Sharif Digital Repository

In this project rotational barrier of C-N bond in Ethyl N-(pyrrolidine carbotioate) has been studied using DNMR spectroscopy. Spectra were taken at various temperatures, and then with simulation of bandshape broadening pattern, rate constants of exchanges were obtained for all temperatures. For simulation of line-shape broadening SpinWorks software was used,which with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from simulations, were used for calculation of thermodynamic activation parameters (?G#, ?H#, ?S# and Ea#).Experimental ?G# 298value(Experimental) of 18.3 Kcal/mol for Ethyl N-(pyrrolidine... 

The coupling of optical and mechanical degrees of feedom via radiation pressure has been a subject of early research in the context of gravitational wave detection. Recent experimental advances have allowed studying the modifications of mechanical dynamics provided by radiation pressure. First, this thesis reviews the consequences of dynamic back-action in optical microcavities with mechanical degree of feedom, and presents a unified treatment of its two manifestations: the parametric instability (mechanical amplification or oscillation) and radiation pressure back-action cooling. Then, by considering the Fabry-Perot cavity with two movable mirrors, and using Multi-Reflection Method, we... 

Few years the traditional medicine in our society is considered: Traditional colleges have been established, Traditional medicine has been established and numerous media programs produced by experts in traditional medicine. All this indicates is that traditional medicine seek lost credibility and gain its rightful place in our society today. One of the most important aspects of the relationship between traditional medicine with modern medicine. On the one hand trying to make traditional medicine with modern medicine can be defined as complementary medicine. In this regard, first of all defined traditional medicine as a specialty, and efforts to rebuild the achievements of traditional... 

Despite the astonishing successes of quantum mechanics, due to some fundamental problems such as the measurement problem and quantum arrival time problem, the predictions of the theory are in some cases not quite clear and unique. Especially, there are various predictions for the joint spatiotemporal distribution of particle detection events on a screen, which are derived from different formulations and interpretations of the quantum theory. Although the differences are typically small, we show that these predictions can be experimentally distinguished by a proposed unconventional double-slit configuration, which is realizable using present-day single-atom interferometry. Furthermore, we... 

In recent years, a strong interplay between quantum mechanics and the physics of waveguide arrays was established based on a formal analogy between atomic and photonic lattices. The study of light evolution in photonic lattices has provided deep insights into the physics of wave function dynamics and, hence, peculiar quantum mechanical features. Arrays of evanescently coupled waveguides is a very versatile model system for discrete physics. Anderson localization and Bloch oscillations are two examples of coherent quantum transport phenomena, which have been investigated in this thesis. In the first part of this thesis, we investigate numerically the effect of long-range interaction on the... 

The goal of this thesis is to evaluate the strengths and weaknesses of the two existing formulations of Bohmian mechanics. The first one was proposed by Bohm, and emphasizes on the dynamics being second-order, and in which, the key tool for explaining the quantum phenomena is a non-classical potential, called "the quantum potential". In this approach, the postulates of de Broglie's "pilot-wave" theory, which now is known as Bohmian mechanics, are non-fundamental and are special to the atomic level. The possibility is proposed that these postulates become subjected to some modifications at the nuclear or lower levels, but no particular way for performing such modifications is suggested. The... 

Quantum mechanics is very succesful in the description and prediction of the microphysical world. So nowadays very few doubt its authenticity. Nevertheless, there are some conceptual issues that are still under debate, such as action at a distance. It took a while after the introduction of the EPR paradox in 1935 until John Stewart Bell derived an inequality, using local hidden variables. This inequality was in contrast with predictions of quantum mechanics. Experiments also contradicted this inequality. This implies that there is action at distance which, in turn suggests, the violation of the special relativity. In this thesis, we consider this issue and shall see that on the one hand we... 

For more than a century, physicists have recognized the contrast between the asymmetry of thermodynamic phenomena and T-symmetry of the fundamental laws, and they have referred to it as the arrow of time. In this thesis we tried to give an overview of the past and present status of this problem, using various theories. It is shown that the problem becomes a question about the boundary conditions of thermodynamic systems, and then a question about cosmology, and finally it becomes the problem of initial conditions of universe. An analysis of initial condition theories is presented for knowing how each of them tries to solve the problem of arrow of time. Different views about the relationship... 

One of the important issues in the fundamental physics is the arrow of time. According to the fundamental theories, motion is symmetry with respect to the passage of time while on a macroscopic level time has direction. In the macroscopic models the arrow of time is provided by the Second Law of Thermodynamics.The thermodynamic arrow is often linked to the cosmological arrow of time, because it is ultimately about the boundary conditions of the early universe.Recently people have tried to suppose this challenge as a fundamental issue and use this as fundamental assumption in their theories.A number of models have attempted to solve the problem based on the concept of information.... 

The influences of metaphysics in physical science in contemporary philosophy of science have the main place. In this article we consideration the scientific experiment and model for understanding of metaphysic influence .we answer the epistemological and metaphysical question about scientific experiment. We notice in the approximation in the scientific experiment and modeling. In this line we inference the exponential radiation law and consider approximation in this inference and conclude that from approximation, metaphysics of individual scientist influence in the future of physical sciences. We consider the role of model in scientific explanation and with this study we understand that... 

Nucleosynthesis and CMB data clearly indicate that most of the matter
in the universe is dark and non-baryonic. There’s no shortage of particle
physics candidates for this dark matter. This candidates can be classified
according to whether the dark matter particles originated via decoupling
from thermal bath or were created in some non thermal process. Thermal relics can be categorized further as to whether they were relatvistic or nonrelativistic at the moment of decoupling. The relics which were relatvistic at this time constitute hot dark matter, while those which where nonrelativistic constitute cold dark matter. The goal of this thesis is reviewing hot dark matter... 

In the early time of the discovery of the quantum mechanics and some decades after that, various interpretations of quantum mechanics were proposed. However, many years after that, the “indetermenistic” perspective well-known for Copenhagen perspective which was proposed mostly by Bohr and his colleagues became the dominant attitude among physicists. But nearly two decades after the fixation point of the Copenhagen perspective, a new interpretation of quantum mechanics was proposed by Bohm which was nonlocal but deterministic and it could reproduce all the predictions of quantum mechanics.Bohm’s theory responded to the many theoretical and philosophical objections assumed to the Copenhagen... 

Non-locality was taken into account, in the first place by Bell’s inequalities in Quantum Mechanics. With the emergence of non-locality, it seems that there is a fundamental conflict between the two basic theories of the 20th century, Quantum Mechanics and Relativity. Relativity is constructed upon local descriptions, but there are some hidden non-local features in Quantum Mechanics .Thus, superluminal signaling, which is in conflict with Relativity, has attracted a lot of attention and some ideas were proposed , using this non-local feature, to send superluminal signal. But, the no-signaling theorems claim that none of these features can be used to send superluminal signal. On the other... 

In the special theory of relativity, it is not necessary to propose that there is no privileged frame of reference but because this formalism is of the epistemological level, we can not deduce this ontological conclusion. On the other hand, there are different physical motivations for a privileged frame of reference and also there is an alternative physical model for special relativity called inertial transformations which is similar to the special theory of relativity at the observational level, but there is a privileged frame of reference in that theory. In this paper, I have tried to collect motivations for a privileged frame of reference in physics, in order to prepare a source for those... 

The worldview and value system can use a cognitive-normative framework to select and shape science and technology. Of course, this framework is not the sole factor in shaping and selecting science and technology. The context in which science and technology flourish is also an important factor. Thus a religious science and technology is possible. Furthermore one can find many examples in the contemporary science and technology which are rooted in a secular and naturalistic outlook., but one can shape a science and technology which are rooted in religious worldview and value system. These examples show that one can generate a religious type of science and technology ,but in order to do this... 

Natural sciences have philosophical and ideological fundamentals. "The attitude towards human", is one of these philosophic or metaphysical fundamentals of science so that scientists and researchers, attentive or not, take it as a basis for their scientific activities. In the other hand, "the science" also affects "The attitude towards human", and different scientific theories caused various attitudes towards human to take shape. "Renaissance" is one of the most important and sophisticated historical periods of the west`s history, and the changes in this period are among the main basics of entering the modern age. In this thesis, first of all some issues about the fundamentals of the science... 

The measurement problem is one of the issues that is still under debate about the Quantum theory. A significant part of literature during the recent years includes the standard point of view about this problem (including the separation of microscopic and macroscopic domains) and the criticisms of some major physicists in this context. Among these, alternative theories and interpretations have been getting more attention. Experimental tests of Quantum Mechanics in the macroscopic domain and their comparison with alternative theories have always encountered various difficulties (in particular the decoherence phenomenon). Anyway, towards the end of the last century, with the advances in...