Sharif Digital Repository

Herein, some (modified) paper–based substrates were prepared and utilized as extractive phases in a microfluidic device and their extraction performances examined for analytes with different polarities. Reagents including hexadecyltrimethoxysilane (HDTMS), phenyltrimethoxysilane (PTES), (3-aminopropyl) triethoxysilane (APTES) and 3–(2,3–epoxypropoxy) propyltrimethoxysilane (EPPTMOS) were implemented for the modification process. Due to the induction of different silane functional groups, it was anticipated to have various interactions for the tested analytes. Eventually, the prepared paper sheets were used as extractive phases for solid–phase extraction within a microfluidic system. The... 

In this study, a low–cost microfluidic device from polymethyl methacrylate was fabricated by laser engraving technique. The device is consisted of a central chip unit with an aligned microchannel. Both sides of the engraved microchannel were sandwiched by two synthesized sheets from polyamide/titania (PA/TiO2) hollow nanofibers as extractive phases. The inlet and outlet of the device were connected to the polyether ether ketone tubes, while a peristaltic pump was used to deliver both sample and desorbing solvent through the microchannel. The recorded scanning electron microscopy images from the surface of the synthesized PA/TiO2 nanofibers, exhibit a good degree of homogeneity and porosity... 

In nonlinear static (pushover) methods of analysis as an alternative to time history analysis, the capacity curve of the structure is established with respect to the roof displacement. Disproportionate increases in the roof displacement and even outright reversals of the higher modes can distort the capacity curve of the equivalent single degree of freedom system in these kinds of method, including MPA. To overcome this problem, recently, "Energy-Based" the Modal Pushover Analysis (Energy-Based MPA) method has been introduced. In this method, the absorbed energy and/or the external work in the pushover analysis is considered. Accordingly, the assessment of the Energy-Based MPA method is... 

A variety of aromatic amines are oxidized to their corresponding quinones in excellent yields by supported iodic acid under microwave irradiation and solvent free conditions  

A simple, high yield, and short time method for nucleophilic displacement reaction of inactive aryl halides is reported. The reaction is performed in microwave oven under thermal condition with montmorillonite supported AgNO 3  

The coupled three-dimensional flexural vibrations of a micro-rotating shaft–disk system, as a basic model for micro-engines, are investigated in this paper by considering small-scale effects utilizing the modified couple stress theory. Governing equations of motion are derived by the use of Hamilton’s principle. Then, implementing the Galerkin approach, an infinite set of ordinary differential equations is obtained for the system. With truncated two-term equations, expressions for the first two natural frequencies are written, and for the two corresponding modes, the maximum rotational speed up to which the system will be stable is analytically determined. Parametric studies on the results... 

In this work, some vibrational response parameters of strain gradient based micro-spinning Rayleigh beams with mass eccentricity distribution are investigated within infinitesimal deformation conditions. Governing equations of motion are derived utilizing the Hamilton’s principle. The gyroscopic effects and rotary inertia are both included in the formulation. By applying the Galerkin method, analytical expressions for natural frequencies of the micro beam in forward and backward whirl motions are obtained. In addition, an expression for the vibrational amplitude of the micro-beam due to mass eccentricity distribution is determined. Some numerical results are presented to study the effect of... 

In this study, several analytical expressions are obtained for the vibrational characteristics of a Jeffcott model for micro-rotor systems based on the strain gradient theory to investigate the small-scale effects on the model. The Jeffcott model consists of a massless microrotating shaft and a disk as a rotor with eccentricity. The disk is mounted on the middle of the shaft. Two second-order differential equations associated with the oscillating motion of the rotor in the plane perpendicular to the longitudinal axis are presented and transformed into a complex form. The stiffness of the system is determined by obtaining the deflection of a strain-gradient-based nonrotating microbeam... 

On the basis of the modified couple stress theory, some analytical results are obtained for vibrational parameters of micro-spinning Rayleigh beams with an axial mass-eccentricity distribution. The modified couple stress theory is a nonclassical continuum theory capable to capture the size effects in small-scale structures. After writing the governing equations of motion, they are transformed to the complex form. Then by utilizing the Galerkin method, analytical expressions for natural frequencies of the micro-spinning beam in forward and backward whirl motions are obtained. Critical speeds are also analytically presented in the two whirl motions for different modes. Moreover, the... 

This paper presents a new architecture for a DLL based frequency synthesizer for wireless transceivers. Owing to its DLL based nature, the synthesizer generates the target frequencies with minimum phase noise and jitter. To cover the desired frequency proposed architecture consists of mixer and divider. As an example, VHF frequency band of IRAN is covered. The circuit level design guidelines and power consumption trade-offs are presented. It was shown that for the mentioned standard a 40 delay cell and 9 switches for switching channels is sufficient. Simulation results confirm the analytical predictions  

This paper presents a new architecture for a DLL based frequency synthesizer. Occupying low area, lower power consumption and phase noise are the advantages of this novel architecture. DLLs are first ordered systems, so good stability can be obtained in this design. This structure also can be used for generating fractional multiple of reference frequencies. The proposed circuit can operate at a substantially low supply voltage. A case in point, the synthesizer is adopted to create the channel frequencies of French DVB-H/T standard. The circuit is designed based on 0.13um CMOS Technology. Also power consumption trade-offs are introduced. It was shown that 27 delay cells are sufficient to... 

A low power 10 bit, 40 MS/s pipeline analog to digital converter is presented. A number of low-power techniques are proposed in various levels of abstraction. In circuit level, a low power class A/AB opamp with direct common-mode-feedback circuit (CMFB) is proposed which significantly reduces power in the opamps. In backend design, optimal series capacitors are layed out to break the deadlock between the mismatch and loading effect of the first stage capacitors. A customized software tool is developed based on the proposed opamp and architecture which provides optimum stage scaling factors, tail current and opamp transistor sizes. Simulations in 0.13um CMOS technology show that the ADC... 

Objective: A novel electrocardiogram (ECG) classification algorithm is proposed for continuous cardiac monitoring on wearable devices with limited processing capacity. Methods: The proposed solution employs a novel architecture consisting of wavelet transform and multiple long short-term memory (LSTM) recurrent neural networks (see Fig. 1). Results: Experimental evaluations show superior ECG classification performance compared to previous works. Measurements on different hardware platforms show the proposed algorithm meets timing requirements for continuous and real-time execution on wearable devices. Conclusion: In contrast to many compute-intensive deep-learning based approaches, the... 

The random PRF method has been suggested for the design of LPD (low probability of detection) radar signals. The LPD improvement in using this kind of signal is discussed quantitatively. First, a detection theoretic approach is used to find the optimum detectors of the unauthorised receiver (ESM receiver) and their performance for both constant PRF and random PRF signals. Then, the effect of the random PRF method on the authorised receiver (radar receiver) is investigated. Based on these analyses and definition of a proper measure, the constant PRF signals are compared with random PRF signals from the LPD point of view. By finding a simple formula for the improvement caused by the random PRF... 

An efficient method is reported for selective oxidation of various types of sulfides to sulfoxides and sulfones in good to high yields using 30% H 2O2 in the presence of catalytic amounts of molybdate-based catalyst in acetonitrile as solvent at room temperature. The catalyst can be easily recovered and reused for seven reaction cycles without considerable loss of activity  

In this study, drastic influence of the intramolecular cation-π interaction on the basicity of selected amines has been considered. The optimized minimum energy geometries of different studied amines and their protonated structures were determined by using DFT calculations at the B3LYP/6-311++G(d,p) level of theory. Geometry optimizations indicate that the most stable structures of protonated amines are stabilized by intramolecular cation-π interaction. The proton affinity (PA) of selected amines is controlled by the strength of intramolecular cation-π interaction of ammonium with aromatic ring. These cation-π interactions strongly influence the basicity of amines. Natural bond orbital (NBO)... 

The Ugi reaction goes fast with high yields in a recyclable and biodegradable low-melting mixture of choline chloride and urea (DES) as a novel and efficient reaction medium. The DES is applicable to a wide range of aldehydes, amines, isocyanides, and acids in good to excellent isolated yields (60-92%) and short reaction times (2-5 h) and can be reused four times without any loss of activity  

A chemoselective synthesis of tetraketone and xanthene derivatives, by means of tandem Knoevenagel condensation and Michael addition in choline chloride-based deep eutectic solvents (DESs), is presented. The reaction of readily available aldehydes and active methylene compounds in malonic acid- and ZnCl2-based DES gives various xanthenes derivatives with good to excellent yields under mild reaction conditions. On the other hand, tetraketones were synthesized in almost quantitative yields by simple condensation of an aldehyde and active methylene compounds in milder deep eutectic solvents of urea and SnCl2. In addition, the reaction of other types of choline chloride-based DES leads to a...