Sharif Digital Repository

Recently, the applications of two dimension materials have been increased in nanotechnology. Among this group of material the Transition metal dichalcogenide due to their energy gap and their particular optical features has attracted much attention. For instance MoS2 is a most famous material in this familyand as a semiconductor has an indirect energy gap about 1.3 eV in the bulk status and 1.9 eV in monolayer. In this project, we investigated the Nano-sheet optical properties of MoS2 by using of tunneling spectroscopy. In this procedure a thin probe is close to the surface until a quantum tunneling occurs between the probe and the sample. By measure the tunneling current we can achieve much... 

Oxygen gas has many applications and is used in respiration, welding, methanol production, steel industry, rocket fuel and most importantly fuel cells. Today, due to the environmental pollution caused by fossil fuels, the use of clean energy production methods such as fuel cells has received much attention. In hydrogen fuel cells, electrical energy is generated using oxygen and hydrogen gases through an electrochemical process. One of the common methods of producing these gases is electrolysis of water in which the kinetics of anodic reaction (oxygen evolution) have led to many researches in the field of improving metal and non - metal electrocatalysts, especially based on carbon... 

Developing a simple, cost effective and accurate detection method for L-lysine (Lys), L-leucine (Leu) and glycine (Gly) as the important analytes in clinical diagnostics, biological processes and food industries is of great interest. Therefore, in the first part of this research, cellulose nanofibrils (CNFs) were coated on a quartz crystal microbalance (QCM) surface by spin coating to achieve a QCM biodetector for Gly. Thus, the two-layer CNFs coating was selected as sensing film and was applied for following experiments. In the next step, the coated QCMs were carefully characterized before and after interaction with Gly using water contact angle (WCA), Fourier transform infrared... 

Many aroma compounds of fruit juice recovered by thermal evaporation and distillation processes can lead to undesirable chemical changes and even their loss. Pervaporation is a promising process for the recovery of volatile organic compounds from their aqueous solutions. In the present work, pervaporation recovery of Ethyl acetate as a model solution of apple juice’s aroma compound was evaluated with polyvinylidene fluoride (PVDF) and ethylvinylacetate (EVA) membranes. For PVDF and PES membranes in the feed concentration of 250-1000 ppm and the operating temperature of 30 ºC, separating factor , respectively, was obtained in the range of 67-70 and 49-53, and also total permeation flux was... 

Developing a simple, cost effective and accurate detection method for L-lysine (Lys), L-leucine (Leu) and glycine (Gly) as the important analytes in clinical diagnostics, biological processes and food industries is of great interest. Therefore, in the first part of this research, cellulose nanofibrils (CNFs) were coated on a quartz crystal microbalance (QCM) surface by spin coating to achieve a QCM biodetector for Gly. Thus, the two-layer CNFs coating was selected as sensing film and was applied for following experiments. In the next step, the coated QCMs were carefully characterized before and after interaction with Gly using water contact angle (WCA), Fourier transform infrared... 

Noise or noise pollution, is defined as an unwanted sound, produced mostly by motor vehicles in urban areas. If the noise exceeds its limit, adverse effects on users and citizens are expected. Thus the assessment of the noise level and its comparison with allowable values is mandatory. Traffic induced noise depends upon different factors such as traffic, weather, and, sound barriers. Noise pollution study has a long history all over the world. Many studies, mostly representing the outdoor noise pollution models, have been done in recent years. This paper presents an assessment of traffic-induced noise in a heavily traveled tunnel, locally referred to as Resalat tunnel, which is located in... 

Data collected from street networks show that travel time in urban street networks is a stochastic variable, whose range of variation increases with the congestion level. Work and school trips comprise the major part of morning peak volumes, whose common characteristic is that they need to be made on time. For this reason, these travelers are pessimistic in their route choice, and try to choose routes which are more reliable. Travel time standard deviation is one of the common measures for estimating travel time reliability that is related to properties of day-to-day travel time distribution on a particular route. Based on the empirical data collected from Tehran street network, this paper... 

With the advancement of automotive industry, the number of electronic systems that need to communicate with each other has increased. An effective strategy to meet these growing demands is using bus-based protocols, which can establish safe communication among numerous nodes with reasonable cost, weight, and space requirements. The objective of this thesis is the design and implementation of a transceiver based on the FlexRay protocol. The significance of this protocol lies in its ability to provide higher data transmission rates compared to other protocols like CAN and LIN, and its role as the foundational communication medium among various domains in modern vehicle architectures. In this... 

In this thesis, we introduce a novel Artificial Intelligence (AI) system inspired by the philosophical and psychoanalytical concept of imagination as a ``Re-construction of Experiences". Our AI system is equipped with an imagination-inspired module that bridges the gap between textual inputs and other modalities, enriching the derived information based on previously learned experiences. A unique feature of our system is its ability to formulate independent perceptions of inputs. This leads to unique interpretations of a concept that may differ from human interpretations but are equally valid, a phenomenon we term as ``Interpretable Misunderstanding". We employ large-scale models,... 

Quantum entanglement is an essential resource in quantum information processing, such as quantum communication and quantum computing. Although entanglement is critical for practical implementations in these fields, creating and transmitting entanglement without altering the states is challenging. External noise may destroy or weaken the entanglement. Consequently, there is a need for methods to improve entanglement. Entanglement distillation is an effort to address this issue. It is a process where, probabilistically, a smaller number of strongly entangled states are created from a fixed number of noisy entangled states. This process is carried out using only local operations and classical... 

The interesting properties of metallic nanowires provide many applications in electronic sensors. In this project, we have synthesized Pd nanowires using electrodeposition method. These nanowires are useful for hydrogen sensors by measuring field ionization current in gas. In this project, Pd nanowires were synthesized by electrochemical deposition method in PCT template with 100 nm pore size. The used solution was contained 2mM PdCl2 + 0.1M HCl. The best reduction potential was determined about -0.2V and the best time for synthesizing nanowires was 7 minutes. Chronoampermetric diagrams showed four steps, capacitive current, growth in the holes, reaching to the surface of PCT and the growth... 

In this research, non-isothermal annealing process at temperatures ranging between 400°C to 830 °C was investigated in warm and cold-rolled austenitic stainless steel 304L. First, the wide variety of austenitic to martensitic structure was produced by the multi-pass rolling process at room temperature -8 °C, 200 °C, and 280°C. The n exponent in Olson-Cohen equation was governed 2.83 after non-linear curve fitting to assess the fraction of deformation-induced martensite as a function of strain. Afterward, Abaqus/Explicit method was utilized to achieve the stored energy and plastic strains distribution through the thickness. Then, Cellular automata and Galerkin-finite element models were... 

Duringfalling a viscous liquid freely on a surface, the viscous thread bends due to a phenomenon called buckling. The gravity force in this process could be replaced by an electric force in electrospinning process. In the present thesis, we have designed a number of setups in order to investigate the buckling phenomenon in two categories of helical and non-helical buckling by using direct electrospinning process. By making the collector moving, the electrospun fibers show several shapes including coiling, meander, figure of 8 shape, etc. There are three effective forces acting in this process which are viscous force, electric force and inertia. Also there are three distinct regimes defined... 

In this research we focus on study and fabrication of titanium dioxide nanofibers and their application in preparation of dye sensitized solar cell’s photo anode in order to improve optical and electrical properties. Titanium dioxide nanofibers was prepared by electroespinning method. To investigate the effect of nanofiber diameter on optical and electrical properties of photo anode, three different diameter of titanium dioxide nanofibers with diameters of 100-200 nm, 200-300 nm and 500-600 nm was prepared by varying the type or amount of polymer in the electrospinning solution and fixing other conditions of electrospinning process. By use of these structures, paste of pure fibers in form of... 

Graphene is one of the most attractive subjects for scientists in the last decade. Its unique properties has been probed by many research groups and innumerable projects have been developed to investigate applications of graphene in electronics, mechanics, biophysics etc. Due to high surface to volume ratio and magnificent electron mobility in graphene, it is a suitable candidate for gas sensing. This has been proved by several theoretical and experimental researches for various gases such as CO, NH3 and NO2 etc. In present thesis, graphene has been prepared chemically and transferred to silicone substrates that are previously coated with a 300 nanometer silicone dioxide layer, by dip... 

The purpose of this project is to construct a gas sensor based on one-dimensional nanostructured electrodes of copper oxide. By creating of these nanostructures, can be reduced breakdown voltage of gases, including flammable, to a few hundred volts. The CuO nanowires were grown by thermal oxidation on copper substrate to form self-assembled. In this method, by heating the copper foil,Cu2O also was formed on substrate. Effects of surface tension of substrate and oxidation temperature on surface density and structure of the nanowires were studied. SEM images taken from the samples showed that the surface tensions increases the density of nanowires and increasing the oxidation temperature leads...