Sharif Digital Repository

Oxygen reduction on a polycrystalline silver electrode was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The reaction occurred by a two-electron pathway. The steps in the mechanism were observed in the cyclic voltammograms recorded with different scan rates. The intermediates formed in the steps were detected by electrochemical impedance spectroscopy  

Background: The development of endoscopic sinus surgery (ESS) training simulators for clinical environment applications has reduced the existing shortcomings in conventional teaching methods, creating a standard environment for trainers and trainees in a more accurate and repeatable fashion. Materials and methods: In this research, the validation study of an ESS training simulator has been addressed. It is important to consider components that guide trainees to improve their hand movements control in the orbital floor removal in an ESS operation. Therefore, we defined three tasks to perform: pre-experiment learning, training, and evaluation. In these tasks, the critical regions introduced in... 

In this letter, we propose a method for real-time high density impulse noise suppression from images. In our method, we first apply an impulse detector to identify the corrupted pixels and then employ an innovative weighted-average filter to restore them. The filter takes the nearest neighboring interpolated image as the initial image and computes the weights according to the relative positions of the corrupted and uncorrupted pixels. Experimental results show that the proposed method outperforms the best existing methods in both PSNR measure and visual quality and is quite suitable for real-time applications  

The ideal simulator for Endoscopic Sinus and Skull Base Surgery (ESSS)training must be supported by a physical model and provide repetitive behavior in a controlled environment. Development of realistic tissue models is a key part of ESSS virtual reality (VR)-based surgical simulation. Considerable research has been conducted to address haptic or force feedback and propose a phenomenological tissue fracture model for sino-nasal tissue during surgical tool indentation. Mechanical properties of specific sino-nasal regions of the sheep head have been studied in various indentation and relaxation experiments. Tool insertion at different indentation rates into coronal orbital floor (COF)tissue is... 

All costs within the life cycle of a building are known as its life cycle cost (LCC). In the design process of a building, the use of a lower initial cost index to select an option among others with similar performance may not lead to an economically optimal alternative during the life cycle. Hence, today, building designers and investors require a tool to estimate life cycle cost at the conceptual design stage to select an economically efficient option. Resilient solutions generally lead to a higher level of complexity and upfront costs and carry additional embodied environmental impact as well. This study aims to support the design of resilient buildings using a sound LCC methodology in... 

A luminescent coating of CaAlSiN3:Eu2+ particles applied on photoanode (TiO2) layer of SQ1 sensitized solar cell by doctor blading the paste of phosphor particles. The luminescent layer acted as a dual functional layer and enhanced the short circuit current density (JSC) by 64% via both scattering effect and downshifting of the photons in 400-600nm spectral range to photons in 600-800nm spectral range. Considerable relative enhancement in incident photon to current conversion efficiency (IPCE) up to 350% in 400-600nm spectral range proves the down shifting effect as the dominant factor for the improved performance of dye sensitized solar cell (DSSC). © 2016 Elsevier B.V  

In this paper, we suggest a general model for the fixed-valued impulse noise and propose a two-stage method for high density noise suppression while preserving the image details. In the first stage, we apply an iterative impulse detector, exploiting the image entropy, to identify the corrupted pixels and then employ an Adaptive Iterative Mean filter to restore them. The filter is adaptive in terms of the number of iterations, which is different for each noisy pixel, according to the Euclidean distance from the nearest uncorrupted pixel. Experimental results show that the proposed filter is fast and outperforms the best existing techniques in both objective and subjective performance measures... 

Ground improvement techniques are inevitable for weak soils that cannot endure the design load imposed by superstructures. Deep mixing technique (DMT) as one of these methods is promising and effective when a deep soil layer with low bearing capacity is encountered. Such deposits are quite common in the South-west of Iran where the studied site is located. In order to validate the influence of DMT on the enhancement of strength, both in-situ and laboratory tests were conducted. Afterwards, a parametric study was carried out to investigate the influence of key factors including cement content, water–cement ratio, curing time and plasticity index (PI) on the performance of DMT. In summary, a... 

The effect of electrostatic field on the aggregation rate and aggregate size of asphaltene particles precipitated from three different crude oil samples suspended in a mixture of toluene and n-heptane (a model oil) was investigated. An electrode-embedded glass micro-model utilizing a high-voltage direct current power supply was utilized in this study. The asphaltene particle size and the rate of aggregation under the electric field were monitored using a high-resolution optical microscope and the average aggregate size for asphaltene particles was estimated using image processing software. To investigate the effects of structural parameters on asphaltene aggregation rate, aggregate size and... 

Abstract In this paper, the solution of multi-group neutron/adjoint equation using Finite Element Method (FEM) for hexagonal and rectangular reactor cores is reported. The spatial discretization of the neutron diffusion equation is performed based on two different Finite Element Methods (FEMs) using unstructured triangular elements generated by Gambit software. Calculations are performed using Galerkin and Generalized Least Squares FEMs; based on which results are compared. Using the power iteration method for the neutron and adjoint calculations, the neutron and adjoint flux distributions with the corresponding eigenvalues are obtained. The results are then validated against the valid... 

Currently, the main portion of knowledge is stored in electronic texts and documents and for transferring that knowledge effectively, we must use proper methods to gather and retrieve relevant information. Ontologies provide means to produce structured documents and use intelligent search instead of keyword search. Ontology defines the common words and concepts used to describe and represent an area of knowledge. However, developing ontologies is a time consuming and labor work. So, many ontology developers try to facilitate and speed up this process by reusing other resources. In fact, thesaurus contains semantic information and hierarchical structure that make it an appropriate resource... 

Probabilistic thermal buckling analysis of composite plates with temperature-dependent properties under stochastic thermal fields is performed by developing a new temperature increment-based algorithm for solving the stochastic nonlinear equation. The temperature distribution is assumed to be a stochastic Gaussian field which leads to spatially varying stochastic mechanical properties. The stochastic thermal field is decomposed by applying the Karhunen–Loeve theorem. The combination of stochastic assumed mode method and polynomial chaos is proposed as an alternative solution for the time-consuming stochastic finite element method. The uncertainty of the critical temperature is studied by... 

Ground improvement techniques are inevitable for weak soils that cannot endure the design load imposed by superstructures. Deep mixing technique (DMT) as one of these methods is promising and effective when a deep soil layer with low bearing capacity is encountered. Such deposits are quite common in the South-west of Iran where the studied site is located. In order to validate the influence of DMT on the enhancement of strength, both in-situ and laboratory tests were conducted. Afterwards, a parametric study was carried out to investigate the influence of key factors including cement content, water–cement ratio, curing time and plasticity index (PI) on the performance of DMT. In summary, a... 

Ground improvement techniques are inevitable for weak soils that cannot endure the design load imposed by superstructures. Deep mixing technique (DMT) as one of these methods is promising and effective when a deep soil layer with low bearing capacity is encountered. Such deposits are quite common in the South-west of Iran where the studied site is located. In order to validate the influence of DMT on the enhancement of strength, both in-situ and laboratory tests were conducted. Afterwards, a parametric study was carried out to investigate the influence of key factors including cement content, water–cement ratio, curing time and plasticity index (PI) on the performance of DMT. In summary, a... 

The corrosion behavior of different grades of commercial aluminum such as AA1040, AA5083, AA6060 and AA7075 in ZnO-containing 4 M NaOH has been determined by using open circuit potential-time measurements (OCP), galvanostatic and potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results of scanning electron microscopy (SEM) and energy dispersive analysis of X-ray (EDAX) reveal that ZnO produces the inhibition effect by the formation of a zinc-containing deposit layer on the surface of aluminum electrodes. Although the influence of zincating on the performance of aluminum alloys and considering the amount of alloying elements such as zinc, magnesium and... 

Protein separation and purification technologies play an essential role in various industries including but not limited to pharmaceuticals, dairy as well as the food sector. Accordingly, a wide variety of techniques such as chromatography and electrophoresis have been developed and utilized extensively over the years for this purpose. Despite their widespread acceptance, conventional techniques still suffer from major limitations and complexities such as short lifetime, low productivity, high-pressure drop and difficulty in scale-up among others. Membrane separation processes have received significant attention in recent years as a promising alternative that can potentially overcome the... 

In this paper, a novel fast straightforward method for thermal generating units scheduling is presented. The new method decomposes the solution of the unit commitment (UC) problem into three subproblems. In the first subproblem, the quadratic cost functions of units are linearized and hourly optimum solution of UC is obtained considering all constraints except the minimum up/down time constraints. In the second subproblem, the minimum up/down times are enforced through a novel optimization process by modifying the schedule obtained in the first step. Finally, in the third subproblem, the extra reserve is minimized using a new decommitment algorithm. For testing the proposed method, the... 

Due to high surface to volume ratio and tunable band gap, two dimensional (2D) layered materials such as MoS2, is good candidate for gas sensing applications. This research mainly focuses on variation of Density of States (DOS) of MoS2 monolayes caused by ethanol adsorption. The nanosheets are synthesized by liquid exfoliation, and then using Scanning Tunneling Spectroscopy (STS) and Density Functional Theory (DFT), local electronic characteristic such as DOS and band gap in non-vacuum condition are analyzed. The results show that ethanol adsorption enhances DOS and deform orbitals near the valence and conduction bands that increase transport of carriers on the sheet. © 2018 IOP Publishing... 

Phytoremediation has been applied for treating an extensive range of environmental contaminants such as anti-diabetic drug metformin which is increasingly found as environmental contaminant. These contaminants are released to the environment via human and veterinary medicine and pharmaceutical industries. In this study, native plant capabilities for uptake of metformin from wastewater were investigated. Moreover, uptake rate of metformin was studied in two different concentrations of 20 and 50 mg l−1 metformin solution by Amaranthus retroflexus, Ricinus communis, Brassica napus, Celosia cristata, Helianthus annuus and Phragmites australis. The results showed that after exposing to 20 mg l−1... 

A luminescent coating of CaAlSiN3:Eu2+ particles applied on photoanode (TiO2) layer of SQ1 sensitized solar cell by doctor blading the paste of phosphor particles. The luminescent layer acted as a dual functional layer and enhanced the short circuit current density (JSC) by 64% via both scattering effect and downshifting of the photons in 400–600 nm spectral range to photons in 600–800 nm spectral range. Considerable relative enhancement in incident photon to current conversion efficiency (IPCE) up to 350% in 400–600 nm spectral range proves the down shifting effect as the dominant factor for the improved performance of dye sensitized solar cell (DSSC). © 2016 Elsevier B.V