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    Silane functionalization of nanodiamond for polymer nanocomposites-effect of degree of silanization

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 506 , 2016 , Pages 254-263 ; 09277757 (ISSN) Hajiali, F ; Shojaei, A ; Sharif University of Technology
    Elsevier B.V  2016
    Abstract
    The silanization of nanodiamond (ND) was successfully carried out by using the esterification reaction of hydrolyzed vinyltrimethoxysilane (VTS) in alcoholic solution. The surface carboxylic group of ND was first enhanced by thermal oxidation to increase the degree of esterification reaction. The extent of silane functionalization of ND was controlled by varying the weight ratio of VTS and oxidized ND (oxND), from 2:1 to 10:1 (w/w) in the functionalization reaction medium. Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) revealed that the highest degree of silanization occurred at VTS/oxND of 5:1 (w/w), while more silane concentrations resulted in... 

    Network structure and mechanical properties of polydimethylsiloxane filled with nanodiamond – Effect of degree of silanization of nanodiamond

    , Article Composites Science and Technology ; Volume 142 , 2017 , Pages 227-234 ; 02663538 (ISSN) Hajiali, F ; Shojaei, A ; Sharif University of Technology
    2017
    Abstract
    Reinforcement of polydimethylsiloxane (PDMS) was investigated using untreated nanodiamond (uND) and silane functionalized ND (sND) at various degrees of silanization. Scanning electron microscopy revealed an improved dispersion of ND in PDMS by silanization. The incorporation of uND and sNDs enhanced tensile strength up to 45% and 70%, respectively; however, greater improvement was observed for sNDs at very low concentrations, e.g. 0.2 wt%. The much improvement in crosslinking density, analyzed by Flory-Rehner model and Mooney-Rivlin plot, and interfacial interaction, characterized by Kraus and Cunneen-Russell plots, was also observed for sNDs. Interestingly, it was found that the extent of... 

    Characterization of Morphology and Properties of Polydimethylsiloxane/Nanodiamond Nanocomposite

    , M.Sc. Thesis Sharif University of Technology Hajiali, Faezeh (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    Polydimethylsiloxane (PDMS) is one of the most important organosilicon elastomers. This polymer has a wide application such as medical engineering due to the unique characteristics, variety and ease of manufacture. Nowadays, the use of nanoparticles such as carbon nanotubes for improving the properties of elastomers is highly regarded owing to the fact that the improvement of properties such as mechanical properties broadens the applications of PDMS. Diamond nanoparticles has been the focus of numerous researchers in the past decade. In fact, nanodiamond has a good mechanical abrasion and thermal properties. In addition, the investigations proved that the nanoparticle is valuable in terms of... 

    Fabrication and properties of polycaprolactone composites containing calcium phosphate-based ceramics and bioactive glasses in bone tissue engineering: a review

    , Article Polymer Reviews ; Volume 58, Issue 1 , 2018 , Pages 164-207 ; 15583724 (ISSN) Hajiali, F ; Tajbakhsh, S ; Shojaei, A ; Sharif University of Technology
    Taylor and Francis Inc  2018
    Abstract
    Polycaprolactone (PCL) is a bioresorbable and biocompatible polymer that has been widely used in long-term implants and controlled drug release applications. However, when it comes to tissue engineering, PCL suffers from some shortcomings such as slow degradation rate, poor mechanical properties, and low cell adhesion. The incorporation of calcium phosphate-based ceramics and bioactive glasses into PCL has yielded a class of hybrid biomaterials with remarkably improved mechanical properties, controllable degradation rates, and enhanced bioactivity that are suitable for bone tissue engineering. This review presents a comprehensive study on recent advances in the fabrication and properties of... 

    A Task Assignment Method to Reduce Aging in Multi-core Processors

    , M.Sc. Thesis Sharif University of Technology Saadatmand, Faezeh Sadat (Author) ; Miremadi, Ghassem (Supervisor)
    Abstract
    Reducing the size of transistors has dramatically increased the impacts of NBTI, HCI, and EM phenomena in comparison with decade ago. These phenomena are able to have influence on properties of different parts of a chip to make it changed gradually; including threshold voltage of a transistor and electrical conductivity of interconnections. These changes are known as the aging of a transistors that diminish the performance and reliability of a chip. A common reason that plays a significant role in all these phenomena is temperature. The temperature becomes more important when the power density increases per unit area due to decreased size of transistors, which is a trend in multi-core... 

    Optimum Design of Air Jet Nozzle Preventing Hot Solid Particles Deposition on the Furnace Wall Using Numerical Simulation of Gas-Particle Two-Phase Flow

    , M.Sc. Thesis Sharif University of Technology Hosseini, Faezeh Sadat (Author) ; Darbandi, Masoud (Supervisor)
    Abstract
    Deposition of solid particles present in the process air on the walls of furnaces is one of the challenges in industries. This phenomenon has various causes. For example, in a furnace, the temperature of particles increases as they pass in front of the furnace burners, and due to the softening of the particles, their chances of deposition increase when they collide with the walls. Over time, with the growth of deposited particle layers on the combustion chamber walls, the performance of the combustion system gradually becomes impaired. present research aims to design air jets intersecting with the process air path, with the purpose of reducing the temperature of particles prone to deposition... 

    An Analysis of Oil Revenues and Monetary and Financial Policies on Iran's Long-term Economic Growth

    , M.Sc. Thesis Sharif University of Technology Mir Jafari, Faezeh Sadat (Author) ; Kianfar, Farhad (Supervisor)
    Abstract
    In many papers, GDP is used as a measure of economic growth, which is shown to possess a nonlinear structure. The study focuses on the nonlinear Granger causality between liquidity, government spending, oil revenues and economic growth by markov-switching vector autoregressive and markov- switching Granger causality approach for the period of 1369-1397 for Iran. The empirical results from MSAI(2)-VAR(4) suggest that Oil revenues and government spending have a significant impact on economic growth in both regimes. Also, markov- switching Granger causality results are quite different from the traditional Granger causality results, that suggests the nonlinear Granger causality has more... 

    Design and Fabrication of Brain Spinal Cord Electrodes for Rehabilitation of Rats with Spinal Cord Injuries

    , M.Sc. Thesis Sharif University of Technology Mashayekhi, Fatemeh (Author) ; Fardmanesh, Mehdi (Supervisor) ; Shanehsazzadeh, Faezeh (Co-Supervisor)
    Abstract
    The use of microelectrode arrays in neural networks has offered a wonderful opportunity for evaluating numerous properties and interactions with excitable tissues such as the brain and spinal cord in the laboratory. In neural network applications, microelectrode arrays can be utilized to analyze nerve impulses or interact with neurons. They are either used to record neural data or to stimulate spinal cord nerves. Previous research has revealed that stimulating the spinal epidural region can help restore after spinal cord injuries (SCIs), which is the key to using them in the rehabilitation of living beings, including humans. According to the international campaign for the treatment of SCI... 

    Characterization of V2O5 Spent Catalyst & Feasibility Study of its Regeneration

    , M.Sc. Thesis Sharif University of Technology Soltani Nejad, Mohammad (Author) ; Sadrnezhaad, Khatiboleslam (Supervisor) ; Farzami, Faezeh ($item.subfieldsMap.e)
    Abstract
    In this study, at first the V2O5 spent catalysts were characterized. The aim was to identifying whether these catalyst may be regenerated. Then, for feasibility study of them, three methods were applied: washing, diffusion and milling the spent catalysts for their subsequent reproduction. A variety of techniques such as XRD, XRF, AAS, TPR and TPO were applied in order to identify factors contributing in vanadium pentoxide catalysts deactivation. The results showed that approximately all of pollutants caused their performance deterioration, while they still have some active phases. Then, the polluted catalysts were washed (their yield increased from 43% to 72.2%). In the underside of the... 

    Experimental Study of Using Cellulosic Compounds in Tissue Engineering

    , M.Sc. Thesis Sharif University of Technology Golizadeh, Mortaza (Author) ; Vossoughi, Manouchehr (Supervisor) ; Karimi, Afzal (Supervisor) ; Faghihi, Faezeh (Co-Supervisor)
    Abstract
    Fabrication and characterization of different surface charged cellulose electrospun scaffolds including cellulose acetate, cellulose, carboxymethyl cellulose and quaternary ammonium cationic cellulose for biomedical applications have been reported in this research. We describe preparation of cellulosic nanofibers through the electrospinning following deacetylation cellulose acetate. Moreover, surface modification of electrospun cellulose nanofibers is carried out to obtain carboxymethyl cellulose and quaternized cellulose nanofibers, respectively. At last, the structural, morphological, mechanical, swelling, wettability and the cell culture properties of the scaffolds were analyzed and...