Sharif Digital Repository

Implementation of metal organic frameworks (MOFs) in the separation science has attracted many researchers attention. In this study, the role of metal, ligand, the reaction condition and modification on the extraction efficiency of some MOFs was investigated. Among the prevalent reported MOFs, some members of the MIL and MOF–5 families were chosen, and eleven MOF–based sorbents were prepared by changing the metal and ligand type, reaction condition, and/or functionality through post synthetic modification (PSM). MIL–101 and MIL–101–NH2 based structures were initially synthesized based on the chromium and iron salts. Also, three zinc–based structures including MOF–5, [NH2(CH3)2]2... 

Here, a three dimensional nickel–based metal organic framework (MOF) was synthesized via solvothermal and room temperature protocols. In order to study the effects of the synthesis conditions on the physical properties such as pore sizes and shapes of the prepared MOFs, their extraction capabilities were examined. Both MOFs were characterized by Fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, Brunauer–Emmett–Teller and thermogravimetric analyses. Brilliant properties such as porous structure, high surface area and considerable thermal stability make them reasonable candidates to be employed as efficient extractive phases. The efficiency of the... 

A stable porous zinc-based metal organic framework (MOF) containing nitrogen-rich bis-tetrazolate ligand was synthesized to study the role of similar structures concerning both extractive phase and the desired solutes to achieve greater sorption efficiency. With implementing a dispersive micro-solid phase extraction (d-µ-SPE) methodology, the sorption capability and influencing structural parameters i.e., porosity, surface area and interactions types were investigated for the synthesized zinc-bis-tetrazolate (ZnBT) MOF and compared with some synthesized sorbents such as MIL-101, MIL-101-NH2, cadmium naphthalene dicarboxylic acid dimethyl formamide [Cd(NDC)(DMF)], polyaniline and LiChrolut®... 

The present work is a numerical investigation into the waves generated by a pressure source moving in straight channels with a nonrectangular cross-channel depth profile. Wave fields generated by the moving pressure source are described, and the effects of channel bathymetry on the generated wave characteristics of wave height, wave-breaking location, wave-breaking type and intensity, and peel angle are presented. Four different channel cross-section shapes were investigated, and the results were analyzed. It was concluded that the maximum wave height depended primarily on pressure-source parameters and that the investigated channel shapes did not have a significant effect on the maximum... 

In the current study, experimental tests are conducted to evaluate the hydrodynamic characteristics and the bottom wetted surfaces of the planing hulls equipped by one transverse step. For this purpose, total resistance, dynamic trim angle, dynamic sinkage, reattachment lengths of the separated flow and forebody and aftbody wetted areas are quantitatively measured at different geometrical parameters of the step and hull velocities. Moreover, the bottom wetted surfaces are qualitatively investigated by analyzing the underwater photographs. Our experimental results are also compared by archival data with good accordance. Based on our experimental observations, dynamic trim angle and dynamic... 

Polyhedral oligomeric silsesquioxanes are 3D nanoscaled materials with large potential in solid phase microextraction (SPME). Here, as a case study, an octaglycidyldimethylsilyl modified polyhedral oligomeric silsesquioxane network is described. It was deposited on a stainless steel wire via a sol–gel method and used as a fiber coating for SPME of aromatic compounds. The uniform pore structure, high surface area, and hydrophobicity of the network make it susceptible toward isolation of non-polar and semi-polar chemical compounds. The performance of the fiber coating was tested with three classes of environmental pollutants, viz. chlorobenzenes (CBs), benzenes (benzene, toluene, ethylbenzene,... 

In this study, the effect of moving pressure source and channel parameters on the generated waves in a channel was numerically investigated; draught, angle of attack, and profile shape as parameters of pressure source, and water depth and blockage factor as channel parameters for wave height. Firstly, the chosen Computational Fluid Dynamics (CFD) approach was validated with the experimental data over a range of speeds. Then, the CFD study was conducted for further investigations. It was shown that that by enlarging draught, angle of attack, and beam of the pressure source, the wave height generated would be increased. Channel study showed that it was possible to increase the wave height... 

Trimaran vessels are developed for different applications and hydrodynamic behavior of such vessels is different than usual mono-hulls. In this paper hydrodynamic resistance and maneuvering of a trimaran with Wigley body form are investigated. The effects of outriggers position in four different longitudinal and two transverse locations are studied. For hydrodynamic simulations a CFD code has been developed and used. This code is capable for simulating three dimensional, time dependent, two phases, viscous flow coupled with rigid body motion. Formulation and solution algorithm are described in detail. Different case studies have been performance and numerical results have shown good... 

A three–dimensional metal organic framework (3D–MOF) and a two–dimensional polyoxometalate (2D–POM), both incorporating nanostructured molybdenum (VI) oxide, were synthesized and implemented for headspace needle trap extraction of traces of chlorobenzenes (CBs). The 3D–MOF of type {(Mo2O6)(4,4′–bpy)}n and the 2D–POM of type [4,4′–bpy][Mo7O22] were synthesized by a solvothermal process and characterized by FT–IR, powder X–ray diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetry, energy dispersive X–ray, elemental mapping and Brunner–Emmet–Teller adsorption analyses. The 3D–MOF proved to be superior. Following thermal desorption, the CBs... 

The hydro-acoustic analysis of submerged propellers is an important issue in marine industries, which is examined to reduce the vibrations and noise level of vessels alongside reducing fuel consumption and improving hydrodynamic efficiency. B-series propellers are common propellers whose hydrodynamic and acoustic investigation through applying suitable rake, and skew angle can offer proper results to designers for enhancing the hydrodynamic performance and reducing noise. In this study, a model of the five-bladed B-series propeller with the normal skew angle is chosen. The effects of geometric parameters, including the rake angle, skew angle, geometric pitch ratio, and the number of blades... 

This paper is a counterfactual analysis investigating the consequences of the formation of a currency union for Canada and the USA: whether outputs increase and prices decrease if these countries form a currency union. We use a two-country cointegrated model to conduct the counterfactual analysis, where the conditional forecasts are generated based on the Gaussian assumption. To deal with structural breaks and model uncertainty, conditional forecasts are generated from different models/estimation windows and the model-averaging technique is used to combine the forecasts. We also examine the robustness of our results to parameter uncertainty using the wild bootstrap method. The results show...