Sharif Digital Repository

The objective of this research was to fabricate nanocomposites based on reduced graphene oxide (rGO) and strontium titanate (SrTiO₃) and investigate their photovoltaic properties as charge transport platforms in dye-sensitized solar cells (DSSCs). Initially, graphene oxide was prepared using the Hummers method and combined with strontium titanate through a ex-situ approach. Subsequently, strontium titanate based on reduced graphene oxide nanocomposites were obtained using thermal and solvothermal methods. Structural and optical characterization of these nanocomposites was performed using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, thermogravimetric... 

Fischer-Tropsch synthesis (FTS) is the main part of a Gas to Liquid (GTL) process. In this reaction which shall be done based upon iron or cobalt catalysts, H2 and CO molecules (namely Syngas) transform to long hydrocarbon chains. Regarding all of the advantages of cobalt catalysts in comparison with iron counterparts, Research Institute of Petroleum Industry (RIPI) began investigations since two decade ago. The present catalyst comprised of cobalt as active metal, ruthenium as activity promiter and lanthanum as support (gamma alumina) modifier. By the way, still some areas such as its lifetime duration and deactivation needs to be improved by complimentary researches. The present... 

PRP is a combination of two classic problems. First one is the lot-sizing and the second one is vehicle’s routing which have been studied for more than fifty years. The prp is solved in attempt to jointly optimize production, inventory, distribution, routing decision and as a result, it is a inventory-routing problem as a whole. Despite the fact that prp involves a complex instructor, both universities and industries have been so eager to this problem since last decade. In this thesis an integrated assessment of PRP and various technics for solving the problem have been discussed. Moreover, taking into account the structure, hypothesis, and the constraints of the problem, a... 

The goal of authenticated encryption is to ensure confidentiality, integrity and authenti-cation of the messages simultaneously. The anouncement of CAESAR comptetition has attracted esearchers’ attention to this branch of symmetric cryptography, since 2014. 57 schemes have been introduced as the first round candidates of this competition, from which 29 where selected as second round candidates. Cryptanalysis of these schemes needs a lot of collective effort. In this thesis after describing preliminaries of authen- ticated encryption, general structure of the schemes and their reported cryptanalysis is reviewed. Then, the details of Pr∅st family of authenticated encryption, which is one of... 

In this research, synthesis, structural and theoretical studies of rhnium(I) tricarbonyl complexes with general formula, fac-[Re(CO)3(NN)X] in which NN´ is chelating bidentate diimine ligand and X = Cl, Br, and OCOCF3 ligands were studied. The synthesized complexes were characterized by 1H-NMR and FTIR spectroscopic methods and their solid state structures were determined by X-ray diffraction analysis. Then, the reaction of the synthesized rhenium complexes were studied by copper(I) iodide. Crystal structure determination by single-crystal X-ray diffraction allows us to fully examine the intramolecular and intermolecular interactions. We also investigated the energy of different... 

Upstream oil industry operators have turned to optimal production methods for further recoveries, such as smart wells. Control algorithms for smart wells must be equipped with online measurements, in other words, reflected in the feedback philosophy. On the other hand, after discretization, an oil reservoir's dynamic and control-driven model becomes a realization or a large-scale and sparse state space. One way to deal with this problem and provide an appropriate model for the design of smart well controllers is to use appropriate reservoir dimensional reduction methods. Therefore, to design low-order controllers, a study must first be performed at the level of the reservoir model and its... 

Superparamagnetic Iron Oxide NPs (SPIONs) because of their multi-task capabilities (e.g. magnetic labeling, cell isolation, hyperthermiaand controlled drug release) have been recognized as one of the most promising NPs for theranosis applications.When NPs come in contact with a biological medium, the surfaces of them are covered by biomolecules (e.g., proteins, natural organic materials, and enzymes). Therefore, what a biological entity, such as cells, tissues, and organs, sees when interacting with NPs is different original pristine surface of the NPs and actually is hard protein corona. Shape of NPs has a great impact on proteins adsorb onto its surface and consequently on the way that... 

In this thesis, the copper oxide - zinc oxide nanocomposite was synthesized and functionalized using 3-aminopropyltrimethoxysilane. The functionalized nanocomposite was characterized using X-ray Diffraction spectroscopy (XRD), Fourier Transform Infrared (FT-IR), X-ray Fluorescence Spectroscopy (XRF), Scanning Electron Microscopy (SEM) and Brunauer–Emmett–Teller (BET). Dye removal from synthetic wastewater was done in a batch system using functionalized copper oxide - zinc oxide nanocomposite as adsorbent. Direct red 23, direct red 80 and direct red 81 were used for preparation of synthetic wastewaters. The effects of operational parameters such as adsorbent dosage, initial dye concentration,... 

One of the problems that affects the lifetime and cycle life of lithium ion batteries is the localized corrosion of aluminum current collector (during the storage and charging cycle). Since applying corrosion-resistant coating has always been one of the ways to reduce corrosion of materials in different environments, in the present project, this method has been used to prevent corrosion of aluminum in lithium-ion batteries. For this purpose, the graphene oxide coating, which has desirable anti-corrosion properties, was coated on aluminum by Electrophoretic deposition and doctor blade methods. linear polarization, cyclic voltammetry and electrochemical impedance spectroscopy were performed to... 

Superparamagnetic iron oxide nanoparticles (SPION) with proper surface coatings are increasingly being evaluated for clinical applications such as hyperthermia, drug delivery, magnetic resonance imaging, transfection, and cell/protein separation. Since the particles with various sizes exhibit different flow rates in the same environment (same capillary size), it is essential to use particles of a desirable size for targeted drug delivery and imaging. Particles of different sizes may be exposed to different viscosities and behave differently, particularly with regard to their velocities as they move through capillaries. In the present work, SPION with different size, purity, shape and... 

In this research, nano composite MgH2-TiCr1.2 Fe0.6 nano crystalline was synthesized by mechanical alloying and Vacuum arc re-melting (VAR). the effect of Milling conditions and adding nano crystalline TiCr1.2 Fe0.6 as a catalyst on the structure and hydrogen desorption properties of MgH2 were studied. MgH2 powder grain size after 4 hours milling gained to 15nm and strain network reached to 0.8%. Determined that the increasing of accumulated lattice strain because of mechanical milling combined with adding nano crystalline alloy TiCr1.2 Fe0.6 significantly improve the properties of MgH2 hydrogen desorption. After an hour mill working, high pressure phase of γ-MgH2 was appeared in... 

In classical vehicle routing problems, a fixed and specific location is considered for each customer, which in many cases does not reflect reality. Many customers change their locations when distribution is carried out, and in some cases, it is challenging to predetermine their locations. This thesis proposes and develops the Vehicle Routing Problem with Mobile and Stochastic Customer Locations (VRP-MSCL), a subproblem of last-mile delivery. The concept of mobile and stochastic customer refers to a type of customer who is constantly moving, lacks a fixed location, and cannot be identified in advance; however, forecasting customers’ locations in advance is possible. This concept introduces a... 

Simulation and controlling nonlinear process is one of the challenging problems in academic and industrial research. Saving data for keeping history of process or arising number of calculation for optimization in control design, is forcing to decrease number of equation or order of system. One of the methods to decrease the order of distillation process is using the travelling wave theory. This solution shows god accuracy for simulation the behavior of distillation column. On the other hand finite difference method as a solver for distillation equation takes some time to converge to steady state condition and the numbers of calculation in this method are high. Finite difference method is... 

Surfactants are widely used in enhancing oil recovery. But application of worm-like micelles which seem to be a perfect candidate for enhancing heavy oil recovery have been less studied despite their significant ability in reducing interfacial tension and their high viscosity. This research consists of three parts. In the first part, the kinetic and equilibrium adsorption of surfactant on reservoir rock is experimentally investigated, and its appropriate kinetic and equilibrium adsorption model is specified. According to the adsorption models, the pseudo second order kintic coefficient of adsorption is proved to have a linear relationship with concentration, so its value at different... 

Diabetes mellitus is a global endemic that is rapidly increasing prevalence in both developing and developed countries. Recently, the American Diabetes Association has recommended the hemoglobin A1c as a possible substitute to fasting blood glucose for diagnosis of diabetes because it is an indicator of long-term glycemic control. Also, centrifugal microfluidics systems have a good potential to be used in the point of care testing systems. In this study, two centrifugal microfluidic discs were designed and manufactured in order to separately measure the hemoglobin and hemoglobin A1c in the whole blood. In the first part of the study, the hemoglobin measurement disc consists of two chambers... 

This master’s thesis has two major parts. The first part which includes chapters 1 to 8, describes the article A. Pfister, Quadratische Formen in beliebigen Körpern, Invent. Math. 1, (1966)pp. 116-132, and expresses important facts about the Witt ring W(K) of quadratic forms over an arbitrary field K of characteristic unequal to 2. Among those, it is shown that the order of each element in the additive group of W(K) is a power of 2, the Witt ring doesn’t have any zero divisor of odd dimension and a necessary and sufficient condition for W(K) to be an integral domain is given. The connections between the square class number of a field and the cardinality of its Witt ring and, providing some... 

This thesis contains four chapters. In first chapter the role of water in organic reactions as a ecofriendly solvent, computational chemistry and dynamic nuclear magnetic resonance were studied. In the second chapter synthesis of new 4-hydroxy pyrrole derivatives in water were reported. For the synthesis of these compounds arylglyoxal derivatives, 1,3-dicarbonyl compounds and ammonium acetate were used. The reaction conditions are very mild. The third chapter contains the synthesis of new (4 or 5)-Aryl-2-aryloeil-(1H)-imidazole compounds in aqueous media. We also investigated the tauto-isomerisation of isomeric imidazoles during this reaction using DNMR technique. In forth chapter a... 

This thesis contains two parts .In the first part a catalyst such as AlCl3/Al20 has been demonstrated to catalyze Michael addition reaction of amines to a,�- unsaturated compounds with high yields , short reaction time and under solvent-free condition.The Michael addition to a,�- unsaturated compounds produces quantitively the mono addition products.The next part is about olefins epoxidation . Alkene epoxidation is a useful reaction in organic synthesis. Epoxides play an important role in industrial intermediates for the production of fine chemicals as well as pharmaceuticals .The hydrogen peroxide has been used as an oxidant because it is considered as an economical and appropriate reagent... 

Enanthioselective synthesis of biological molecules are so important in synthetic chemistry, and because of their biological activities, β-amino carbonyl compounds have earned so much attention in this area of chemistry. Mannich reaction is a classical method for synthesis of these molecules. The Mannich reaction is a three-component reaction between an enolizable CH-acidic carbonyl compound, an amine, and an aldehyde producing β-amino carbonyl compounds. But acidic or basic difficult circumstances, long reaction time, low yield and enantioselectivity, are the drawbacks of classical methods. In this project, we used titania-based solid acid as an enantioselective catalyst to overcome these...