Sharif Digital Repository

The synthesis of new dispiropyrrolidines containing a thiophenone ring has been achieved by a one-pot, three-component 1,3-dipolar cycloaddition reaction. Unsaturated thiophenone dipolarophiles were reacted with azomethine ylides, generated in situ from sarcosine and cycloketone derivatives (isatin, ninhydrin, acenaphthoquinone), to produce the corresponding cycloadducts in good yields (70-90%). The cycloaddition reaction was found to be highly regio- and diastereoselective  

Aims. We aim to obtain time-series photometry of the very crowded central regions of Galactic globular clusters; to obtain better angular resolution thanhas been previously achieved with conventional CCDs on ground-based telescopes; and to complete, or improve, the census of the variable star population in those stellar systems. Methods. Images were taken using the Danish 1.54-m Telescope at the ESO observatory at La Silla in Chile. The telescope was equipped with an electron-multiplying CCD, and the short-exposure-time images obtained (ten images per second) were stacked using the shift-and-add technique to produce the normal-exposure-time images (minutes). Photometry was performed via... 

Current design codes provide empirical equations for the drift capacity of unreinforced masonry (URM) walls that are based on results of quasi-static cyclic shear-compression tests. Yet different experimental campaigns have used various approaches of imposing fixed-fixed boundary conditions at the wall top which may affect the test results. This article investigates, by means of numerical simulations, the influence of experimental setups on the force and drift capacities of in-plane loaded URM walls subjected to double-fixed conditions. It is shown that controlling the shear span or the top rotation while keeping the axial force constant leads to very similar results. Controlling the axial... 

Inverted perovskite solar cells (PSCs) have been introduced as better candidate for roll-to-roll printing and scale-up than their conventional configuration counterparts, while their fabrication is technically more demanding. The common light absorbing layer in inverted PSCs is the single cation methylammonium lead iodide (MAPbI3) perovskite, whereas mixed-ion perovskites are chemically more stable. In mixed-ion perovskites, where FA (formamidinium) is the main replacement for MA, the electron affinity is larger than in MAPbI3 perovskites, leading to possible barriers against photoelectron collection by the electron transporting layer (ETL). In this paper we report on a mixed-ion... 

Usually, resources are short in supply when earthquakes occur. In such emergency situations, disaster relief organizations must use these scarce resources efficiently to achieve the best possible emergency relief. This paper therefore proposes a multi-objective, multi-mode, multi-commodity, and multi-period stochastic model to manage the logistics of both commodities and injured people in the earthquake response. Also, a robust approach is developed and used to make sure that the distribution plan performs well under the various situations that can follow an earthquake. Afterwards, it proposes a solution methodology according to hierarchical objective functions and uses it to illustrate the... 

This paper presents an approach that integrates clinical methods with Neuro-Fuzzy system in order to diagnose Neonatal Jaundice in newborns. First, a fuzzy logic system designed with medical rules to model the uncertainty that exists in medical diagnosis. Then a fuzzy neural network with an evolutionary learning helps the system to learn the new data gained from the patient and to help the fuzzy system to update itself in an online manner. By combining the aforementioned systems, the proposed approach can help physicians to diagnose jaundice with low risk cost associated with this disease. © 2006 IEEE  

We use multifractal detrended fluctuation analysis (MF-DFA) to numerically investigate correlation, persistence, multifractal properties and scaling behavior of the hourly spot prices for the Spain electricity exchange-Compania O Peradora del Mercado de Electricidad (OMEL). Through multifractal analysis, fluctuations behavior, the scaling exponents and generalized Hurst exponents are studied. Moreover, contribution of fat-tailed probability distributions and nonlinear temporal correlations to multifractality is studied. © 2007 Elsevier B.V. All rights reserved  

Hematite is recognized as a promising photoanode for photoelectrochemical water oxidation to produce solar hydrogen due to its favorable properties. However, the high charge carrier recombination rate due to low electrical conductivity and sluggish oxygen reduction kinetics of pure hematite hinder its photocatalytic activity. This work proposed a new hematite-based heterostructure of Ti-Fe2O3/Fe2TiO5/FeOOH, synthesized through a hydrothermal method. The photoanode morphology was branched nanorods that expanded their surface area and improved charge transfer at the photoanode/electrolyte interface. In a novel and complement modification approach, a thin pseudobrookite interlayer was applied... 

Aims. In this paper, we present the analysis of time-series observations from 2013 and 2014 of five metal-rich ([Fe/H] > -1) globular clusters: NGC 6388, NGC 6441, NGC 6528, NGC 6638, and NGC 6652. The data have been used to perform a census of the variable stars in the central parts of these clusters. Methods. The observations were made with the electron-multiplying charge-couple device (EMCCD) camera at the Danish 1.54m Telescope at La Silla, Chile, and they were analysed using difference image analysis to obtain high-precision light curves of the variable stars. Results. It was possible to identify and classify all of the previously known or suspected variable stars in the central regions... 

Compound 3-benzyl-2H-pyrano[3,2-c]chromene-2,5(6H)-dione(3), was prepared and fully characterized. The vibrational modes (FT-IR) and NMR data ( 1H and 13C chemical shifts) were compared with the results of Density Functional Theory (DFT) method at the B3LYP/cc-PVTZ level. The calculated vibrational frequencies and NMR chemical shifts are in good agreement with the experimental results. The electronic (UV-Vis) spectrum was calculated using the TD-DFT method in CH2Cl2 with the Polarizable Continuum Model using the integral equation formalism variant (IEFPCM) and was correlated to the experimental spectra. The assignment and analysis of the frontier HOMO and LUMO orbitals indicate that... 

Miniaturized culture systems of hepatic cells are emerging as a strong tool facilitating studies related to liver diseases and drug discovery. However, the experimental optimization of various parameters involved in the operation of these systems is time-consuming and expensive. Hence, developing numerical tools predicting the function of such systems can significantly reduce the associated cost. In this paper, a perfusion-based three dimensional (3D) bioreactor comprising encapsulated human liver hepatocellular carcinoma (HepG2) spheroids are analyzed. The flow and mass transfer equations for oxygen as well as different metabolites such as albumin, glucose, glutamine, ammonia, and urea were... 

A Legendre polynomial expansion of electromagnetic fields for analysis of layers with an inhomogeneous refractive index profile is reported. The solution of Maxwell's equations subject to boundary conditions is sought in a complete space spanned by Legendre polynomials. Also, the permittivity profile is interpolated by polynomials. Different cases including computation of reflection-transmission coefficients of inhomogeneous layers, band-structure extraction of one-dimensional photonic crystals whose unit-cell refractive index profiles are inhomogeneous, and inhomogeneous planar waveguide analysis are investigated. The presented approach can be used to obtain the transfer matrix of an... 

The possibility of electromagnetic slow wave propagation in dielectric slab waveguides, when free two-dimensional interface charge layers are generated at film-substrate and film-cover interfaces, is already explored. In this paper, the propagation of electromagnetic slow waves supported by induced charge layers of nonzero thickness, whose induced charge densities have Gaussian profiles, is investigated for the first time. In order to analyze the effects of inhomogeneity in the conductivity profile, the electric field is expanded in terms of Hermite polynomials and each eigenmode is sought in the complete space spanned by them. © 2007 IEEE  

Discrete motion equations of an Euler-Bernoulli, Timoshenko and higher-order beams under a moving mass are derived for different boundary conditions. To this end, the reproducing kernel particle method (RKPM) has been utilized for spatial discretization, beside the extension of Newmark-β method for time discretization of the beams motion equations. The effects of significant parameters such as the beam's slenderness and velocity of the moving mass on the maximum deflection and bending moment of different beams are studied in some details. The results indicate the existence of a critical beam's slenderness mostly as a function of beam's boundary conditions, in which for slenderness lower than... 

Three-dimensional vectorial diffraction analysis of gratings is presented based on Legendre polynomial expansion of electromagnetic fields. In contrast to conventional rigorous coupled wave analysis (RCWA) in which the solution is obtained using state variables representation of the coupled wave amplitudes, here the solution of first-order coupled Maxwell's equations is expanded in terms of Legendre polynomials, where Maxwell's equations are analytically projected in the Hilbert space spanned by Legendre polynomials. This approach yields well-behaved algebraic equations for deriving diffraction efficiencies and electromagnetic field profiles without facing the problem of numerical... 

This study focuses on the numerical investigation and optimization of the heat-fluid transfer process within a novel cavity containing a ternary nanofluid (Cu–MgO–ZnO/water) influenced by a magnetic field. The research is conducted within a circular cavity featuring a cold wall and a complex internal heat source. The governing equations, converted into dimensionless form, are solved using a computational code based on the finite volume approach. The analysis encompasses the effects of a wide range of physical parameters, including the Rayleigh number (Ra), Hartmann number (Ha), magnetic field angle (α), radiation (Ra), nanoparticle shape factor (Sf), and porosity (ԑ). The results revealed... 

Perovskite solar cells (PSCs) are one of the most promising emerging energy-conversion technologies because of their high power conversion efficiencies (PCEs) and potentially low fabrication cost. To improve PCE, it is necessary to develop PSCs with good interfacial engineering to reduce the trap states and carrier transport barriers present at the various interfaces of the PSCs' architecture. This work reports a facile method to improve the interface between the perovskite absorber layer and the hole transport layer (HTL) by adding a small amount of acetonitrile (ACN) in the Spiro-OMeTAD precursor solution. This small amount of ACN dissolves the surface of the perovskite layer, allowing the... 

A mathematical model has been suggested for the numerical study of blood flow in a vessel due to the pumping action of the heart. Blood is assumed to contain some impurities in the form of chemically reactive species (undergoing a first-order irreversible reaction) and, being a hybrid nanofluid, also contains the nano-sized solid particles, thus forming a homogeneous mixture which is subjected to a pressure gradient (of trigonometric nature) in the horizontal direction. Human vessel is subjected to a transverse magnetic field and is presumed to be filled with plaque which is considered as a porous medium, and is mathematically modeled by applying the Darcy-Forchheimer theory. The nonlinear... 

Multi-site photoplethysmography is an optoelectronic technique that measures changes in blood volume associated with cardiac contraction. Photoplethysmogram (PPG) recording enables researchers to study the vascular and hemodynamic properties of human subjects. Currently, there is no commercial system available in the market to perform multi-channel PPG recording. The measurements can be obtained from fingertips, ear lobes and toes due to their low absorption and high degree of vasculature. The main objective of this project is to develop a suitable data compression algorithm for two-channel simultaneous high resolution wireless PPG recording system. MATLAB software was used during the... 

Fully supramolecular dendrosomes (FSD) as bi-phase drug delivery systems are reported in this work. For preparation of FSD, amphiphilic linear-dendritic supramolecular systems (ALDSS) have been synthesized by host-guest interactions between hyperbranched polyglycerol having β-cyclodextrin core and bi-chain polycaprolactone (BPCL) with a fluorescine focal point. Self-assembly of ALDSS in aqueous solutions led to FSD. They were able to encapsulate paclitaxel with a high loading capacity. The dendrosome-based drug delivery systems were highly sensitive to pH and temperature. They were stable at 20-37. °C and pH7-8, but dissociated and released drug at temperatures lower than 20. °C or higher...