Sharif Digital Repository

Modeling fate of nitrogen in unsaturated and saturated zone is a complex process, which requires detailed geochemical data. Complexities of the process as well as data insufficiencies are two major issues, which make quantitative assessment of the problem more complicated. In this work, a lumped-parameter model (LPM) is proposed that has been evaluated for a data-limited case to study temporal and steady-state behavior of Nitrate and Ammonium in unsaturated zone. The concentration of components in the model are assumed as the depth-averaged concentrations, and dispersive fluxes have been neglected. The case study area is Tehran City aquifer, which is highly contaminated by domestic... 

Since most of models for estimation of groundwater contamination are developed for agricultural applications and they are often sophisticated, in this paper a combined approach based on analytical methods that need limited input data has been developed. To estimate nitrate contamination of unsaturated zone in large areas, a Lumped Parameter Model (LPM) and the mass balance approach have been used together. In the case study, model results show an acceptable correlation with field measurements. In addition, the fate of nitrogen in the unsaturated zone is simply defined. © 2008 Taylor & Francis Group, London, UK  

Wettability alteration is the principal low-salinity-effect (LSE) in many oil-brine-rock (OBR) systems. Our recent experimental results have demonstrated that wettability alteration by low salinity is slow. It is expected that the electrical behavior of oil/brine and rock/brine interfaces and the water film geometry control both the transient hydrodynamic pressure, and the time-scale of ionic transport in the film, thus the kinetics and degree of wettability alteration. In this paper, the electro-diffusion process induced by the imposed ionic strength gradient is simulated by solving Poisson-Nernst-Planck equations in a water film bound between two charged surfaces, using a finite... 

The slow kinetics of wettability alteration toward a more water-wetting state by low-salinity waterflooding (LSWF) in oil-brine-rock (OBR) systems is conjectured to be pertinent to the electrokinetic phenomena in the thin brine film. We hypothesize that the nanoscale physicochemical heterogeneities such as surface roughness and surface charge heterogeneity at the rock/brine interface control further the dynamics of electrodiffusion and electrostatic disjoining pressure (Πel), thus the time-scale and the magnitude of the low salinity effect (LSE). In this regard, film-scale computational fluid dynamics (CFD) simulations were performed. The coupled Poisson-Nernst-Planck (PNP) equations were... 

The efficiency of low salinity waterflooding, particularly during tertiary mode injection, is highly controlled by in situ mixing between the stagnant regions holding high salinity water (HSW) and the flowing regions containing low salinity water (LSW) because it impacts directly the electrokinetics of wettability alteration and the time scale of the low salinity effect. This study aims to address the effects of oil polarity and charged rock surfaces on the time scale of mixing and transport under two-phase flow conditions. A systematic series of micromodel experiments were performed. The micromodels were first saturated with high salinity formation brine and oil (both model and crude oil);... 

The dynamics of droplet detachment from a surface is a fundamental topic studied in coating engineering, fluid mechanics, and subsurface engineering applications. This topic has direct relevance to wettability alteration using the modified ionic composition of water in contact with oil droplet, low salinity waterflooding (LSWF). Previous experimental studies of LSWF have shown a very long timescale in wettability alteration which cannot be explained using bulk diffusion coefficient. In the present study, we address both the time scale of detachment, as well as the impact of buoyancy and interfacial forces (referred to as Bond number) on droplet detachment by proposing an advanced... 

As the result of safety factors considered in load and resistant values for the design of new offshore platforms, a higher resistance compared to the 100 year return period environmental loading, is achieved in the structure. This type of design is usually performed using linear methods of structural analysis. In this case the structure practically has a high reserve capacity which is disregarded in the design phase but may be considered in special cases. One of these important cases is when an existing structure is assessed and evaluated after elapse of its structural life. In this case using the platforms reserve capacity, through a non-linear analysis such as push-over, would be logical... 

The use of neural networks for the optimization of amine mixtures formulations in gas sweetening is presented. This is an abstract of a paper presented at the AIChE Spring National Meeting (Orlando, FL 4/24-26/2006)  

To locate accurately the occurrence of a partial discharge in a power transformer winding, a wide frequency band model of the winding is required. In this paper a wide frequency band Multi Conductor Transmission Line model (MTL) is employed to simulate the propagation of PD signal in transformer windings. The MTL model is briefly reviewed and the related equations of the model are reformulated to easily simulate occurrence of a PD signal along the winding. Software is developed in Matlab to calculate the windings resonance frequencies and the magnitudes of over-voltages occurring between different disks along the winding. Then propagation of PD signal in a power transformer (900MVA, 525kV),... 

In the present work we obtained a series of NIR luminescent platinum(II) complexes with a pincer N^N^C ligand based on the conjugated {benzoimidazo[1,2-a]pyrazine} system with the [Pt(N^N^C)L]n+ structural motif (L = phosphine, alkynyl or pyridine-type ligands). We have also synthesized two complexes with bidentate phosphines that demonstrate different types of coordination: 1) as chelating ligand (in case of 1,2-bis(diphenylphosphino)benzene), that led to de-coordination of pyridine ring of N^N^C ligand and formation of a [Pt(N^C)dppb]+ complex; 2) as a bridging ligand (in case of bis(diphenylphosphino)methane) between two {Pt(N^N^C)} fragments in a dimeric complex of type... 

The combined action of ultraviolet irradiation and microwave heating onto acetonitrile solution of [Re((Formula presented.))(CO)3(NCMe)]OTf ((Formula presented.) =phenantroline and neocuproine) afforded cis,trans-Re((Formula presented.))(CO)2(NCMe)2]+ acetonitrile derivatives. Substitution of relatively labile NCMe with a series of aromatic N-donor ligands (pyridine, pyrazine, 4,4’-bipyridine, N-methyl-4,4’-bipyridine) gave a novel family of the diimine cis,trans-[Re((Formula presented.))(CO)2(L)2]+ complexes. Photophysical studies of the obtained compounds in solution revealed unusually high absorption across the visible region and NIR phosphorescence with emission band maxima ranging from... 

A Deza graph with parameters (n, k, b, a) is a k-regular graph with n vertices such that any two of its vertices have b or a common neighbours, where b ≥ a. In this paper we investigate spectra of Deza graphs. In particular, using the eigenvalues of a Deza graph we determine the eigenvalues of its children. Divisible design graphs are significant cases of Deza graphs. Sufficient conditions for Deza graphs to be divisible design graphs are given, a few families of divisible design graphs are presented and their properties are studied. Our special attention goes to the invertibility of the adjacency matrices of Deza graphs. © 2020, © 2020 Informa UK Limited, trading as Taylor & Francis Group  

A Deza graph with parameters (Formula presented.) is a k-regular graph with n vertices such that any two of its vertices have b or a common neighbours, where (Formula presented.). In this paper we investigate spectra of Deza graphs. In particular, using the eigenvalues of a Deza graph we determine the eigenvalues of its children. Divisible design graphs are significant cases of Deza graphs. Sufficient conditions for Deza graphs to be divisible design graphs are given, a few families of divisible design graphs are presented and their properties are studied. Our special attention goes to the invertibility of the adjacency matrices of Deza graphs. © 2020 Informa UK Limited, trading as Taylor &... 

The influence of the addition of the nonionic surfactants C12DMPO, C14DMPO, C10OH, and C10EO5 at concentrations between 10-5 and 10-1 mmol/L to solutions of β-casein (BCS) and β-lactoglobulin (BLG) at a fixed concentration of 10-5 mmol/L on the dilational surface rheology is studied. A maximum in the viscoelasticity modulus |E| occurs at very low surfactant concentrations (10-4 to 10-3 mmol/L) for mixtures of BCS with C12DMPO and C14DMPO and for mixtures of BLG with C10EO5, while for mixture of BCS with C10EO5 the value of |E| only slightly increased. The |E| values... 

The aim of this work was to study the treatment of strong beet sugar wastewater by an upflow anaerobic fixed bed (UAFB) at pilot plant scale. Three fixed bed bioreactors (each 60 L) were filled with standard industrial packing, inoculated with anaerobic culture (chicken manure, cow manure, anaerobic sludge digested from domestic wastewater) and operated at 32-34 °C with 20 h hydraulic retention time (HRT) and influent COD ranging between 2000-8000 mg/L. Under these conditions the maximum efficiency of organic content reduction in the reactor ranged from 75% to 93%. The reactor filled with standard pall rings made of polypropylene with an effective surface area of 206 m2/m3 performed best in... 

Let two coordinate systems, in possession of Alice and Bob, be related to each other by an unknown rotation R∈ SO (3). Alice is to send identical states | ψ⟩ to Bob who will make measurements on the received state and will determine the rotation R. The task of Bob is to estimate these parameters of the rotation R by the best possible measurements. Based on the quantum Fisher information, we show that Greenberger–Horne–Zeilinger (GHZ) states are near optimal states for this task. We show concrete measurements which will allow Bob to determine the rotation R. This shows that GHZ states, as superposition of macroscopically distinct states, are useful in yet another context in quantum... 

A Deza graph G with parameters (n,k,b,a) is a k-regular graph with n vertices such that any two distinct vertices have b or a common neighbours. The children GA and GB of a Deza graph G are defined on the vertex set of G such that every two distinct vertices are adjacent in GA or GB if and only if they have a or b common neighbours, respectively. A strongly Deza graph is a Deza graph with strongly regular children. In this paper we give a spectral characterisation of strongly Deza graphs, show relationships between eigenvalues, and study strongly Deza graphs which are distance-regular. © 2021 Elsevier B.V