Synthesis and Characterization of NxOy-Naphthodiazacrowns and Study of Supramolecular Chemistry with C60 and Cu(II)

, M.Sc. Thesis Sharif University of Technology Jamjah, Ali (Author) ; Ghanbari, Bahram (Supervisor)

Abstract

New N4O6 molecular tweezers were synthesized from N2O2 benzo- and naphthodiazacrown macrocycles bearing benzylic dialdehydes as a flexible and semi-flexible spacer in a short time and at room temperature. The products were characterized by IR, 1H and 13C NMR spectroscopy as well as elemental microanalysis. The interactions of some of these tweezers with C60, Cu(II), Co(II), Ni(II), Zn(II), Hg(II) and Mn(II) were investigated by employing UV-Vis and fluorescence spectroscopy. Efficient fluorescence responses for 2NM3BD were observed in the presence of C60, Cu(II), Mn(II), Hg(II) and Zn(II). Meanwhile, the calculation of the association constants (K¬BH) employing Benesi-Hildebrand equation in...

Chromogenic detection of xylene isomers and luminogenic chemosensing of o-xylene employing a new macrocyclic cobalt complex: synthesis, and X-ray crystallographic, spectroscopic and computational studies

, Article New Journal of Chemistry ; Volume 46, Issue 43 , 2022 , Pages 20745-20754 ; 11440546 (ISSN) Ghanbari, B ; Asadi Mofarrah, L ; Jamjah, A ; Sharif University of Technology

Royal Society of Chemistry 2022

Abstract

Here, we report the synthesis and characterization of a binuclear Co(ii) complex (Co2(2py)2Cl4) with two dinaphtho-diazacrown ether macrocyclic ligands, bearing two pyridine arms as a colourimetric and fluorescent sensor for detecting different xylene isomers as well as acting as a catalyst for the oxidation of o- and m-xylene under vacuum at room temperature. Chromogenic detection occurred when Co2(2py)2Cl4 was exposed to the xylene isomers, wherein the original blue colour of the complex changed to green and green-blue in the presence of o- and m-xylene, respectively. Meanwhile, no colour change was observed in the presence of the p-xylene isomer. Fluorescence spectroscopy revealed that...

Tetranuclear Au2Cu2 clusters with butterfly- and planar-shaped metal cores: strong rigidochromism induced by jahn-teller distortion in two-coordinated gold(I) centers

, Article Inorganic Chemistry ; Volume 58, Issue 18 , 2019 , Pages 12122-12131 ; 00201669 (ISSN) Nayeri, S ; Jamali, S ; Jamjah, A ; Samouei, H ; Sharif University of Technology

American Chemical Society 2019

Abstract

Two tetranuclear Au2Cu2 cluster complexes [Au2Cu2(μ-(PPh2)2py)2(μ-OH)](PF6)3, 2, and [Au2Cu2Cl2(μ-(PPh2)2 py)2](OTf)2, 4, have been prepared by the reactions of precursor complexes [Au2(μ-(PPh2)2py)2](OTf)2, 1, and [Cu2(μ-(PPh2)2py)2(μ-SMe2)(OTf)2], 3, with [Cu(NCCH3)4]PF6 and AuCl(SMe2), respectively. The crystal structures of complexes 2 and 4 were determined by X-ray crystallography, indicating a butterfly-shaped Au2Cu2 metal core for 2 and a planar-shaped Au2Cu2 metal core for 4. In complex 2, the Cu atoms occupy the edge-sharing bond, while in complex 4, alternating Au and Cu atoms occupy the tetragon vertices. The optical properties of the complexes were investigated by experimental...

Dynamic and Photophysics of Coinage Metal Complexes Containing Phthalazine and Cyanine Ligands

, Ph.D. Dissertation Sharif University of Technology Jamjah, Ali (Author) ; Jamali, Sirous (Supervisor) ; Ghanbari, Bahram (Co-Supervisor)

Abstract

This dissertation focuses on the design, synthesis, and investigation of the photophysical and chemical properties of three groups of novel compounds. In the first part, dual chromophore systems based on the combination of heptamethine cyanines and naphthalimides have been designed and synthesized, which are linked directly at the meso position. This design was carried out to optimize the energy transfer process between chromophores over short distances. In these systems, naphthalimides with various substituents such as diethylamine, diphenylamine, tert-butylphenoxy, bromine, and unsubstituted forms have been utilized to evaluate their effects on the photophysical properties and energy...

Bis-N-Heterocyclic carbene complexes of coinage metals containing four naphthalimide units: a structure-emission properties relationship study

, Article Inorganic Chemistry ; Volume 60, Issue 17 , 2021 , Pages 12924-12933 ; 00201669 (ISSN) Hendi, Z ; Jamali, S ; Chabok, S. M. J ; Jamjah, A ; Samouei, H ; Jamshidi, Z ; Sharif University of Technology

American Chemical Society 2021

Abstract

Naphthalimide derivatives provide highly versatile self-assembled systems and aggregated forms with fascinating emission properties that make them potential candidates for many applications such as bioimaging and sensing. Although various aggregated species of naphthalimide derivatives have been well documented, little is known about the correlation between their structure and photophysical properties. Here the preparation of a series of tetrameric naphthalimide molecules in which naphthalimide units are linked by bis-N-heterocyclic carbene complexes of coinage metals is described. An in-depth structural investigation into these tetramers has been carried out in solution and the solid state...

Five- and six-coordinated silver(I) complexes formed by a metallomacrocyclic ligand with a “Au2N2” donor group: observation of pendulum and linear motions and dual phosphorescence

, Article Inorganic Chemistry ; Volume 59, Issue 8 , 31 March , 2020 , Pages 5702-5712 Nayeri, S ; Jamali, S ; Jamjah, A ; Shakirova, J. R ; Tunik, S. P ; Gurzhiy, V ; Samouei, H ; Shahsavari, H. R ; Sharif University of Technology

American Chemical Society 2020

Abstract

The six-coordinated silver(I) complex [Au2Ag(μ-(PPh2)2py)2(OTf)2](OTf), 4 (py = pyridine, OTf = CF3SO3), and the five-coordinated silver(I) complex [Au2Ag(acetone)(μ-(PPh2)2py)2](PF6)3, 6, were prepared by the reaction of the precursor complexes 1(OTf)2 and 1(PF6)2, in which 1 = [Au2(μ-(PPh2)2py)2]2+, with 1 equiv of Ag(OTf) in dichloromethane and excess of Ag(PF6) in a mixture of dichloromethane/acetone, respectively. Also, the five-coordinated silver(I) complex [Au2Ag(μ-(PPh2)2py)2(py)(OTf)](OTf)2, 5, was obtained by the reaction of 4 with pyridine. The clusters 4-6 were characterized using multinuclear NMR spectroscopy and elemental microanalysis. The single-crystal X-ray diffraction...

Pt-M (M = Au and Tl) Dative Bonds Using Bis(cyclometalated)platinum(II) Complexes

, Article Organometallics ; Volume 38, Issue 8 , 2019 , Pages 1709-1720 ; 02767333 (ISSN) Rajabi, S ; Jamali, S ; Naseri, S ; Jamjah, A ; Kia, R ; Samouei, H ; Mastrorilli, P ; Shahsavari, H. R ; Raithby, P. R ; Sharif University of Technology

American Chemical Society 2019

Abstract

Symmetrical and unsymmetrical biscyclometalated platinum(II) complexes [Pt(ptpy)2], 1, and [Pt(ptpy)(bppy)], 2, in which ptpy = deprotonated 2-(p-tolyl)pyridine and bppy = deprotonated 2-(3-bromophenyl)pyridine, have been prepared from the reaction between tris(pentafluorophenyl)borane, B(C6F5)3 and 1 equiv of monocyclometalated complexes [PtMe(ptpy)(ptpyH)], B, and [PtMe(ptpy)(bppyH)], C, respectively. The solid-state structures of 1 and 2 have been determined by X-ray crystallography. The reaction of 1 with 1 equiv of TlPF6 or [Au(PPh3)]OTF resulted in the production of heteronuclear complexes [Pt(ptpy)2Tl]PF6, 3 and {Pt(ptpy)2[Au(PPh3)]}OTF, 4, respectively. X-ray diffraction data showed...

Technical English for mechanical engineers

, Book Alemi, Minoo ; Meghdari,Ali

Sharif University Press 2014

Abstract

Local educational institutions produce in-house English for Specific Purpose (ESP) materials according to the curriculum policies designated and developed by the Ministry of Higher Education In Iran. To this end, this book aims to be used in the Iranian setting at the tertiary level for undergraduate students majoring in Mechanical Engineering. Moreover, the style of English usage in this ESP textbook is American.
Regarding the content of the textbook, it has both thematic organizations in which the topics are relevant and includes sufficient treatment of the target language areas necessary for the students. The principle organizing approach of this textbook is theme-based. In addition,...

Feedback control of the neuro-musculoskeletal system in a forward dynamics simulation of stair locomotion [electronic resource]

, Article Proc. of IMechE Part H: Journal of Engineering in Medicine ; 2009, Vol. 223, No. 6, pp. 663-675 Journal of NeuroEngineering and Rehabilitation ; Volume 11, Issue 1, 30 April 2014, Article number 78 Selk Ghafari, A. (Ali) ; Meghdari, Ali ; Vossough, Gholam Reza ; Sharif University of Technology

Abstract

The aim of this study is to employ feedback control loops to provide a stable forward dynamics simulation of human movement under repeated position constraint conditions in the environment, particularly during stair climbing. A ten-degrees-of-freedom skeletal model containing 18 Hill-type musculotendon actuators per leg was employed to simulate the model in the sagittal plane. The postural tracking and obstacle avoidance were provided by the proportional—integral—derivative controller according to the modulation of the time rate change of the joint kinematics. The stability of the model was maintained by controlling the velocity of the body's centre of mass according to the desired centre of...

Design and Construction of a Soft Actuated Exoskeleton for Hand Rehabilitation of Stroke Patients

, M.Sc. Thesis Sharif University of Technology Razavi Zadehgan, Ali Akbar (Author) ; Ghafari, Ali (Supervisor) ; Meghdari, Ali (Supervisor)

Abstract

The main goal of this thesis is the design and development of a rehabilitation device for helping patients “to improve blood circulation” & retain and recover their abilities if possible that were lost during the stroke or a accident like that (my research in karaj/iran shows that it is possible by just movement of the specific body part). The focus is on hand in this thesis because Injuries to the hand are common and can be very debilitating since our hands are our primary means for interacting with our world. For rehabilitation in case of human hand there are several practices that should be done for patients either in home or in a rehabilitation center, time and money that is supposed to...

Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]

, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 Mirjalili, B. F. (BiBi Fatemeh) ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid

Abstract

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition

Earthquake Branch

, M.Sc. Thesis Sharif University of Technology Bagher Shemirani, Ali Reza (Author) ; Bakhshi, Ali (Supervisor)

Abstract

In the past few decades, shaking tables are widely used to evaluate system response of structures under seismic excitations. These devices are used without any fundamental research performed on a shaking table system as an entity model. In most of these studies for simplicity, it is assumed that there exist no considerable vibration and displacement around the shaking tables, and no attention is paid to the peripheral substances such as soil settled under the foundation.
In this thesis, result of ambient vibration test on shaking table system (solid deck, concrete foundation and soil layer) has been presented. Precise sensors known as low frequency and high accuracy accelerometers have...

Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions [electronic resource]

, Article Journal of Chemical Research ; Volume 2002, Number 8, 1 August 2002, pp. 378-380(3) Pourjavadi, A. (Ali) ; Bagheri Marandi, Gholam

Abstract

Free Content Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions

Selective preparation of fluorescent 1,8-naphthalimides using acidic alumina under microwave irradiation [electronic resource]

, Article Journal of Chemical Research ; 01/2001; 2001(11):485-487 Pourjavadi, A. (Ali) ; Bagheri Marandi, Gholam

Abstract

7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one compounds were prepared in a selective manner by reaction between o-phenylenediamines and appropriate 1,8-naphthalenedicarboxylic anhydrides using acidic alumina under microwave irradiation

Comparison between Performance of Stone Columns and RAPs from the Bearing Capacity and Settlement Reduction Viewpoints

, M.Sc. Thesis Sharif University of Technology Golestani Dariani, Ali Akbar (Author) ; Pak, Ali (Supervisor)

Abstract

Out of several ground improvement techniques available, stone columns have been widely used. This technique has been successfully applied to increase the bearing capacity and to reduce the settlement for foundation of structures like liquid storage tanks, earthen embankments, raft foundations, etc., where a relatively large settlement is permissible. This technique has, generally, been proven successful in increasing the stiffness of weak soils, upgrading their safe bearing capacity, and reducing their total and differential settlements, as well as speeding up their consolidation process. The beneficial effects of stone column installation in weak deposits is manifested in the form of...

Performance of Partially Filled Mini-Channels with Porous Media

, M.Sc. Thesis Sharif University of Technology Azimi, Adel (Author) ; Nouri, Ali (Supervisor) ; Moosavi, Ali (Co-Advisor)

Abstract

Laminar forced convection flow through a channel partially filled with a porous material was numerically studied in this thesis. The Navier-Stokes and Brinkman-Forchheimer equations were used to model the fluid flow in the free and porous regions, respectively. Coupling of the pressure and velocity fields was resolved using the SIMPLEC algorithm. The local thermal equilibrium was adopted in the energy equation. The effects of the thermal conductivity ratio, Darcy number, porosity, Reynolds number and height of the porous insert on velocity and temperature field were investigated. The results show that the flow behavior and its associated heat transfer are susceptible to the variation of the...

Improvement of Stability of Haptic Force Interaction with Virtual Environments Using a Haptic Interface with a Separate Tracker

, M.Sc. Thesis Sharif University of Technology Mashayekhi, Ahmad (Author) ; Meghdari, Ali (Supervisor) ; Nahvi, Ali (Supervisor)

Abstract

In the present study, a new version of haptic devices is presented in which user’s hand is in contact with the device just while collision with virtual surface. In this system, the position of user’s finger can be traced by using a camera and the haptic device follows user’s finger at the distance of about two centimeters. While the haptic device approaches to the virtual surface, gradually reduces its speed and stops about two centimeters distant of virtual plane. Then user’s hand collides with the haptic device which is static. Greater fidelity, transparency, more stability and also no need to large actuators are of the advantages of this system. In this project, first we present a new...

Simulation of the Biomolecule Imaging and Manipulation Via AFM by Molecular Dynamics Method

, M.Sc. Thesis Sharif University of Technology Kheiroddin, Mohsen (Author) ; Meghdari, Ali (Supervisor) ; Moosavi, Ali (Supervisor)

Abstract

In this thesis we try to find optimized parameters for imaging and manipulation of a biosample with AFM. For this we have prepared a numerous Molecular Dynamics simulation and find some reliable result. So, first we have focused on imaging process in Non contact mode (the less harmful mode). Then we headed into the manipulation process. The main problem about manipulating a biosample is the environment. In imaging section, the process of imaging a biomolecule by AFM is modeled using molecular dynamics simulations. Since the large normal force exerted by the tip on the biosample in contact and tapping modes may damage the sample structure and produce irreversible deformation, the non-contact...

Characterzing Variation of Small Strain Shear Modulus of Unsaturated Sand During Hydraulic Hysteresis with Bender Elements

, M.Sc. Thesis Sharif University of Technology Shahbazan, Parisa (Author) ; Pak, Ali (Supervisor) ; Khosravi, Ali (Supervisor)

Abstract

Results of previous studies on silt and clay indicated that variations in the small strain shear modulus, Gmax, during drying had a non-linear increasing trend with matric suction with greater values upon wetting. However, due to different material properties and inter-particle forces, different behaviour in Gmax is expected for sand. Although considerable research has been devoted in recent years to characterize the behaviour of Gmax of sand during drying, rather less attention has been paid to the effect of hydraulic hysteresis on Gmax and its variations during wetting. In the study presented herein, an effort was made to characterize the variation of Gmax for specimens of sand during...

Sequential Competitive Facility Location In Continuous Geometric Space

, M.Sc. Thesis Sharif University of Technology Lavasani, Ali Mohammad (Author) ; Abam, Mohammad Ali (Supervisor)

Abstract

Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...