Sharif Digital Repository

In this work, we present the design and fabrication of a novel nanocomposite based on noble metal and metal oxide nanoparticles dispersed on highly porous carbon obtained via the pyrolysis of an inorganic complex and metal-organic frameworks. This nanocomposite is prepared by a two-step procedure: first, the composite support of nanoporous carbon (NPC) is obtained by the direct carbonization of the Cr-benzene dicarboxylic ligand (BDC) MOF in an Argon atmosphere at 500 °C (Cr2O3-NPC). A mixture containing Cr2O3-NPC and [PtCl(SnCl3)(SMe2)2] is then prepared, and underflow of Argon is heated to 380 °C. Finally, Pt-SnO2 nanoparticles are loaded on the Cr2O3-NPC support, and the obtained... 

Implementation of metal organic frameworks (MOFs) in the separation science has attracted many researchers attention. In this study, the role of metal, ligand, the reaction condition and modification on the extraction efficiency of some MOFs was investigated. Among the prevalent reported MOFs, some members of the MIL and MOF–5 families were chosen, and eleven MOF–based sorbents were prepared by changing the metal and ligand type, reaction condition, and/or functionality through post synthetic modification (PSM). MIL–101 and MIL–101–NH2 based structures were initially synthesized based on the chromium and iron salts. Also, three zinc–based structures including MOF–5, [NH2(CH3)2]2... 

Here, a three dimensional nickel–based metal organic framework (MOF) was synthesized via solvothermal and room temperature protocols. In order to study the effects of the synthesis conditions on the physical properties such as pore sizes and shapes of the prepared MOFs, their extraction capabilities were examined. Both MOFs were characterized by Fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, Brunauer–Emmett–Teller and thermogravimetric analyses. Brilliant properties such as porous structure, high surface area and considerable thermal stability make them reasonable candidates to be employed as efficient extractive phases. The efficiency of the... 

A stable porous zinc-based metal organic framework (MOF) containing nitrogen-rich bis-tetrazolate ligand was synthesized to study the role of similar structures concerning both extractive phase and the desired solutes to achieve greater sorption efficiency. With implementing a dispersive micro-solid phase extraction (d-µ-SPE) methodology, the sorption capability and influencing structural parameters i.e., porosity, surface area and interactions types were investigated for the synthesized zinc-bis-tetrazolate (ZnBT) MOF and compared with some synthesized sorbents such as MIL-101, MIL-101-NH2, cadmium naphthalene dicarboxylic acid dimethyl formamide [Cd(NDC)(DMF)], polyaniline and LiChrolut®... 

Spacecraft rendezvous and docking are two processes in which a chaser pursues and meets a leader spacecraft in order to perform several mission based tasks. Although in some preliminary design analysis, these two operations may be pursued independently there could be circumstances in which the spacecraft trajectory and attitudes are coupled and interdependent. The present study is based on the presumption that the often independent translational and rotational motions of the spacecraft are coupled as a result of thrust misalignment. So the thrusters not only contribute to the rendezvous translational motion, but also affect the docking reorientation maneuver through their disturbing effects.... 

In this work, high-performance thin-layer chromatography (HPTLC) coupled with multivariate image analysis (MIA) is proposed as a fast and reliable tool for authentication and adulteration detection of Iranian saffron samples based on their HPTLC fingerprints. At first, the secondary metabolites of saffron were extracted using ultrasonic-assisted solvent extraction (UASE) which was optimized using central composite design (CCD). Next, the RGB coordinates of HPTLC images were used for estimation of saffron origin based on principal component analysis (PCA). The PCA scores plot showed that saffron samples were clustered into two clear-cut groups which was 92% matched with the geographical... 

The present work is a numerical investigation into the waves generated by a pressure source moving in straight channels with a nonrectangular cross-channel depth profile. Wave fields generated by the moving pressure source are described, and the effects of channel bathymetry on the generated wave characteristics of wave height, wave-breaking location, wave-breaking type and intensity, and peel angle are presented. Four different channel cross-section shapes were investigated, and the results were analyzed. It was concluded that the maximum wave height depended primarily on pressure-source parameters and that the investigated channel shapes did not have a significant effect on the maximum... 

In the current study, experimental tests are conducted to evaluate the hydrodynamic characteristics and the bottom wetted surfaces of the planing hulls equipped by one transverse step. For this purpose, total resistance, dynamic trim angle, dynamic sinkage, reattachment lengths of the separated flow and forebody and aftbody wetted areas are quantitatively measured at different geometrical parameters of the step and hull velocities. Moreover, the bottom wetted surfaces are qualitatively investigated by analyzing the underwater photographs. Our experimental results are also compared by archival data with good accordance. Based on our experimental observations, dynamic trim angle and dynamic... 

Polyhedral oligomeric silsesquioxanes are 3D nanoscaled materials with large potential in solid phase microextraction (SPME). Here, as a case study, an octaglycidyldimethylsilyl modified polyhedral oligomeric silsesquioxane network is described. It was deposited on a stainless steel wire via a sol–gel method and used as a fiber coating for SPME of aromatic compounds. The uniform pore structure, high surface area, and hydrophobicity of the network make it susceptible toward isolation of non-polar and semi-polar chemical compounds. The performance of the fiber coating was tested with three classes of environmental pollutants, viz. chlorobenzenes (CBs), benzenes (benzene, toluene, ethylbenzene,... 

In this study, the effect of moving pressure source and channel parameters on the generated waves in a channel was numerically investigated; draught, angle of attack, and profile shape as parameters of pressure source, and water depth and blockage factor as channel parameters for wave height. Firstly, the chosen Computational Fluid Dynamics (CFD) approach was validated with the experimental data over a range of speeds. Then, the CFD study was conducted for further investigations. It was shown that that by enlarging draught, angle of attack, and beam of the pressure source, the wave height generated would be increased. Channel study showed that it was possible to increase the wave height... 

Trimaran vessels are developed for different applications and hydrodynamic behavior of such vessels is different than usual mono-hulls. In this paper hydrodynamic resistance and maneuvering of a trimaran with Wigley body form are investigated. The effects of outriggers position in four different longitudinal and two transverse locations are studied. For hydrodynamic simulations a CFD code has been developed and used. This code is capable for simulating three dimensional, time dependent, two phases, viscous flow coupled with rigid body motion. Formulation and solution algorithm are described in detail. Different case studies have been performance and numerical results have shown good... 

Implementation of metal-organic frameworks (MOFs) in the separation science is attractive for many researchers, nowadays. In this study, three MOFs were synthesized and employed as extractive coating fibers. The MIL-101-NH2-based coatings were implemented in immersed solid phase microextraction (ISPME) of organophosphorus pesticides (OPPs) from real-life samples. The three different kinds of fiber coatings included MIL-101-NH2 and its acyl and ethyl modified structures as particles and 3-aminopropyl triethoxysilane (APTES) sol-gel precursor as binder. Each single MOF was coated on a stainless steel substrate via sol-gel technique. The uniform and tunable pore structure, high surface area,...