained via the electrospinning technique, and sol-gel formation occurred during this process. Based on previous reports, with the aim of increasing the selectivity, we used the molecular imprinted methodology to produce a selective medium via sol-gel electrospinning. In this process, sol-gel was formed during electrospinning and then, the backbone polymer was removed by heating. To obtain a thin layer of silica nanofibers, the influencing parameters such as backbone polymer types, imprinting time... 

A cryogel–based semi–interpenetrating polymer network (Cryo–SIPN) was prepared in which conductive polymers such as polyaniline (PANI) and polypyrrole (PPy) were formed within the super porous network of acrylic acid cryogel. For completion of cryo-polymerization, all the constituent solutions were severely mixed and placed into the plastic straws and kept at -20°C and then the synthesized cyrogels were cut into the 1-cm length and freeze dried after washing with water. The Cryo–SIPN polymeric composite was applied in micro solid phase extraction (µSPE) of some selected antibiotic residues from various samples. The µSPE method combined with a high performance liquid... 

Low accuracy, requirement of expensive instruments, derivatization and multi-step sample preparation, inconsistencies during the fabrication process, time-consuming procedures and utilization of eco-unfriendly chemicals are some limitations of various developed methods for detection of 4-methylimidazol (4-MeI). Herein, a rapid and miniaturized fluorescent probe based on the ultrasound‒assisted formation of carbon dots (CDs) in a metallic deep eutectic solvent (MDES) was developed and conveniently implemented to detect 4-MeI in commercial dark soft drinks. In-situ synthesis of CDs-chelated metals in the presence of the target analyte facilitates a kinetically fluorescence emission with no... 

In this study, organic aerogels were synthesized by the sol-gel polycondensation of mixed cresol with formaldehyde in a slightly basic aqueous solution. Carbon aerogels and xerogels are generated by pyrolysis of organic aerogels. The novel sol-gel-based micro-solid-phase extraction sorbent, resorcinol-formaldehyde xerogel, was employed for preconcentration of some selected herbicides. Three herbicides of the aryloxyphenoxypropionate group, clodinafop-propargyl, haloxyfop-etotyl, and fenoxaprop-P-ethyl, were extracted from aqueous samples by micro-solid-phase extraction and subsequently determined by gas chromatography with mass spectrometry. The effect of different parameters influencing the... 

An attempt was made to combine μ-solid phase extraction and headspace single drop microextraction techniques and use their advantages for trace determination of some volatile organic compounds in aqueous samples. After performing the two-step preconcentration approach, the desired analytes were determined by gas chromatography-mass spectrometry. A resorcinol-formaldehyde-based xerogel was used as the extraction medium in the μ-solid phase extraction (μ-SPE) method. Then, the extracted BTEX was eluted with a rather large amount of methanol. To remove the laborious process including solvent evaporation and further reconstitution, which is usually accompanied by loss of analytes and accuracy,... 

In this study, scaling effects on fiber metal laminates under tensile and three-point bending tests were investigated numerically and experimentally. The fiber metal laminate specimens were made of aluminum 1050 and unidirectional glass-epoxy. Two scaled sizes of specimens were prepared based on A1n, 0n=90n s. Some specified mechanical properties of these samples were investigated and results showed that fiber metal laminates obey scaling law under quasi-static loading. Explicit finite element code LS-DYNA was utilized for numerical simulation. After validating numerical simulation with experiments, scaling law was studied numerically for four different... 

An imprinted interpenetrating polymer network (IPN) was synthesized and used as a medium for isolation of carbamazepine from urine samples. The polymer network consisted of a homogeneous polystyrene–sol gel hybrid constructed by in–situ radical polymerization method. In this process, within the sol–gel reaction duration, styrene monomer could penetrate into the reaction mixture and after the polymerization initiation, a monolithic IPN structure was prepared. The scanning electron microscopy (SEM) image and energy dispersive spectroscopy (EDX) are indications of the polystyrene dispersion at nano- to micro-meter level in the sol gel matrix. Eventually, the synthesized IPN was used as a... 

Solid-phase microextraction probes based on poly(ethylene glycol)/C18-bonded silica were used for in vivo monitoring of drugs from circulating blood of beagles, over a period of 8 h. After sampling, the extracted drugs were subsequently quantified by liquid chromatography coupled with tandem mass spectrometry. External calibrations in whole blood and phosphate-buffered saline were used to correlate the amount of analytes extracted in regard to the total and free concentrations in blood respectively. The probe provided sufficient sensitivity for the drugs in the blood matrix, while the need for drawing blood was eliminated. The limit of detections of the method from whole blood were 1.7, 1.4... 

In this article, the problem of simultaneous heat, mass, and momentum transfer in the developing region of tubular reactors with homogeneous chemical reaction and laminar power-law fluid flow under unsteady-state conditions has been solved. In this regard, the general governing equations were solved using finite-difference method and analyzed carefully. Moreover, the influences of various parameters and dimensionless numbers such as power-law index, heat of reaction, reaction order, and Damköhler number value on the numerical results were investigated. In addition, the numerical results obtained for the fully-developed velocity distribution of Newtonian fluid flow and Sherwood number value... 

In this paper a novel soft switching isolated buck rectifier is proposed. Various switching state sequences of a three-phase three-switch buck-type unity power factor rectifier are reviewed and the value of switching power loss in each state transition is investigated. The switching power loss of the converter is decreased by using zero current switching (ZCS) method. The operation modes of the converter are explained and analyzed. By using an auxiliary circuit with a simple method of energy recovery, the current is diverted away from the main power switches before they are turned off; so, switching losses in the converter are reduced. In this topology, the power transformer has only the... 

The present study investigates the possibility of using a small hydropower/PV hybrid power system for low-cost electricity production which can satisfy the energy load requirements of a typical rural-urban area. In this context, the optimal dimensions to improve the technical and economical performances of the hybrid system are determined according to the load energy requirements and the solar and hydro resources data using linear programming. The application of the model is demonstrated using a case study of a rural-urban area in Mazandaran province, Iran. Two scenarios were considered for optimizing the system components. In the first scenario, a stand-alone hybrid small hydropower/PV... 

In this paper, a new zero-voltage-switching high power-factor (PF) rectifier with Line-Modulated Fixed-Off-Time current control is introduced, that off time is a function of the instantaneous line voltage. The auxiliary circuit provides soft switching for all semiconductor devices, without any extra current and voltage stress on the main switches. The proposed converter is bridgeless, and all semiconductor devices are soft switched. In addition, there is no extra stress on the switches. Thus, the conduction and switching losses are reduced and maximum efficiency is achieved. A 250W, with an input ac voltage of 90265 Vrms and an output voltage 400 Vdc, 100 kHz is designed and simulated to...