Sharif Digital Repository

Ionic liquids (ILs) are a growing trend in Enhanced Oil Recovery (EOR) studies as alternatives to commercial surfactants due to their environmentally friendly nature, and their resistance in harsh temperatures and salinities. ILs are customizable and come in an immense variety, and therefore, it is vital that different combinations of cation/anion be investigated for use in the industry. In this work, experiments are designed and performed to evaluate novel ILs’ surface activity and performance in a lab-scale EOR set-up, compatible with Iranian oil reservoir conditions. Three imidazolium-based ionic liquids were used, namely, butyl-methylimidazolium nitrate, hexyl-methylimidazolium nitrate,... 

Efficient location of medical services is an issue of paramount importance in healthcare strategic planning. In this research, a mathematical model is developed for the location of multi-service health centers, assuming probabilistic demand and service time. Since patients may be shifted to another service after receiving a service by doctors’ order, health system is considered a Jackson queueing network. We assume that patients have “probabilistic choice behavior” and the primary factors contributing to their choice of one center over another are their proximity to the center and the number of medical services offered by the center. The proposed mixed integer nonlinear programming model... 

Real-world, large-scale problems often have coefficient matrices with special structures that can be obtained by reordering their rows and columns. One fundamental problem in the field of combinatorial optimization is the Set Packing Problem (SPP), which takes on added significance in view of its far-reaching applications in routing and scheduling problems, scheduling surgical procedures, the winner determination problem, forestry, production management, etc. The coefficient matrix of this problem has low density (the number of 1’s is much less than the number of 0’s in the matrix); therefore, by reordering the matrix, one can aggregate its 1’s in order to exploit special structures like... 

This chapter at first proposes a framework to solve set covering problems (SCPs) with block-angular structures through solving their sub-problems and then develop the method for solving general SCPs without this structure. The proposed framework generates a guaranteed solution for the SCPs with block-angular structure based on a theorem which relates the optimal solution of the original problem to the optimal solutions of its sub-problems. Therefore, since sub-problems involve much fewer constraints and variables than the original problem, the complexity to solve the original SCP is much reduced. In addition, a method to exploit the block-angular structure of SCPs is proposed, using... 

This chapter at first proposes a framework to solve set covering problems (SCPs) with block-angular structures through solving their sub-problems and then develop the method for solving general SCPs without this structure. The proposed framework generates a guaranteed solution for the SCPs with block-angular structure based on a theorem which relates the optimal solution of the original problem to the optimal solutions of its sub-problems. Therefore, since sub-problems involve much fewer constraints and variables than the original problem, the complexity to solve the original SCP is much reduced. In addition, a method to exploit the block-angular structure of SCPs is proposed, using... 

The set covering problem (SCP) has quite a large coefficient matrix in practical problems, but due to its low density, most of its entries are zero. Drawing on this observation, some methods can be developed to exploit special structures of the coefficient matrix of an SCP in such a way that they contain smaller dense subproblems. Against this backdrop, in this paper, three structures, namely 'partitioned', 'semi-block angular', and 'block angular', are proposed. To begin with, some heuristic methods are presented to exploit these structures of the coefficient matrices of SCPs; then, by optimally solving the smaller subproblems of these structures, their solutions are used to solve the whole... 

In this paper, a decomposition technique based on constraint partitioning is developed to solve the crew pairing problem (CPP) which has an overriding importance in the airline industry as it determines the crew cost. The method is based on the observation that in large-scale problems, the constraints can be partitioned to some sub-problems which involve special subsets of variables. The resultant structure is called the 'partitioned structure'. Therefore, in the proposed method, first, a feasible solution is generated for a reduced CPP with a 'partitioned structure' through the optimal solutions of its sub-problems. Then, at each step, the feasible solution is improved through... 

The composition of the essential oil obtained from the dried flowering aerial parts of Chenopodium botrys L. (Chenopodiaceae) was analyzed by GC and GC-MS. Forty-one components have been identified in the essential oil of C. botrys. The major components of the essential oil were γ-terpineol (52.8%), p-cymene (19.0%) and iso-ascaridole (7.0%). © 2007 Taylor & Francis Group, LLC  

The composition of the essential oil obtained from the dried flowering aerial parts of Marrubium vulgare L. (Labiatae) was analyzed by GC and GC/MS. Twenty components have been identified in the essential oil of M. vulgare. The major constituents of the essential oil were β-bisabolene (20.4%), δ-cadinene (19.1%) and isocaryophyllene (14.1%). © 2008, Taylor & Francis Group, LLC. All rights reserved  

Continuous fixed-bed column studies were carried out by using Amberlite CG-400 anion exchange resin for the recovery of uranium from aqueous solutions (synthetic solutions and uranium conversion facility (UCF) liquid waste). Effects of operating parameters such as flow rate and bed height were studied. The breakthrough capacity decreases with increasing flow rate, but this dependence was not significant with a long column. The maximum breakthrough capacity of uranium ions were achieved by CG-400 resin at a flow rate of 0.2 mL min-1 and bed height 9.1 cm (4 g resin). The elution behavior of uranium from CG-400 resin by various eluents have been investigated and the results show that 0.5 mol... 

In this paper, uranium sorption onto amberlite CG-400 anion exchange resin in the presence of phosphate anions was studied. The effect of contact time between the sorbent and aqueous solution, pH, initial concentration of uranium and temperature were also investigated. Kinetic studies show that uranium sorption onto amberlite CG-400 resin in the presence of phosphate is a fast process and follows pesudo-second-order kinetics. It was also found that the pH value and the presence of phosphate play very important roles in the uranium sorption onto CG-400 resin. Optimum pH for uranium sorption in the presence of phosphate anions was about 3.5. The experimental sorption isotherm is successfully... 

The polysaccharide, kappa-carrageenan (κC) was chemically modified to achieve a novel superabsorbent hydrogel via graft copolymerization of methacrylamide (MAM) onto the substrate followed by alkaline hydrolysis. Ammonium persulfate (APS) and N,N′-methylene bisacrylamide (MBA) were used as a free-radical initiator and a crosslinker, respectively. The saponification reaction was carried out using sodium hydroxide aqueous solution. Either κC-g-PMAM or hydrolyzed κC-g-PMAM (PMAM: polymethacrylamide) was characterized by FT-IR spectroscopy. The effect of grafting variables (i.e. concentration of MBA, MAM, and APS) and alkaline hydrolysis conditions (i.e. NaOH concentration, hydrolysis time and... 

To synthesize a novel biopolymer-based superabsorbent hydrogel, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) was grafted onto kappa-carrageenan (KC) backbones. The graft copolymerization reaction was carried out in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator, N,N,N',N'-tetramethyl ethylenediamine (TMEDA) as an accelerator, and N,N'-methylene bisacrylamide (MBA) as a crosslinker. A proposed mechanism for KC-g-AMPS formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy. The affecting variables on swelling capacity, i.e., the initiator, the crosslinker, and the monomer concentration, as well as reaction temperature,...