Sharif Digital Repository

The observed response of medium rise buildings during sever earthquakes worldwide has indicated that RC buildings with shear walls behave considerably better than other buildings. The conviction that shear walls are inherently brittle still prevails amongst engineers, and therefore, they usually prefer to choose moment resisting RC frames without shear walls. In this study, a number of RC frames, with and without shear walls are designed in accordance with the seismic codes, and are then subjected to an assemble of severe earthquakes. The results of timehistory nonlinear analyses of these models are then used to investigate the effect of the presence of shear walls within the framework of... 

Today, Mg and Al as the widely used metals, make a special contribution to automotive, electronics and aerospace industries. Increasing the application of alloys of these metals, has extended the demand for reliable joint between alloys of these two metals. The main problem with the dissimilar joining of A356 alloy and AZ91 alloy is hard and brittle intermetallic compounds formation such as Mg17Al12 and Mg2Si which brings about welding strength reduction. By far, a large number of researches about dissimilar joining of AZ91 alloy and A356 alloy in semi-solid condition have not accomplished. In this method two fragments, one from AZ91 alloy and another from A356 alloy among which was a 2... 

Seismic behavior of multi-story frames widely has been studied in recently. So that such studies can lead the earthquakes-resistance system to better performance. The dramatic growth of computer processing power make it possible that nonlinear dynamic analysis of structures with great precision could be done. One of the advantages of nonlinear analysis is achieve behavioral performance of structures during an earthquake. Knowledge of the performance, enables us to identify structural weaknesses result in devising to improve these. The aim of this study is to evaluate the seismic performance of reinforced concrete frames have been improved, using different techniques. The frames are designed... 

After three decades of research, the concept of emotion as an aspect of initelligence in artificial systems, is still unclear. Most of emotion models in AI are aimed to simulate the emotional states of human in differenct levels of abstraction and functionality. Therefore, the concept of emotions in artificial systems is completely dependent on human being’s emotional states and can not be used as a general tool for improving the intellingence of artificial systems. In this thesis, we have tried to show that defining emotion in a more abstract level can expand the domain of its appications in AI. According to some existing theories about emotions, we modeled emotions as local semi-soloutions... 

Two-phase flows are widely used in petrochemical industry, chemical processes, boilers, nuclear reactors, cooling systems and air conditioning equipment. Since the problem of earth’s ozone layer and global warming, the analysis of flow characteristics in evaporators are necessary to improve performance of refrigerating systems and saving the environment. Most of the researchers have been studied the evaporation of two phase flow refrigerant through experimental studies and numerical analysis has less attention in the literature. In this Thesis, a mathematical model based on the two-phase separated flow model is developed to simulate the evaporation of pure refrigerant under constant heat... 

Different parts of this research are focused on developing FO membranes and improving their performance. For this purpose, thin film composite (TFC) membranes with fixed composition of polyethersulfone/polyamide (PES/PA) have been used to investigate the effect of nanocomposites containing transition metal dichalcogenides (TMDs) on their performance. The support layer in all cases is PES, which is prepared through the phase inversion process and does not contain any nanofillers. The modification process takes place in the polyamide layer by dispersing the desired nanoparticles in the aqueous monomer solution necessary to form this active layer. Identification and characterization of... 

The first part of this thesis describes the synthesis and characterization of several Mn, Fe and Mo complexes containing tridentate Schiff base and oxazoline ligands and their reactivities as catalysts in the oxidation of organic compounds like olefins and sulfides, as well. The crystal structures of newly prepared cis-dioxo-bis[2-(2′-hydroxyphenyl)-oxazolinato]molybdenum(VI), cis-[MoO2(phox)2] and (N-hydroxyphenyl-salicylidenamine)(acetylacetonato)ethanol iron(III), [FeIII(N-OPh-sal)(acac)EtOH] complexes have been described by X-ray crystallography. Due to the difficulties in the preparation of suitable single crystals of novel... 

This thesis deals with the front-End of an Integrated RFID Reader operated in 860MHz to 960MHz, which integrates a RF transceiver including PA, LNA and Mixer. In the receiver part, a power amplifier was fabricated and measured and in the transmitter part, LNA and Mixer were designed. There is a growing interest in utilizing CMOS technologies for RF power amplifiers (PAs). Although several advances have been made recently to enable full integration of PAs in CMOS, it is still among the most difficult challenges in achieving a truly single-chip radio system in CMOS. This is exacerbated by supply voltage reduction due to CMOS technology scaling and on-chip passive losses due to the conductive... 

Inert gold become catalytically active when dispersed in the form of nanoparticles. Isolated gold nanoparticles have demonstrated high catalytic activity for both oxidation and reduction reactions. In order to obtain high catalytic activity, gold nanoparticles are generally dispersed on support materials, among which oxides are commonly used. However, a substantial decrease in activity and selectivity of the immobilized catalysts is frequently observed due to the heterogeneous nature of these support materials in reaction media. In the course of our study on the metal-based catalysis for synthesis of organic compounds, we herein report that rod-shaped Au nanoparticles in aqua solution... 

The 2-(2′-hydroxyphenyl)-oxazoline ligand (Hphox) is generated from 1:1 condensation of methyl salicylate with 2-aminoethanol. Novel [Ru(Hphox)2(H2O)2] (Hphox = 2-(2′-hydroxyphenyl)-oxazoline ) complex has been synthesized and characterized by physic-chemical methods. Oxidation of sulfides catalyzed by the mixed-ligand ruthenium(II) complex [Ru(Hphox)2(H2O)2]using urea-hydrogen peroxide (UHP) as oxidant was investigated under mild condition within 1 h. The results showed that mixed-ligand ruthenium(II) complex was effective catalyst in oxidation of sulfides in whichsulfoxideswere the only products. Using this catalytic system in the oxidation of alkanes, ketones were obtained as the main... 

In this work, synthesized Fe3O4 magnetic nanoparticles andcoated with SiO2 to prepare magnetic core-shell nanoparticles. Then immobilized Schiff baseof iron and vanadium complexes on magnetic core-shell nanoparticles was prepared as a recoverable magnetic nano catalysts. These catalysts were named Fe3O4@SiO2@L1@Fe, Fe3O4@SiO2@L2@Fe and Fe3O4@SiO2@L3@V. Furthermore,olefines epoxidation, sulfides and alcohols oxidation were studied with using iron and vanadium magnetic nano catalysts. The supported catalysts were characterized by atomic absorption, FT-IR and UV–Vis spectra.The catalytic performance of the synthesized iron catalyst was tested for the epoxidation of cyclohexene, styrene and... 

This thesisconsiders new fundamental approaches to yield heterogeneous catalysts in to three sections. The first section described the immobilization of the molybdenum-Schiff base complexes in pores of SBA-15 in two different methodologies depending on the actual structure of the complexes., (i) stepwise formation of the complex by initial covalent anchoring of one of the components and consecutive solid phase synthesis consisting of the condensation of the other components of the salen complex (iii) one-step complex immobilization by covalent binding through the ligand.Based on the first methodology, we report the preparation of ordered mesoporous silica SBA-15 containing a molybdenum... 

In nature, catalysis is of vital importance in a wide variety of biochemical processes catalyzed by metalloenzymes. The functions performed by the metalloenzymes and their significance have inspired a range of biomimetic studies, and intense efforts have been concentrated on the synthesis of low molecular weight complexes to model the spectroscopic features of such enzymes. Concomitantly, a challenging frontier in the field of biomimetic chemistry is the development of highly reactive model compounds that are able to effect rapid and selective substrate conversion. Some important catalytic transformations that have gained attention in recent years involve the carbon-carbon coupling, olefin...