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    Synthesis of Graphene and its Application for Adsorption of Cobalt and Strontium Ions, and as an Electrode in Electrochemical Cells (Battery)

    , M.Sc. Thesis Sharif University of Technology Jalilzadeh, Hassan (Author) ; Outokesh, Mohammad (Supervisor) ; Hosseinpour, Morteza (Co-Supervisor)
    Abstract
    Although much progress has been made in eliminating, conserving, and reducing migration and emissions of radioactive materials, the risk of radioactive material release into the environment is still one of the most important hazards in the use of nuclear energy. In this study, graphene compounds have been used as adsorbents for the removal of radioactive materials due to their high level, cost-effectiveness and simplicity of the synthesis process of various composites. In this regard, the removal of strontium and cobalt by graphene compounds has been investigated. Magnetite nanoparticles were anchored on the surface of graphene by sol-gel method and adsorption in batch mode was investigated.... 

    Determination of Number and Location of Models to Improve Transient Response in a Multi-model Adaptive Control

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Sajjad (Author) ; Haeri, Mohammad (Supervisor)
    Abstract
    In recent decays, multiple model controllers have been attracted much attention due to their essential ability to control of non-linear systems with wide operating ranges. Number and location of models are two important factors. In this research an algorithm for determining number of models and their locations has been proposed which can be counted as an extension to existing algorithms. Utilizing the proposed algorithm, the minimum number of models which achieve closed-loop stability can be determined. If transient response of non-linear system with these models be not satisfactory, the number of models are increased by one using Binary Search method, and consequently the location of models... 

    Investigation of heat transfer enhancement in a microchannel heat sink with the aid of internal fins: a metamodel approach

    , Article Computer Aided Chemical Engineering ; Volume 48 , 2020 , Pages 85-90 Hosseinpour, V ; Kazemeini, M ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Heat transfer enhancement with microchannel tools has been increased in recent year. In this study effect of geometric parameters as well as Reynolds number have been studied with experimental design approach. A metamodel was generated in this study for pressure drop and average Nusselt number passed all statistical tests. Order of an individual effect upon a response has been evaluated and interaction effects have been determined. Numerical results indicated that heat transfer increased significantly with inserting pyramidal micro fins. © 2020 Elsevier B.V  

    Chemical-Biological Phosphate Removal Using MBBR Bioreactors

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Mehdi (Author) ; Borgheei, Mahdi (Supervisor)
    Abstract
    Growing rate of eutrophication in receiving waters has made the enhancement of wastewater treatment plants to advanced methods of nutrients removal as necessary. Nitrogen and Phosphorus as the nutrients can reduce the quality of water and even make it unusable. Phosphorus is known to be one of the main reasons of eutrophication and creation of algal bloom. In this study, chemical-biological method for phosphate removal from the municipal wastewater is studied. Experiments are implemented for hydraulic retention times of 4, 8 and 16 hours, total intake concentration of phosphorus 7 ppm, COD 400 ppm and Nitrogen 25 ppm. Ferric Chloride as the precipitator chemical substance injected into the... 

    Visibility Testing of Uncertain Segments

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Hamed (Author) ; Ghodsi, Mohammad (Supervisor)
    Abstract
    Evaluating the enviroment for achieving efcient kwnoledge in order to justifed environment recognition and making decision based on data analysis is proponed in many felds.One of these problems is Visibility Problem. The Recieved data from real world as input, for visibility problem, is uncertain such that the recieving data of two different measurments will be different with high probability. Therefore, we defne the goal of this research to solving the visibility problem conditioned to that objects or segments are uncertain.Consider ”S” as a set of ”n” uncertain segments in plane. Each uncertain segment locates in two certain places and with probability 1 2 in each place, the goal is to... 

    Development of Hollow Cylinder Apparatus for Testing of Unsaturated Sandy Soils

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Saeed (Author) ; Jafarzadeh, Fardin (Supervisor)
    Abstract
    The main purpose of this study is to develop the Hollow Cylinder Apparatus (HCA) for unsaturated testing on granular materials and to investigate the effect of stress anisotropy on dynamic parameters of soils like shear modulus and damping ratio. Direction of loading and the magnitude of intermediate principal stress have significant effect on the anisotropic response of soils. In many of in-situ loading the direction of major principal stress does not coincide with deposition direction of soil or because of the three dimensional loading condition of soil, the effect of the intermediate principal stress cannot be ignored. On the other hand, in many areas, soils are in unsaturated condition.... 

    Enhancing Energy Efficiency in Ideal Binary Distillation tower with a Dynamic Process Intensification

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Ali (Author) ; Vafa, Ehsan (Supervisor)
    Abstract
    In this thesis titled "Enhancing Energy Efficiency in Ideal Binary Distillation tower with a Dynamic Process Intensification," operational methods in distillation units are explored and improved. Given the high cost of energy, limited energy resources, and environmental considerations, increasing energy efficiency in process industries has become significantly important. In this context, this research attempts to enhance the performance of the distillation unit by utilizing dynamic process intensification with two operational points corresponding to the production of products with purities both higher and lower than the desired product purity, and switching between these two points. The... 

    Ant colony algorithm for the shortest loop design problem [electronic resource]

    , Article Computers and Industrial Engineering, Elsevier ; Volume 50, Issue 4, August 2006, Pages 358–366 Eshghi, K. (Kourosh) ; Kazemi, Morteza ; Sharif University of Technology
    Abstract
    In this paper, a new algorithm for solving the shortest loop design problem is presented. The shortest loop design problem is to find the shortest loop for an automated guided vehicle covering at least one edge of each department of a block layout. In this paper, first it is shown that this problem can be represented as a graph model. The properties of the presented model enable us to design a meta-heuristic based on ant colony system algorithm for solving the shortest loop design problem. Computational results show the efficiency of our algorithm in compare to the other techniques  

    An efficient approach to cathode operational parameters optimization for microbial fuel cell using response surface methodology

    , Article Journal of Environmental Health Science and Engineering ; Vol. 12, issue. 1 , 2014 Hosseinpour, M ; Vossoughi, M ; Alemzadeh, I ; Sharif University of Technology
    2014
    Abstract
    Background: In the recent study, optimum operational conditions of cathode compartment of microbial fuel cell were determined by using Response Surface Methodology (RSM) with a central composite design to maximize power density and COD removal. Methods: The interactive effects of parameters such as, pH, buffer concentration and ionic strength on power density and COD removal were evaluated in two-chamber microbial batch-mode fuel cell. Results: Power density and COD removal for optimal conditions (pH of 6.75, buffer concentration of 0.177 M and ionic strength of cathode chamber of 4.69 mM) improve by 17 and 5%, respectively, in comparison with normal conditions (pH of 7, buffer concentration... 

    An experimental design approach to determine effects of the operating parameters on the rate of Ru promoted Ir carbonylation of methanol

    , Article World Academy of Science, Engineering and Technology ; Volume 73 , March , 2011 , Pages 598-603 ; 2010376X (ISSN) Hosseinpour, V ; Kazemini, M ; Mohammadrezaee, A ; Sharif University of Technology
    2011
    Abstract
    carbonylation of methanol in homogenous phase is one of the major routesfor production of acetic acid. Amongst group VIII metal catalysts used in this process iridium has displayed the best capabilities. To investigate effect of operating parameters like: temperature, pressure, methyl iodide, methyl acetate, iridium, ruthenium, and water concentrations on the reaction rate, experimental design for this system based upon central composite design (CCD) was utilized. Statistical rate equation developed by this method contained individual, interactions and curvature effects of parameters on the reaction rate. The model with p-value less than 0.0001 and R 2 values greater than 0.9; confirmeda... 

    Optimisation of Ru-promoted Ir-catalysed methanol carbonylation utilising response surface methodology

    , Article Applied Catalysis A: General ; Volume 394, Issue 1-2 , February , 2011 , Pages 166-175 ; 0926860X (ISSN) Hosseinpour, V ; Kazemeini, M ; Mohammadrezaee, A ; Sharif University of Technology
    2011
    Abstract
    In this study, central composite design (CCD) at five levels (-1.63, -1, 0, +1, +1.63) combined with response surface methodology (RSM) have been applied to optimise methanol carbonylation using a ruthenium-promoted iridium catalyst in a homogenous phase. The effect of seven process variables, including temperature, pressure, iridium, ruthenium, methyl iodide, methyl acetate and water concentrations, as well as their binary interactions, were modelled. The determined R 2 values greater than 0.9 for the rate and methane formation data confirmed that the quadratic equation properly fitted the obtained experimental data. The optimum conditions for maximum rate and minimum methane formation were... 

    A study of the water-gas shift reaction in Ru-promoted Ir-catalysed methanol carbonylation utilising experimental design methodology

    , Article Chemical Engineering Science ; Volume 66, Issue 20 , October , 2011 , Pages 4798-4806 ; 00092509 (ISSN) Hosseinpour, V ; Kazemeini, M ; Mohammadrezaee, A ; Sharif University of Technology
    2011
    Abstract
    The water-gas shift reaction occurs competitively to the main reaction of the Ir-catalysed methanol carbonylation process. To study the effect of seven factors including temperature, pressure, iridium, ruthenium, methyl iodide, methyl acetate and water concentrations on the formation of hydrogen and carbon dioxide as a result of the water-gas shift reaction and other side reactions in the carbonylation of methanol to acetic acid, the experimental design method combined with response surface methodology (RSM) was utilised. Central composite design at five levels (with α=1.63) was used to design experiments. A quadratic model that included the main and interaction effects of variables for H 2... 

    Estimation Elasticity of Calorie and Macronutrients with Respect to Income in the Islamic Republic of Iran, 2008-2016

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Mitra Sadat (Author) ; Vesal, Mohammad (Supervisor)
    Abstract
    Inadequate nutrition is perhaps the most important problem facing the poor. Being hungry lowers productivity and decreases individuals’ income. All of these factors conspire to help the poor stay poor. Raising the income of the poor is one solution for this problem if the elasticity of calorie and macronutrients with respect to income is greater than zero. This study employs both nonparametric and parametric methods to obtain the elasticity of per capita calorie and macronutrients with respect to household per capita expenditure. The case presented is for urban areas of Islamic republic of Iran, 2008-2016. Under each estimation strategy we employ, we find a strongly significant and positive... 

    Developing a metamodel based upon the DOE approach for investigating the overall performance of microchannel heat sinks utilizing a variety of internal fins

    , Article International Journal of Heat and Mass Transfer ; Volume 149 , 2020 Hosseinpour, V ; Kazemeini, M ; Rashidi, A ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    In this study, the effects of geometry and operating conditions upon the thermal and hydraulic performance of Finned Microchannel Heat Sink (FMCHS) were investigated. Water and aluminum were considered as fluid and solid for the computational domain (30 mm × 0.8 mm × 0.8 mm). The Microchannel (MC) was supposed to have 0.65 mm height with an aspect ratio of 0.5. CFD analysis was applied for the assessments of four-types of micro-fins (i.e., conical, pyramidal, cylindrical and cubical). In order to evaluate the effects of height, diameter, the spacing of fins and Reynolds number on the overall performance of FMCHS, central composite design at five levels was used to generate design points.... 

    Effects of Nano Metallic Catalysts on The Life-Time and Efficiency of Proton Exchange Membrane Fuel Cells

    , M.Sc. Thesis Sharif University of Technology Hosseinpour, Milad (Author) ; Vesaghi, Mohammad Ali (Supervisor)
    Abstract
    The Fuel cell is an energy converter which converts the chemical energy of a chemical reaction to electricity and heat directly and without any pollution. One of the most important types of fuel cells is the proton exchange membrane (PEM) fuel cell. The importance of PEM fuel cells is a result of their high energy density, quick start up ability, lower operating temperature, high efficiency and low or zero emissions. Catalysts play an important role in both costs and durability of PEM fuel cells. Alloying the Pt with other metals can increase the activity of the catalysts of the fuel cells and also reduces the amount of costly Pt. In this study, the nanoparticles of Ni were added to the... 

    Adsorption behavior of toxic metal Ions on nano-structured CuO granules

    , Article Separation Science and Technology (Philadelphia) ; Volume 47, Issue 7 , 2012 , Pages 1063-1069 ; 01496395 (ISSN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Sharif University of Technology
    2012
    Abstract
    In this study, copper oxide nano particles were synthesized by batchwise supercritical hydrothermal method. After preparation of CuO nano particles, they were immobilized into the porous matrix of sodium alginate. The drying process formed a very porous structure that is useful for enhancing of adsorption activity. Produced CuO particles were characterized by X-ray diffractometery (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and BET for measuring the surface area. The prepared materials were then used as adsorbent in the removal of toxic metal ions in aqueous solution. To optimize the adsorption system, the effect of various parameters such as adsorbent... 

    Adsorption of lead ions in aqueous solution using Yttrium oxide nanoparticles

    , Article Journal of Nano Research ; Volume 16 , 2011 , Pages 83-87 ; 16625250 (ISSN) Sadjadi, S ; Ahmadi, S. J ; Hosseinpour, M ; Sharif University of Technology
    2011
    Abstract
    By a single-step supercritical hydrothermal synthesis method, yttrium oxide nanoparticles were successfully prepared without additional treatment. Yttrium oxide nanoparticles were employed as an adsorbent to study the adsorption of some heavy metal ions. This study revealed that nano structure yttrium oxide was an effective adsorbent for removal of lead ions from aqueous solutions  

    A green protocol for Erlenmeyer-Plöchl reaction by using iron oxide nanoparticles under ultra sonic irradiation

    , Article Ultrasonics Sonochemistry ; Volume 20, Issue 1 , 2013 , Pages 408-412 ; 13504177 (ISSN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Sharif University of Technology
    2013
    Abstract
    Azlactones have been prepared via Erlenmeyer synthesis from aromatic aldehydes and hippuric acid using Fe 2O 3 nanoparticles under ultrasonic irradiation. Short reaction times, easy and quick isolation of the products, and excellent yields are the main advantages of this procedure  

    Granulated copper oxide nanocatalyst: A mild and efficient reusable catalyst for the one-pot synthesis of 4-amino-5-pyrimidinecarbonitriles under aqueous conditions

    , Article Monatshefte fur Chemie ; Volume 142, Issue 11 , November , 2011 , Pages 1163-1168 ; 00269247 (ISSN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Sharif University of Technology
    2011
    Abstract
    An efficient method for the synthesis of 4-amino-5-pyrimidinecarbonitriles by the three-component reaction of malononitrile, aldehydes, and N-unsubstituted amidines under aqueous conditions using CuO microspheres as catalyst is reported. The catalyst exhibited remarkable reusable activity. Graphical abstract: [Figure not available: see fulltext.]  

    CuO nanoparticles: A mild and efficient reusable catalyst for the one-pot synthesis of 4-amino-5-pyrimidinecarbonitriles under aqueous conditions

    , Article Defect and Diffusion Forum ; Volume 326-328 , 2012 , Pages 372-376 ; 10120386 (ISSN) ; 9783037854006 (ISBN) Ahmadi, S. J ; Sadjadi, S ; Hosseinpour, M ; Sharif University of Technology
    2012
    Abstract
    An efficient method for the synthesis of 4-amino-5-pyrimidinecarbonitriles by three-component reaction of malononitrile, aldehydes and N-unsubstituted amidines, under aqueous conditions, using CuO nanoparticles as catalyst is reported. The protocol offers advantages in terms of higher yields, short reaction times, and mild reaction conditions, with reusability of the catalyst