Sharif Digital Repository

The importance of accurate determination of the critical properties of plus fractions in prediction of phase behaviour of hydrocarbon mixtures by equations of state is well known in the petroleum industry. It has been stated in various papers (Elsharkawy, 2001) that using the plus fraction as a single group in equation of state calculations reduces the accuracy of the results. However in this work it has been shown that using the proper values of critical temperature and pressure for the plus fraction group can estimate the properties of hydrocarbon mixtures, and they are accurate enough to be used in reservoir engineering and enhanced oil recovery calculations. In this paper, a new method... 

Asphaltene deposition in a reservoir severely reduces the effective permeability and results in a reduction in oil production. The main term in asphaltene deposition modeling in the porous media is pore surface deposition. Previous models do not describe the effects of different parameters (i.e., concentration, velocity, and temperature) on the pore surface deposition term. We report the results of a series of experiments carried out to study the effects of the above parameters on the surface deposition term using an accurate thermal method. Based on these data, a new expression for the surface deposition term has been developed and implemented in asphaltene deposition modeling. The... 

Asphaltene precipitation and deposition is a serious problem in many Iranian fields. The deposited asphaltene results in partial or total blockage of the wellbore and wellstring reducing or completely seizing oil production. This paper studies the asphaltene problem and mitigation methods in wellstring systematically. It presents new approach based on the combination of thermodynamic modeling of asphaltene precipitation with hydrodynamic well modeling. The developed model is capable to determine the asphaltene precipitation and deposition interval through the wellstring. Therefore, it could study the effect of hydrodynamic parameters such as wellhead pressure, well flow-rate and tubing size... 

Boiling of water/triethyleneglycol (TEG) binary solution has a wide-ranging application in the gas processing engineering. Design, operation and optimization of the involved boilers require accurate prediction of boiling heat transfer coefficient between surface and solution. In this investigation, nucleate pool boiling heat transfer coefficient has been experimentally measured on a horizontal rod heater in water/TEG binary solutions in a wide range of concentrations and heat fluxes under ambient condition. The present experimental data are correlated using major existing correlations. In addition a correlation is presented for prediction of pool boiling heat transfer for the system in which... 

Asphaltene deposition is one of the unresolved problems in oil industries. Little information is available on the critical question of "how fast" the flocculated asphaltene particles deposit across the production wells from the flowing oil. In this study, the mechanisms of deposition of flocculated asphaltene particles from oil have been studied experimentally and theoretically under forced convective conditions using an accurate thermal approach. The effects of oil velocity, flocculated asphaltene concentration and temperature on the rate of asphaltene deposition are investigated. It is observed that during the first few weeks the deposition mechanism is dominant and the erosion of the... 

Asphaltene precipitation and deposition is one of the main problems in some of the oil fields. The deposited asphaltene results in partial or total blockage of the wellstring and reducing or completely seizing oil production. Asphaltene deposition problems have been experienced in the field for a long time. Although, the asphaltene precipitation has been studied thoroughly and different parameters that effects this process has been investigated but little work has been carried out in the asphaltene deposition across the production system of flowing oil well. This paper introduces a new comprehensive model for description of asphaltene deposition behavior in wellstring. The mechanisms of... 

Recently, application of silica nanoparticles (SNP) for enhancing oil recovery during water flooding has been much attended. However, understanding how rock and nanoparticles (NP) interacts through adsorption onto the carbonate reservoir rocks is not well discussed. In this work, adsorption behavior of SNP onto the calcite had been characterized, through kinetic, equilibrium, thermodynamics and electrokinetic studies as well as interaction energy analysis by DLVO theory. Also, field emission scanning electron microscopy (FESEM) was utilized to visualize the adsorption process. It had been found that kinetic behavior of SNP-calcite system followed the pseudo-second order model. Equilibrium... 

Oil recovery from carbonate reservoirs can be enhanced by altering the wettability from oil-wet toward water-wet state. Recently, silica nanoparticle (SNP) suspensions are considered as an attractive wettability alteration agent in enhanced oil recovery applications. However, their performance along with the underlying mechanism for wettability alteration in carbonate rocks is not well discussed. In this work, the ability of SNP suspensions, in the presence/absence of salt, to alter the wettability of oil-wet calcite substrates to a water-wet condition was investigated. In the first step, to ensure that the properties of nanofluids have not been changed during the tests, stability analysis... 

Precipitation of strontium sulfate (or SrSO4) has already been distinguished as one of the most costly and critical problems which may occur in process industries and oilfield operations. Costs due to scaling and remedial actions that need to be taken afterward are generally high owing to low solubility of SrSO4 in aqueous solutions. Therefore, a thorough understanding of the SrSO4 thermodynamic behavior under various operating conditions is vital to predict or even avoid the overall damage caused by scaling. The primary aim of this work is to develop a model based on Least Squares Support Vector Machine (LSSVM) and Coupled Simulated Annealing (CSA) referred to as CSA-LSSVM to predict... 

In this work, application of silica nanoparticles for wettability alteration of initially oil-wet calcite was investigated through analysis of surface forces and DLVO theory. Doing so, the wettability and zeta potential of calcite surfaces were measured through the sessile drop method and an in-house experimental setup, respectively. Primary evaluation indicated that incorporating DLVO terms in the Frumkin-Derjaguin model was not sufficient to describe the wettability in an oil-wet calcite/nanofluid system. Sensitivity analysis showed that calculating the double-layer interaction using constant potential-constant potential boundaries along with structural hydrophobic forces (non-DLVO... 

Deposition of barium sulfate (or BaSO4) has already been recognized as a devastating problem facing process industries and oilfield operations, mainly owing to its low solubility in aqueous solutions. Predicting and also preventing the overall damage caused by BaSO4 precipitation requires a profound knowledge of its solubility under different thermodynamic conditions. The main aim of this study is to develop a solubility prediction model based on a hybrid of least squares support vector nachines (LSSVM) and coupled simulated annealing (CSA) aiming to predict the solubility of barium sulfate over wide ranges of temperature, pressure and ionic compositions. Results indicate that predictions of... 

Precipitation and scaling of calcium sulfate have been known as major problems facing process industries and oilfield operations. Most scale prediction models are based on aqueous thermodynamics and solubility behavior of salts in aqueous electrolyte solutions. There is yet a huge interest in developing reliable, simple, and accurate solubility prediction models. In this study, a comprehensive model based on least-squares support vector machine (LS-SVM) is presented, which is mainly devoted to calcium sulfate dihydrate (or gypsum) solubility in aqueous solutions of mixed electrolytes covering wide temperature ranges. In this respect, an aggregate of 880 experimental data were gathered from... 

Secure routing is a major key to service maintenance in ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. As a result of the resource limitations in such networks nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a novel data redirection method to mitigate the impact of node misbehavior on network...