Sharif Digital Repository

The nitrate-citrate gel exhibits auto-catalytic behavior, which can be used to synthesize nanocrystalline YIG powders. In this study, yttrium iron garnet (Y3Fe5O12) nanocrystalline powders were prepared by a sol-gel auto-combustion process. The influence of metal nitrates to citric acid molar ratio (MN/CA) of the precursor solution on the combustion behavior and crystallite size of synthesized powders was investigated by scanning electron microscopy (SEM), thermal analyses (DTA/TGA) and X-ray diffraction (XRD). The results show that with increasing MN/CA value, the combustion rate increases and the single-phase YIG forms at a higher temperature. The crystallite size of the single phase YIG... 

Nanocrystalline Y3-xMMxFe5O12 powders (MM denotes Misch-metal, x = 0.0, 0.25, 0.5, 0.75, and 1.0) were synthesized by a sol-gel combustion method. Magnetic properties and crystalline structures were investigated using X-ray diffraction (XRD), a vibrating sample magnetometer (VSM), and a scanning electron microscope. The XRD patterns showed that the single-phase garnet of Y3-xMMxFe5O12 was formed at x values ≤ 1.0. The saturation magnetization of powders increased with decreasing MM content and reached the maximum value at Y3 Fe5O12. The crystallite size of powders calcined at 800°C for 3 h was in the range of 38-53 nm. © 2008 American Ceramic Society  

The nitrate-citrate gels exhibit auto-catalytic behavior, which can be used to synthesize the nanocrystalline YIG powders. In this study yttrium iron garnet (Y3Fe5O12) nanocrystalline powders were prepared by a sol-gel auto-combustion process. The influence of pH value of the precursor solution on the combustion behavior and the garnet phase formation of synthesized powders were investigated by scanning electron microscopy (SEM), thermal analysis (DTA/TGA), infrared (IR) spectroscopy and X-ray diffraction technique (XRD). The results show that with increasing pH value, the combustion rate increases. The as-burnt powder prepared with pH 1 yielded a single phase YIG after calcination at 800... 

In this study, UV‐Vis-NIR photodetectors based on decorated ZnO nanofibers (NFs) with optimized coverage of Au nanoparticles (NPs) fabricated via combined simple electrospinning and sputtering techniques are introduced. The effect of different coverages of Au NPs resulted from different Au nominal layer thicknesses on the morphology and optical properties of the ZnO fibers are investigated through various characterization methods. It is discovered that 4 nm Au nominal thickness provides the highest UV on/off ratio (~460), responsivity (~332 A/W), detectivity (~2.93×10 11 Jones) as well as faster rise and decay times as compared to pure ZnO nanofibers. A broad spectral response from UV to NIR... 

This work aims to develop a nonlinear layerwise shell element formulation for shear-deformable laminated composite plate and shell structures. The element is formulated based on a zigzag theory in presence of individual local coordinates in the thickness direction for separate layers. In order to properly employ the zigzag theory, the considered local coordinates have different ranges of variation for middle, upper and lower layers. Using Mindlin-Reissner theory a convenient displacement field is derived for each layer and an ordered algorithm is adapted to calculate increments in the director vector of each layer due to relative finite rotations of its adjacent layers. Employing this shear... 

Handling recurring concepts has become of interest as a challenging problem in the field of data stream classification in recent years. One main feature of data streams is that they appear in nonstationary environments. This means that the concept which the data are drawn from, changes over the time. If after a long enough time, the concept reverts to one of the previous concepts, it is said that recurring concepts has occurred. One solution to this challenge is to maintain a pool of classifiers, each representing a concept in the stream. This paper follows this approach and holds an ensemble of classifiers for each concept. As for each received batch of data, a new classifier is created;... 

Data streams have some unique properties which make them applicable in precise modeling of many real data mining applications. The most challenging property of data streams is the occurrence of "concept drift". Recurring concepts is a type of concept drift which can be seen in most of real world problems. Detecting recurring concepts makes it possible to exploit previous knowledge obtained in the learning process. This leads to quick adaptation of the learner whenever a concept reappears. In this paper, we propose a learning algorithm called Pool and Accuracy based Stream Classification with some variations, which takes the advantage of maintaining a pool of classifiers to track recurring... 

One of the main challenges of data streams is the occurrence of concept drift. Concept drift is the change of target (or feature) distribution, and can occur in different types: sudden, gradual, incremental or recurring. Because of the forgetting mechanism existing in the data stream learning process, recurring concepts has received much attention recently, and became a challenging problem. This paper tries to exploit the existence of recurring concepts in the learning process and improve the classification of data streams. It uses a pool of concepts to detect the reoccurrence of a concept using two methods: a Bayesian, and a heuristic method. Two approaches are used in the classification... 

In this study, nanostructure zinc oxide (ZnO) films with different thicknesses were sprayed on glass substrates by controlling deposition time. Morphology and roughness of the films were investigated with scanning electron and atomic force microscopes as well as X-ray diffractometer. Considering with structure and surface roughness, two different growth modes as a function of spray time were determined: lateral and vertical modes which were illustrated schematically. Optical properties including photoluminescence, transmission, optical band gap and refractive index as a function of film's thickness and structure were studied. It was observed that the average transmittance is more than 80% in... 

In this paper, a numerical model is developed based on the X-FEM technique to simulate the transport of dense solute in a single fluid phase through the fractured porous media. The governing equation is based on the mass conservation law which is applied to the fluid phase and the solute in both matrix and fracture domain. The integral governing equations of the mass exchange between the fracture and the surrounding matrix is derived. The extended finite element method (X-FEM) is applied by employing appropriate enrichment functions to model the fractured porous domain. The superiority of the X-FEM is that the FE mesh is not necessary to be conformed to the fracture geometry, so the regular... 

This article presents a multi-scale progressive micro-mechanical fatigue model. The model employs fundamental equation of the kinetic theory of fracture to calculate damage parameters of both fiber and matrix during cyclic loading. In order to adapt the equation, required material coefficients of the constituents can be achieved from fatigue test results of longitudinal and transverse unidirectional composites, only. Sharing stress capacities of fiber and matrix are determined using a modified progressive micro-mechanical bridging model in the presence of damage. The damage parameters in the constituents are calculated employing two different equivalent scalars. However, during sinusoidal... 

Uniform layers of ZnO nanostructures were formed on quartz and alumina substrates through a simple vapor phase transport (VPT) method without any catalyst or buffer layer by making proper growth conditions. The effect of substrate on morphology, crystalline structure and photoluminescence spectra has been investigated. Scanning electron microscopy images revealed that morphlogical grwoth depends on used substrate, aligned rods with flower-like bundels and entangled rods are vertically aligned rods on the quartz and alumina substrates, respectively. X-ray diffraction studies showed that grown films on the quartz substrates possess stronger c-axis orientation compared to those on the alumina... 

In the present study, we designed a pH-responsive drug nanocarrier based on polyamidoamine-modified Fe3O4 nanoparticles coated by PEGylated starch-co-poly(acrylic acid). This carrier was used for the controlled release of doxorubicin as an anticancer drug model. The purpose of using the polyethylene glycol moiety is to generate a biostable nanocarrier in blood stream as it has been reported widely in the pharmaceutical literature. The use of a poly(acrylic acid) segment also provided pH-sensitivity to the polymer. Besides, the magnetic nanoparticles facilitate the cancer cell targeting with an external magnetic field located near the tumor site. This carrier was... 

Rather vertically aligned ZnO rods with flower-like structures were grown on quartz substrates through vapor phase transport method. X-ray diffraction (XRD) analysis and photoluminescence (PL) measurement were performed to determine crystalline structure and defects, respectively. H2S gas sensing properties of the grown structure were investigated at both room temperature and 250 °C for comparison. A remarkable increase in response and selectivity at room temperature compared to 250 °C was observed. High response and selectivity to low concentrations of H2S at room temperature as well as good stability make the sensor a promising candidate for practical applications  

In drilling industry, barite particles settling and barite sag as a major problem can potentially impose significant operational issues. Static conditions, in which well undergoes an extended shut-in period, could occur during different drilling and completion operations such fishing operation, tripping, and logging. Despite its importance, such phenomenon is not well understood yet. To avoid issues related to barite settlement and barite sag, a good understanding of the impact of different drilling parameters on barite settlement and sag phenomenon is required. Recently, the mathematical formulation and modeling of settlement and sag processes have gained more attention. In order to better... 

The synthesis and catalytic behavior of palladium loaded magnetic nanocomposite based on natural polysaccharide salep modified with poly (amino pyridine) is described. The synthesized support is loaded with relatively large amounts of palladium ions (0.34mmol g−1). This is a simple, ecologically safe and cost-effective route for the preparation of the novel heterogeneous catalyst that shows high activity for Suzuki coupling reactions under remarkably mild conditions. Furthermore, the prepared catalyst is magnetically recovered and effectively reused for seven cycles of reactions without significant loss of its catalytic activity and loaded palladium nanoparticles. © 2017  

Ancillary services in interconnected networks are crucial to secure real power transfers, maintaining network reliability, improving power quality as well as network stability. Reactive power has always been of special importance as one of the most substantial ancillary services required to control the voltage in power grid. This paper presents a fresh reactive power pricing approach by embedding variable transformer taps into voltage ampere reactive (var) pricing method. To carry out the resultant optimization problem with a set of complicating constraints, the genetic algorithm takes part and guarantees the global optimal solution. The simulation results show that when transformer tap... 

In the present work we report an approach to resistive hydrogen sensing based on graphene quantum dots(GQDs)/WO3 thin films that work reproducibly at low temperatures. GQDs were chemically synthesized and evenly dispersed in WO3 solution with 1:1 molar ratio. The structural evaluation and crystallization of the prepared films was studied by X-ray diffraction, Raman and scanning electron microscopy (SEM) techniques. The SEM images showed uniform distribution of the GQDs in WO3 films with sizes around 50 nm. Raman experiment showed the GQDs are partially reduced with high edge defects as hydroxyl and carboxyl groups which involve both in bridging between WO3 grains via bindings as well as... 

Pursuing a sensing structure with a large effective surface area, partial ordered arrays of ZnO nanorods with flower-like structures are introduced for gas sensing applications. Room temperature H2S response of the grown structure shows significant enhancement after modification with Au nanoparticles. High response (about 1270 at 6 ppm H2S gas) and selectivity were achieved by depositing an Au layer with nominal thickness ∼6 nm. X-ray photoelectron spectroscopy (XPS) was utilized to describe the H2S sensing mechanism  

Titanium oxide (TiO2)-based photodetectors were fabricated using a thermal oxidation technique. The effect of two different annealing temperatures on morphology, structure, and I-V characteristics has been investigated. TiO2/Si heterostructure exhibited diode-like rectifying I-V behavior both in dark and under illumination. Dependence in photoresponse on annealing temperature was observed that was related to effective surface area of quasi-one-dimensional TiO2 nanostructures. Fabricated TiO2/Si diodes in 850 °C as the lower annealing temperature showed higher responsivity and sensitivity compared with grown ones in 950 °C (R850 °C/R950 °C ∼ 5 and S850 °C/S950 °C ∼ 1.6). Rather good...