Sharif Digital Repository

We are interested in the relation between entanglement and quantum phase transitions. We have presented a formulation on how the entanglement of a very large the system is related to the entanglement of a small part of system. The renormalization of entanglement is an indicator of the critical behavior of the models. The framework of our approach is introduced about the Ising model. In particular, we show that derivative of entanglement developes a minimum close to the critical point. We further clarify that this minimum point approaches to the exact critical point of the system as the system becomes thermodynamic. This phenomenon is governed by an exponent that is closely related to the... 

In this study, pitting corrosion of 304, 316 and 316L stainless steels in 3.5% NaCl solution at different temperatures (25, 40, and 70°C), were studied by electrochemical methods such as Cyclic Potentiodynamic Polarization, Electrochemical Impedance Spectroscopy and Immersion tests. Also, the effects of different concentrations of polyethyleneimine with two molecular weights (2000 and 60000 g/mol) on pitting corrosion of these steels were investigated. Finally, the adsorption behavior of inhibitors on surface of alloys was investigated by Atomic Force Microscopy (AFM) and Attenuated Total Reflectance Fourier transform spectroscopy (ATR-FTIR). It was found that both inhibitors prevent... 

The anisotropic Heisenberg ferrimagnet which is composed of two different kind of spins is studied. We have found the exact (factorized) ground state of a general class of ferrimagnets in the presence of a magnetic field which includes the frustrated, anisotropic and long range interactions for arbitrary dimensional space. The factorized ground state is a product of single particle kets on a bipartite lattice composed of two different spins (σ, ρ) which is characterized by two angles, a bi-angle state. The spin waves analysis around the exact ground state show two branch of excitations which is the origin of two dynamics of the model. The signature of these dynamics is addressed as a peak... 

Entanglement spectrum is the set of eigenvalues of reduced density matrix for a definite state. It contains more information than the entanglement entropy. This spectrum can show entanglement measure, quantum phase transition and topological order in a system. In recent years, the entanglement spectrum for several models has been studied. The entanglement spectrum shows a correspondence to the energy spectrum within some specific regions, which are related to the edge state of the system; It has been verified for the Heisenberg ladder [1] and fractional quantum Hall effect [3]. Moreover, the topological order can be seen in the entanglement spectrum. There exists an acceptable adaption... 

In this thesis, we consider the Kondo-necklace model to investigate the quantum phase transition between the Kondo-singlet and antiferromagnetic phases. There is no exact solution for this model. We would like to study the quantum critical behaviour of this model on one, two and three dimensional spaces in addition to ladder geometry. In this respect, we looked for a proper method which can give us some information for our model on any spaces mentioned above. Therefore, we implemented the perturbation continuous unitary transformation (PCUT) for the Kondo-necklace model. By using this method, we can not only calculate the ground state energy for 1, 2, 3 dimension and n-leg ladder... 

Bioactive glasses are able to bond to soft and hard tissues in living body and their application as coating on metallic implants like 316L stainless steel has two important effects: (1) intimate link between bone and materials and (2) corrosion protection of metallic implant in body fluid and protection from tissues in front of corrosion products. Therefore, in this research, 45S5 bioactive glass prepared via sol- gel method was dip coated on 316L stainless steel substrates and its characteristics was investigated.Results of phase analysis showed that by sintering 45S5 bioglass at 600 ˚C for 5 h, an amorph sample with small amount of Na2Ca2Si3O9 was obtained. So, the bioglass coated samples... 

Strongly correlated materials are kind of materials in which novel electric and magnetic properties will appear as a result of strong correlations among their electrons like “heavy fermion materials”. Kondo lattice model is a model to describe heavy fermion materials. If we are merely interested in the magnetic properties of heavy fermions we can replace the Kondo lattice Model with the simpler model called the Kondo-necklace model which consists of the interactions only among the spins of the itinerant (conduction) and localized electrons (magnetic impurities) and also the interactions between the spins of the itinerant electrons. In this thesis we investigate the properties of the one... 

One of the most important factors of reducing durability of concrete structures is corrosion of steel reinforcement in concrete. In this paper, corrosion behavior of reinforcing steel in concrete is investigated in two different methods of protection based on neural network. As regard the first method, pozzolanic additives with optimized percentage were added to Concrete mix design (the percentage of these additives are 25% Weight of cement of fly ash, Micro silica with 10 percent of weight of cement and 25% of Blast Furnace slag weight of cement). In the second approach of protection, 0/5 percent weight of cement of ferrogard 901 inhibitor is added to basic mix concrete design and the... 

Magnesium and its alloys have been used as biodegradable implements in recent years. However Magnesium implements may corrode in the body before the natural healing process of the damaged tissue. MAO process was studied in order to reduce primary corrosion of Magnesium alloy in Simulated Body Fluid (SBF). MAO coating was created on AZ31 alloy in a nontoxic alkaline-silicate solution at DC current densities of 5, 10, 15 and 20 mA/cm2 for 30 minutes and the current was in form of 20-10-5 mA/cm2 steps that each were applied for 10 minutes. The maximum corrosion resistance was observed for the mentioned step applied current in a 30g/l Sodium Silicate solution. Furthermore the effects of adding... 

In this thesis, we have implemented the quantum renormalization group method to study quantum spin systems. We reviewed the recent progress to calculate the quantum information properties of these models. The recent investigations show that concurrence and entanglement are two quantities which can show quantum critical properties of the quantum systems. More specifically, the derivative of entanglement and the second derivative of ground state energy show divergent behavior at the quantum critical point. Moreover, the ground state fidelity for two different parameters close to quantum critical point shows a drop which leads to a divergent behavior in its corresponding susceptibility. We have... 

The fascinating subject of heavy fermion physics in rare-earth and actinide systems has been a challenge for theoretical and experimental investigations for decades. Kondo Necklace model is one of the promising models in the study of strongly-correlated heavy fermion compounds, which is studied in this project.One of the methods to diagonalize a Hamiltonian properly, regardless of system size, is the continuous unitary transformation. In this approach, the Hamiltonian is considered as a function of a flow parameter. The Hamiltonian is transformed to a simpler form (diagonal or band-block diagonal) under a flow equation which is based on applying infinite numbers of infinitesimal unitary... 

Microbiologically Influenced Corrosion (MIC) of concrete sewer ptpes and wastewater collection systems has been reported in many places of the world. Recently, numerous copper compounds have been used for bacterial growth control in sewer pipes. In this thesis, bath parameterswere optimized in order to maximize copper osmosis to the porous concrete matrix.Concrete pipes were electrochemically coated inCopper Lactate bath in a constant current mode (1=0.6 A), while temperature was set to 25, 50, 75 and 95
°Cand pH to 9,10 and 11. Specimens were then characterized by scanning electron

microscopy, optical microscopy, XRD andAAS. Copper Osmosis was highest in pH=9 and... 

Recently magnesium alloys have shown great potential as biodegradable metallic implants. However, due to high corrosion rate in the body environment, these alloys would be degraded before the tissue healing time period. Therefore corrosion resistance of these alloys has to be improved in order to be used in biological environments. In the present work, supposing improvement of corrosion properties of magnesium AZ91D alloy, the alloy has been coated with biocompatible nano-Zirconia particles using Electrophoretic deposition method and the effects of deposition parameters such as bath agitation, Zirconia concentration, current density and duration of deposition process on the properties of the... 

Due to their favorable biodegradability, Magnesium and its alloys have always attracted such a lot of research interests for making temporary implants. With the same direction, Mg-4Zn-0.2Ca has recently absorbed lots of research interests, due to its excellent biocompatibility. As the most regarded draw back concerned with this alloy, poor corrosion resistance is frequently discussed. Accordingly, in the present work it has been tried to come over this problem by addition different amount of aluminum, including 1, 3, 5, 7.5, and 10 percent, to this alloy; without causing any negative effect on its biocompatibility, and to present a new alloy composition with modified degradation behavior.... 

In this research, role of zirconia nanoparticles as a biocompatible material which has great mechanical properties, was investigated on corrosion behavior and bonding strength of HA coating. HA- ZrO2 composite prepared by a 2-step pulse electrodeposition method. Effect of pH (3.5, 4.5), bath temperature (60, 80 ͦC), current density (0.5, 1, 2 mA/cm2) and zirconia concentration (5, 10, 15 g/L) on coating characteristics were studied. X-ray diffraction was employed for phase analysis. Morphology and microstructure of samples observed utilizing scanning electron microscope (SEM) and elemental analysis was done by EDS. In order to corrosion studies electrochemical impedance spectroscopy (EIS)... 

In this study anodized none composite and composite film containing ZrO2 nanoparticles were prepared on 1050 Al Alloy using hard anodizing method in sulfuric and oxalic acid mixed solution by pulse Currents. The microstructure and properties of the film were studied by field emission scanning electron microscopy with EDS analyzer and XRD diffraction and friction wear test were performed to evaluate the mechanical properties of coating . Results indicate that the composite film with ZrO2 nanoparticles have reduced friction coefficient with high micro hardness friction coefficient of composite film can be small as 0.16 which is much smaller than that 0.39 of none composite film. Micro hardness... 

Plants and aquatic creatures growth on the surface of human made structures is a typical phenomena. One of the approaches to prevent algae and moss to grow is using paint coatings including biocides. In this research project, anti-moss paints containing Copper Oxide as the major biocide and Zinc Oxide as the minor biocide have been synthesized. The effects of different parameters like the type of resin, biocide concentration, biocide grain sizes, dip time, and the coating layer thickness on the release rate which is the most important factor to prevent moss growth, have been investigated. Then, the experiment has been conducted on the specimens in algae growth and flustered sea water... 

In this study, linear polarization resistance (LPR) of cathodic pulse electrodeposited graphene- Nickel-Molybdenum coating is optimized by design of experiments approach (central composite design). Applied current density (i), cathodic pulse durations (Ton) and total electrodeposition time (Ttotal) are selected as the substantial factors. The best prediction model proposes a definitive linear relation without any significant interaction of the LPR by analysis of variance. The best value of LPR is achieved equal to 1406KΩ.cm2, obtaining at i of 137.5 A/cm2, Ton of 45.5 ms and Ttotal equal to 315 s. Polarization test is carried out to determine corrosion behavior of the coating. It shows... 

Metallic implants are useful in dental and orthopedic applications. Bio coating is necessary to improve bio-compatibility and bio-activation of metallic implants. For this goal, HA is the most important material. In this research, the goal is to improve bio-compatibility of St. St 316 by coating HA, HA-ZrO2, HA-TiO2, HA-ZrO2-TiO2 using combination of electrodeposition and electrophoretic methods. To form HA, calcium and phosphor salt solution was used then ZrO2- TiO2 nanoparticles was added to solution. In order to analyst the coatings different tests were done. Thickness analysis, XRD, FT-IR, FE-SEM and EDS, bonding Strength, Polarization test, bio-compatibility and surface roughness...