Sharif Digital Repository

Surface-enhanced Raman spectroscopy is a highly sensitive phenomenon and a powerful fingerprint detection tool that reflects the small changes in polarizability on the pattern and intensity of Raman signals. The SERS enhancement signals elucidate with the surface-selection rules. In this regard, molecular configuration and adsorption orientation on the surface, in addition to the direction of external electric field, can lead to different patterns of SERS spectra. To evaluate how the variation of these features influences the pattern and reproducibility of the spectra, the chemical charge-transfer SERS spectra for pyridine on silver clusters are calculated for different field directions,... 

We construct the most generic Hamiltonian of the 8Pmmn structure of a borophene sheet in the presence of spin orbit, as well as background electric and magnetic fields. In addition to spin and valley Hall effects, this structure offers a framework to conveniently manipulate the resulting "tilt" of the Dirac equation by applying appropriate electric fields. Therefore, the tilt can be made space as well as time dependent. The border separating the low-field region with undertilted Dirac fermions from the high-field region with over-tilted Dirac fermions will correspond to a black-hole horizon. In this way, space-time-dependent electric fields can be used to design the metric of the resulting... 

Spin lattice relaxation rate is investigated for 3D tilted cone Weyl semimetals (TCWSMs). The nuclear spin relaxation rate is presented as a function of temperature and tilt parameter. We find that the relaxation rate behaves as (1-ζ2)-α with α ≈ 9 where 0 ζ < 1 is the tilt parameter. We demonstrate that such a strong enhancement for ζ ≲ 1 that gives rise to very fast relaxation rates, is contributed by a new hyperfine interactions arising from the tilt itself. This can be attributed to the combination of anisotropy of the Fermi surface and an additional part related to the structure of the spacetime: extracting an effective density of states (DOS) ρ from the Korringa relation, we show that... 

Resonance Raman spectroscopy has long been established as one of the most sensitive techniques for detection, structure characterization, and probing the excited-state dynamics of biochemical systems. However, the analysis of resonance Raman spectra is much facilitated when measurements are accompanied by Density Functional Theory (DFT) calculations that are expensive for large biomolecules. In this work, resonance Raman spectra are therefore computed with the Density Functional Tight-Binding (DFTB) method in the time-dependent excited-state gradient approximation. To test the accuracy of the tight-binding approximations, this method is first applied to typical resonance Raman benchmark... 

Using Green's function of semi-infinite Weyl semimetals, we present the quantum theory of the collective charge dynamics of Fermi arcs. We find that the Fermi arc plasmons in undoped Weyl semimetals are linearly dispersing gapless plasmon modes. The gaplessness comes from proper consideration of the deep penetration of surface states near the end of the Fermi arcs into the interior of the Weyl semimetal. The linear dispersion - rather than square root dispersion of pure 2D electron systems with extended Fermi surface - arises from the strong anisotropy introduced by the Fermi arc itself, due to which the continuum of surface particle-hole (PH) excitations in this system will have a strong... 

Abstract In this work, two [60] fullerene derivatives were employed as flow improvers for waxy crude oil to reduce problems caused by the crystallization of paraffin during the production and/or transportation of the crude oil. These amine-based derivatives of [60] fullerene have been applied as wax inhibitor for improvement of rheological performance as well as pour point depressant in a waxy crude oil. Moreover, the influence of these [60] fullerene derivatives on the viscosity and pour point was also investigated in an Iranian waxy crude oil sample. The [60] fullerene derivatives were simply prepared by stirring a solution of [60] fullerene and two lipophilic amines. The results similarly... 

The biological oxidation of ferrous ion by iron-oxidizing bacteria is potentially a useful industrial process for removal of H2S from industrial gases, desulphurization of coal, removal of sulfur dioxide from flue gas, treatment of acid mine drainage and regeneration of an oxidant agent in hydrometallurgical leaching operations. The main purpose of this study was to find optimum values of the process parameters on the ferrous biooxidation rate by immobilization of a native Sulfobacillus species on the surface of low density polyethylene (LDPE) particles in a packed-bed bioreactor using Taguchi method. Five control factors, including temperature, initial pH of feed solution, dilution rate,... 

We have investigated the effect of bias voltage on sheet resistance, surface roughness and surface coverage of Co/NiO x magnetic bilayer. In addition, interface topography and corrosion resistance of the Ta/Co/Cu/Co/NiO x /Si(1 0 0) system have been studied for Co layers deposited at an optimum bias voltage. Atomic force microscopy (AFM) and four point probe sheet resistance (Rs) measurement have been used to determine surface and electrical properties of the sputtered Co layer at different bias voltages ranging from 0 to -80 V. The Co/NiO x bilayer exhibits a minimum surface roughness and low sheet resistance value with a maximum surface coverage at Vb=-60 V resulted in a slight increase of... 

Protecting users’ privacy over the Internet is of great importance; however, it becomes harder and harder to maintain due to the increasing complexity of network protocols and components. Therefore, investigating and understanding how data are leaked from the information transmission platforms and protocols can lead us to a more secure environment. In this paper, we propose a framework to systematically find the most vulnerable information fields in a network protocol. To this end, focusing on the transport layer security (TLS) protocol, we perform different machine-learning-based fingerprinting attacks on the collected data from more than 70 domains (websites) to understand how and where... 

We have studied the effect of annealing temperature on the statistical properties of WO3 surface using atomic force microscopy (AFM) techniques. We have applied both level crossing and structure function methods. Level crossing analysis indicates an optimum annealing temperature of around 400°C at which the effective area of the WO3 thin film is maximum, whereas the composition of the surface remains stoichiometric. The complexity of the height fluctuation of surfaces was characterized by roughness, the roughness exponent and the lateral size of surface features. We have found that there is a phase transition at around 400°C from one set to two sets of roughness parameters. This happens due... 

We propose a method for analyzing the data for the rates of exchange of various currencies versus the U.S. dollar. The method analyzes the return time series of the data as a Markov process, and develops an effective equation which reconstructs it. We find that the Markov time scale, i.e., the time scale over which the data are Markov-correlated, is one day for the majority of the daily exchange rates that we analyze. We derive an effective Langevin equation to describe the fluctuations in the rates. The equation contains two quantities, D(1) and D(2), representing the drift and diffusion coefficients, respectively. We demonstrate how the two coefficients are estimated directly from the... 

Experimental parameters have direct influences on materials properties and therefore their applications. The effect of plasma power on the properties of cobalt oxide thin films, prepared using plasma-enhanced chemical vapor deposition technique, on stainless steel substrates have been addressed in this paper. The structural, morphological, and compositional properties of these films were investigated by means of X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) technique. The XRD patterns demonstrated the growth of polycrystalline Co3O4 thin film with a cubic spinel structure such that the intensity of (511) and (311) peaks increase as the... 

In this study, in-silico properties of Gingerol (Gin) and Letrozole (Let), as two potential anti-cancer drugs, were investigated and some significant ADME drawbacks were predicted. Accordingly, to address the drawbacks, mesoporous silica nanoparticles (MSNs) were prepared, functionalized with zinc, amine, and graphene oxide (GO) (MZNG), and employed for loading and delivery of the both to breast cancer cells in-vitro. Biophysical analysis showed that Let and Gin-loaded MZNGs have spherical structure with a mean diameter of ∼210 nm. The MZNGs provided high entrapment efficiency of Let and Gin with a pH-sensitive sustained release profile. The cytotoxicity assay demonstrated that loading of... 

In a nanoscopic thin film of a strong topological insulator (TI) the Coulomb interaction in the channel that exchanges the two electrons with the same chirality in two different planes of the slab takes advantage of the minus sign resulting from such "exchange" and gives rise to a bound state between the positive-energy states in one surface and the negative-energy states in the opposite surface. Therefore particle and hole pairs in the undoped Dirac cone of the TI thin film form an inter-surface spin-singlet state that lies below the continuum of free particle-hole pairs. This mode is similar to the excitons of semiconductors, albeit formed between the electron and hole pairs from two... 

The particle-hole continuum (PHC) for massive Dirac fermions provides an unprecedented opportunity for the formation of two collective split-off states, one in the singlet and the other in the triplet (spin-1) channel, when the short-range interactions are added to the undoped system. Both states are close in energy and are separated from the continuum of free particle-hole excitations by an energy scale of the order of the gap parameter Δ. They both disperse linearly with two different velocities, reminiscent of spin-charge separation in Luttinger liquids. When the strength of Hubbard interactions is stronger than a critical value, the velocity of singlet excitation, which we interpret as a... 

We present a formulation for the nonlinear optical response in gapped graphene, where the low-energy single-particle spectrum is modeled by massive Dirac theory. As a representative example of the formulation presented here, we obtain a closed form formula for the third harmonic generation in gapped graphene. It turns out that the covariant form of the low-energy theory gives rise to peculiar logarithmic singularities in the nonlinear optical spectra. The universal functional dependence of the response function on dimensionless quantities indicates that the optical nonlinearity can be largely enhanced by tuning the gap to smaller values  

Within the block spin renormalization group, we give a very simple derivation of the exact phase boundaries of the XYZ spin chain. First, we identify the Ising order along ◯ or ŷ as attractive renormalization group fixed points of the Kitaev chain. Then, in a global phase space composed of the anisotropy λ of the XY interaction and the coupling Δ of the Δσzσz interaction, we find that the above fixed points remain attractive in the two-dimesional parameter space. We therefore classify the gapped phases of the XYZ spin chain as: (1) either attracted to the Ising limit of the Kitaev-chain, which in turn is characterized by winding number ±1, depending on whether the Ising order parameter is... 

We show that the continuum limit of the tilted Dirac cone in materials such as 8-Pmmn borophene and layered organic conductor α-(BEDT-TTF)2I3 corresponds to deformation of the Minkowski space-time of Dirac materials. From its Killing vectors we construct an emergent tilted-Lorentz (t-Lorentz) symmetry group for such systems. As an example of the t-Lorentz transformations we obtain the exact solution of the Landau bands for a crossed configuration of electric and magnetic fields. For any given tilt parameter 0≤ζ<1, if the ratio χ=vFBz/Ey of the crossed magnetic and electric fields satisfies χ≥1+ζ, one can always find appropriate t-boosts in both valleys labeled by τ=±1 in such a way that the... 

Dirac cone can be tilted in condensed matter setting. As a result of tilt, the Lorentz symmetry is reduced to what we call tilted-Lorentz symmetry. In this paper, we derive the tilted-Lorentz transformations that leave a world with tilted Dirac cone invariant. © 2020, Isfahan University of Technology. All rights reserved