Sharif Digital Repository

In this study, density, viscosity and surface tension of aqueous solution of Sulfolane, ( TEA+TMS+H2O) and (DIPA+TMS+H2O) systems were measured . Density, viscosity and surface tension were measured using pycnometer, Cannon – Fenske viscometer and Capillary rise method, respectively. Surface tension measurements of (DIPA+TMS+water) were carried out by the ring method using a LAUDR TD3 tensiometer,. The experiments were carried out in low concentrations and atmospheric pressure in the temperature range (70 - 30) . The obtained Data was modeled using empirical and thermodynamic models. Density calculation was done using the Setchenov and Redlich – Kister models.and the results indicated that... 

Generating real traffic and attacks for network equipment and applications are not yet considered a clear straight forward subject. To overcome this issue, we produce real traffic and then add some vulnerability attacks to it. This is an important step towards achieving security tests or evaluation methods which let us examine or assess intrusion detection (IDSs) features of a system.In this dissertation, we generate legitimate and anomalous traffic beside some attacks. Our study yields an implementation which is tested in real environment. We introduce a substantial method to generate DDoS attack in network and transport layers. We develop a software tool for this purpose. The performance... 

These days the usage of welded tailor blanks with sufficient stability and flexibility is accelerating rapidly in order to production of slighter parts and reduction of fuel consumption in transportation means. Therefore, the conjuncture of blanks by welding methods is highly considerable before forming and ultimate production. Friction Stir Welding is greatly appealing to industry as one of the newest methods of solid state welding in production of TWB blanks. In this research, the feasibility study of Friction Stir Welding of thin Al 1100 – H18 alloy blanks with 1.5, 2 and 2.5mm thickness has been evaluated first. After creation of sound welds with same thicknesses, Friction Stir Welding... 

The microstructure and wear performance of WC/Cu-Zn-Ni composite surface coating has been investigated using a combination of microscopy, hardness, and wear testing. The oxidation behavior of tungsten carbide hard metal in the temperature range between 600 and 900 ◦C was also researched. The oxidation mass gain of WC correlated almost directly with temperature as well as time. The particle of hard metal is surrounded by the α Cu+β Zn phase in the surface coating. The size of hard metal is almost unchanged from its original one. There exists an inter-diffusion zone at the interface of the hard metals and Cu-based matrix. The wear volume of the WC/Cu-Zn-Ni composite surface coatings increased... 

In order to control accesses in semantic environments, a semantic-based access control and policy specification language should be choosen. Upon to them, some security mechanisms should be designed and implemented. Several access control models and policy specification languages have been arisen, but seldom have focused on designing mechanisms to satisfy their models in any environment. In this thesis, we focus on implementation aspects of access control in semantic environments. We chose semantic web as our studying environment and an extension of the SBAC model named MA(DL)2 as our access control model. To control accesses in the selected environment, we divide semantic web into some... 

Intrusion Detection Systems (IDSs) are among the mostly used security tools in computer networks. While they are promising technologies, they pose some serious drawbacks: When utilized in large and high traffic networks, IDSs generate high volumes of low level alerts which are hardly manageable. In addition, IDSs usually generate redundant or even irrelevant (false) alerts. One technique proposed to circumvent such drawbacks is alert correlation, which extracts useful and high-level alerts, and helps in making timely decisions when a security breach occurs. This thesis will survey current alert correlation techniques, and introduces a real-time and data-mining–based algorithm for alert... 

Due to their low volatility, negligible flammability, and high regeneration capacity, ionic liquids have attracted a lot of attention in chemical and process engineering fields. Regarding the limited access to the laboratory facilities, developing theoretical methods such as equations of state is important in this research field. Thus, data for density and viscosity of pure ionic liquids and vapor pressure data for binary mixtures of ionic liquids and acidic gas have been collected and validated from the IL Thermo website for 42 ionic liquids. By consideration of theoretical studies and comparison of the performance of different cubic equations of state in predicting the aforementioned... 

Although Machine Learning (ML) and especially Deep Learning (DL) has shown significant success in solving complex problems, recent studies have shown that ML algorithms are vulnerable to adversarial attacks. So far, ML algorithms have been designed to run in benign environments. However, the increasing use of ML algorithms in security-sensitive applications motivated adversaries to focus on their vulnerabilities. In the adversarial environment, an adversary can interfere in the training and inference processes of ML algorithms. Adversarial examples are one of the most critical vulnerabilities of ML models at the inference time. Adversarial examples are maliciously crafted inputs that cause... 

Deep neural networks attain high performance on many domains and gaining more attention from real-world businesses in recent years. With the emergence of Machine Learning as a Service (MLaaS), users have the opportunity to produce their model on these platforms and make it available to others through the prediction APIs. However, studies have shown that an adversary can produce a surrogate model with similar characteristics to the victim's model by accessing these APIs. Aside from ruining the victim's business plan, studies have shown that an adversary can implement more sophisticated attacks on the victim's model by accessing a surrogate model. Due to the adversary's inaccessibility to the... 

Today’s large networks, such as global enterprise networks, carry heavy network traffic from a wide range of diverse protocols. Scalable and accurate classifcation of network traffic is of the most importance to security policy enforcement of large networks. The complexity of current network traffic along with the high speed links makes traffic classification more difficult. The dynamicity of heavy network traffic have necessitated the need for traffic classification algorithms which are adaptable to new concepts. The changes in traffic characteristic over time lead to concept drift, which is an important challenge in this domain. Data stream classification methods have been introduced to... 

The need to build underground structures like tunnels, oil reservoirs are increasing and it requires a good knowledge of behavior of mass rock, exact data and parameters for safe and economic design. Filling materials which usually transfer with water into the joints reduce shear strength of joints significantly and change the behavior of the joints. To evaluate shear behavior of filled joints, 24 tests were conducted with large scale direct shear test apparatus on model rock joints with a regular “saw tooth” surface profile with the dimensions of 15cmx15cmx18cm. Filled material had specified specifications like particles size and strength parameters.
Infill thickness, moisture content... 

One of the most important conditions in weak rock masses with high overbuerden which causes problems in the tunnel construction, is squeezing condition. This is actually defined as increases in the shear deformation of the rock element, when the element is under constant deviatoric stress. Qomroud water tunnel with a length of 36 km and a drilling diameter of 4.5 meters deliveres water from the branches of the Dose to the Golpaygan and Qom. Because of a high overbuerden and existence of schist, slate, clay limestone zones, studing of squeezing potential,prediction of convergence of tunnel wall and lining pressure in this tunnel is very important.In this research, we stuied the 25th to 35th... 

Inrecent years,research onionic liquidsarehighly developed. Because ofthe uniqueproperties ofionic liquidssuch asnegligiblevapor pressureandthermalstability for use inlarge areasofmajor industries have been considered.However,ionic liquids because they have lessenvironmental wasteas an alternative to convention alorganic solventssuch asaminesalkanolanarise.Ionic liquid sassolventsfor theremoval ofacid gases such as water and gasare investigated. The solubility of CO2 and H2S in the [Emim] [OTF] (1-ethyl-3-methylimidazolium triflate) in the temperature range 303.15 to 343.15 K and pressures up to 2 MPa has been studied experimentally. In order to capture modeling, the model equations of state... 

With considering the existence of carbonyl sulfide in natural gas and crude oil, we need to study the absorption of this gas in aqueous alkanolamine solutions. In this project the solubility of carbonyl sulfide in different pressures and two temperatures of 313.15 and 348.06 K have been measured.The absoption of carbonyl sulfide in aqueous alkanolamine solutions is a very slow process. In this study we used different methods for measuring the required data. Befor the experiments we calibrated the set up with reliable data. Finaly the results simulated with Deshmakh-Mather thermodynamic model, numerically. The simulation results show a good agreement with experimental data  

Ionic liquids (IL's) are found to be potentially suitable solvents for the chemical process industry, especially due to their negligible vapor pressure which can result in a major decrease of solvent loss and the environmental harm. One of the foreseeable industrial applications in the field of natural gas processing is the replacement of traditional organic solvents (usually alkanol amines) presently used for the absorption of H2S from sour gases, by suitable IL's. Ionic liquids have been proposed for the separation of gas mixtures. In particular, ionic liquids have been suggested for the removal of the acid gases, hydrogen sulfide, and carbon dioxide, from natural gases and refinery gases.... 

Formation of gas hydrates is a challenge in the oil and gas industry. Gas hydrate formation can be prevented by several methods. One of these methods is to utilize of inhibitor components. The gas hydrate inhibitors can affect hydrate formation from two aspects, i.e., thermodynamic or kinetic. In this work, thermodynamic and kinetic effects of [Emim][BF4] ionic liquid on growth and dissociation of methane hydrate crystal were investigated using molecular dynamics simulation. Molecular dynamics simulation is powerful tool to investigate the thermophysical, structural, and dynamic properties of methane hydrate and the formation, dissociation, and inhibition mechanisms at the molecular scale.... 

The rapid pace of development of nanoscience and nanotechnology and their applications in various fields have made the study of materials in smaller scales more important than any time ever. Having an insight of materials’ microstructure and the mechanism of different phenomena in the atomic scale will be very beneficent in designing new and advanced materials or modifying the current manufacturing processes. Since molecular dynamics (MD) method has been well known as a mean of studying materials in atomic scale, it has been used in this study to investigate two different phenomena. The selection of the appropriate interatomic potential is of great importance in MD; Embedded Atom Method... 

Removal of some hazardous and toxic components of natural gas is of a great importance in industries. Thus solubility measurement of these components in appropriate solvents is a necessary task. Methylmercaptan due to its high toxicity as one of these components is separated by means of Alkanolamines. In this project a physical solubility experimental setup for absorption Methylmercaptan (CH3SH) in 48wt%, 35wt% and 25wt% MDEA aqueous solutions at 50°C and in pressures between (0.7 to 3)bar was designed and developed. The suggested setup can be used for measurement of solubility of gases (physical and chemical) in different solutions. The performance basis of the system is on precise... 

New experimental results are presented for the solubility of carbon dioxide and hydrogen sulfide sulfide in six imidazolium-based ionic liquids included 1-octyl-3-methylimidazolium tetrafluoroborat ([C8mim][BF4]), 1-octyl-3-methylimidazolium hexafluorophosphate ([C8mim][PF6]), 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide ([C8mim][Tf2N]), 1-octyl-3-methylimidazolium trifluoromethanesulfonate ([C8mim][TfO]), 1-hexyl-3-methylimidazolium trifluoromethanesulfonate ([C6mim][TfO]), 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([C4mim][TfO]) at temperatures range from 303.15 to 353.15 K and pressures up to about 2.5 MPa. The solubilities of the mixture of CO2/H2S in...