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Debismuthizing of Lead with Alkaline and alkaline Earth Elements
, M.Sc. Thesis Sharif University of Technology ; Yoozbashizadeh, Hossein (Supervisor) ; kaflou, Ali (Supervisor)
Abstract
Lead produced by pyrometallurgy method has a number of impurities. Most of these eimpurities can easily be removed, but this property does not apply in the case of bismuth. Since chemical properties of bismuth are close to the lead, refining of bismuth below 250 ppm is difficult and expensive. Because of problems related to electrochemical discussion of the batteries, bismuth it is possible to reduce below than 20 ppm. Jollivet and Dittmer process is capable of reducing bismuth below 20 ppm. As the main goal of this project is to reduce bismuth to small amounts, Jollivet process was used. Potassium needed for Jollivet process, produced by electrolysis of Potassium chloride salt....
Preoxidation Study of Fe-Ni-Co (KOVAR) Alloy on Glass to Metal Sealing Performance
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor) ; Kaflou, Ali (Supervisor)
Abstract
The Fe-Ni-Co alloy to borosilicate glass seals have been used for many years as hermetic and electrically insulating seals. It is not only excellent in thermal expansion matching but also in good wettability and bond strength too. Oxidation of Kovar was performed in Water vapor, Saturated Nitrogen and N2-H2-H2O atmosphere in tube furnace. Oxide layer composition and thickness changed by varying in oxidation temperature and time. XRD analysis showed different Iron oxides in oxide layer, FeO, Fe3O4 and Fe2O3. However in the third atmosphere no Hematite observed. Increasing oxidation temperature and time result in increasing sample weight gains and roughness. Oxide layer microstructure also was...
Hydrogen desorption properties of MgH 2–TiCr 1.2 Fe 0.6 nanocomposite prepared by high-energy mechanical alloying [electronic resource]
, Article Journal of Power Sources ; 2011, Vol. 196, No.10, P.4604-4608 ; Kaflou, A ; Simchi, A. (Abdolreza) ; Sharif University of Technology
Abstract
In the present work, high-energy mechanical alloying (MA) was employed to synthesize a nanostructured magnesium-based composite for hydrogen storage. The preparation of the composite material with composition of MgH2–5at% (TiCr1.2Fe0.6) was performed by co-milling of commercial available MgH2 powder with the body-centered cubic (bcc) alloy either in the form of Ti–Cr–Fe powder mixture with the proper mass fraction (sample A) or prealloyed TiCr1.2Fe0.6 powder (sample B). The prealloyed powder with an average crystallite size of 14nm and particle size of 384nm was prepared by the mechanical alloying process. It is shown that the addition of the Ti-based bcc alloy to magnesium hydride yields a...
Hydrogen desorption properties of MgH2-5at% TiCr1.2Fe0.6 nanocomposite synthesized by high-energy mechanical alloying
, Article World Powder Metallurgy Congress and Exhibition, World PM 2010, Florence, 10 October 2010 through 14 October 2010 ; Volume 1 , 2010 ; 9781899072194 (ISBN) ; Simchi, A ; Kaflou, A ; Sharif University of Technology
European Powder Metallurgy Association (EPMA)
2010
Abstract
We have synthesized nanocrystalline MgH2-5at% TiCr1.2Fe0.6 nanocomposite powder by high-energy mechanical alloying for onboard hydrogen storage application. Magnesium hydride and the elemental Ti, Cr, and Ni powders were milled in a SPEX 800 mill under a high purity argon atmosphere. The dehydrogenation properties of the nanocomposite were studied by simultaneous thermal analyzer. The crystallite size of the nanocomposite was determined by XRD method. It is shown that nanometric grain structure, ultrafine particle size, and the catalytic effect of the transition metals possess a relatively low desorption temperature (262 °C) with 5.5wt % hydrogen release for the nanocomposite powder. The...
Desorption properties of nanostructured MgH2 synthesized by high-energy mechanical milling
, Article European International Powder Metallurgy Congress and Exhibition, Euro PM 2008, Mannheim, 29 September 2008 through 1 October 2008 ; Volume 2 , 2008 , Pages 351-356 ; 9781899072033 (ISBN) ; Simchi, A ; Kaflou, A ; Sharif University of Technology
European Powder Metallurgy Association (EPMA)
2008
Abstract
The hydrogen desorption properties of nanocrystalline magnesium hydride processed by high-energy mechanical milling was investigated. MgH2 powder was milled for various times (up to 16 h) under a high purity argon atmosphere and the effect of milling on the particle size and morphology, grain refinement, lattice strain, and desorption temperature was studied. It was shown that accumulated lattice strain combined with nanometric grain structure significantly decrease the desorption temperature. The effect of powder particle size was found to be of less importance. The lowest desorption temperature was obtained after 4 h high-energy milling. Nanostructured magnesium hydride with grain size of...
Structural characteristics and desorption properties of nanostructured MgH2 synthesised by high energy mechanical milling [electronic resource]
, Article Journal of Powder Metallurgy ; September 2011, Volume 54, Issue 4 , P.480-483 ; Kaflou, A ; Simchi, A. (Abdolreza) ; Sharif University of Technology
Abstract
The effect of particle size, lattice strain and crystallite size on the hydrogen desorption properties of nanocrystalline magnesium hydride powder was investigated. Commercial MgH2 powder was milled in a Spex 8000M up to 16 h and its structural evolution and desorption characteristics at different time intervals were examined using various analytical techniques. At the early stage of milling, the formation of metastable γ-MgH2 phase was noticed. While the crystallite size gradually decreased to 12 nm with increasing the milling time, the accumulated lattice strain gained a maximum value of 0·9% after 4 h milling. The highest drop in the desorption temperature (∼100°C) was attained at the...
Synthesis of a nanostructured MgH2–Ti alloy composite for hydrogen storage via combined vacuum arc remelting and mechanical alloying [electronic resource]
, Article Journal of Materials Letters ; 15 April 2011, Volume 65, Issue 7, Pages 1120–1122 ; Kaflou, A ; Simchi, A. (Abdolreza) ; Sharif University of Technology
Abstract
To improve the hydrogen kinetics of magnesium hydride, TiCr1.2Fe0.6 alloy was prepared by vacuum arc remelting (VAR) and the alloy was co-milled with MgH2 to process nanostructured MgH2–5 at.% TiCr1.2Fe0.6 powder. The hydrogen desorption properties of the composite powder were studied and compared with pure magnesium hydride. X-ray diffraction (XRD) analysis showed that the composite powder prepared by VAR/mechanical alloying (MA) procedure consisted of β-MgH2, γ-MgH2, bcc Ti–Cr–Fe alloy, and small amount of MgO. The average size of particles and their grain structure after 4 h MA were determined by a laser particle size analyzer and XRD method and found to be 194 nm and 11 nm, respectively....
Technical English for mechanical engineers
, Book ; Meghdari,Ali
Sharif University Press
2014
Abstract
Local educational institutions produce in-house English for Specific Purpose (ESP) materials according to the curriculum policies designated and developed by the Ministry of Higher Education In Iran. To this end, this book aims to be used in the Iranian setting at the tertiary level for undergraduate students majoring in Mechanical Engineering. Moreover, the style of English usage in this ESP textbook is American.
Regarding the content of the textbook, it has both thematic organizations in which the topics are relevant and includes sufficient treatment of the target language areas necessary for the students. The principle organizing approach of this textbook is theme-based. In addition,...
Regarding the content of the textbook, it has both thematic organizations in which the topics are relevant and includes sufficient treatment of the target language areas necessary for the students. The principle organizing approach of this textbook is theme-based. In addition,...
Feedback control of the neuro-musculoskeletal system in a forward dynamics simulation of stair locomotion [electronic resource]
, Article Proc. of IMechE Part H: Journal of Engineering in Medicine ; 2009, Vol. 223, No. 6, pp. 663-675 Journal of NeuroEngineering and Rehabilitation ; Volume 11, Issue 1, 30 April 2014, Article number 78 ; Meghdari, Ali ; Vossough, Gholam Reza ; Sharif University of Technology
Abstract
The aim of this study is to employ feedback control loops to provide a stable forward dynamics simulation of human movement under repeated position constraint conditions in the environment, particularly during stair climbing. A ten-degrees-of-freedom skeletal model containing 18 Hill-type musculotendon actuators per leg was employed to simulate the model in the sagittal plane. The postural tracking and obstacle avoidance were provided by the proportional—integral—derivative controller according to the modulation of the time rate change of the joint kinematics. The stability of the model was maintained by controlling the velocity of the body's centre of mass according to the desired centre of...
Design and Construction of a Soft Actuated Exoskeleton for Hand Rehabilitation of Stroke Patients
, M.Sc. Thesis Sharif University of Technology ; Ghafari, Ali (Supervisor) ; Meghdari, Ali (Supervisor)
Abstract
The main goal of this thesis is the design and development of a rehabilitation device for helping patients “to improve blood circulation” & retain and recover their abilities if possible that were lost during the stroke or a accident like that (my research in karaj/iran shows that it is possible by just movement of the specific body part). The focus is on hand in this thesis because Injuries to the hand are common and can be very debilitating since our hands are our primary means for interacting with our world. For rehabilitation in case of human hand there are several practices that should be done for patients either in home or in a rehabilitation center, time and money that is supposed to...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Earthquake Branch
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor)
Abstract
In the past few decades, shaking tables are widely used to evaluate system response of structures under seismic excitations. These devices are used without any fundamental research performed on a shaking table system as an entity model. In most of these studies for simplicity, it is assumed that there exist no considerable vibration and displacement around the shaking tables, and no attention is paid to the peripheral substances such as soil settled under the foundation.
In this thesis, result of ambient vibration test on shaking table system (solid deck, concrete foundation and soil layer) has been presented. Precise sensors known as low frequency and high accuracy accelerometers have...
In this thesis, result of ambient vibration test on shaking table system (solid deck, concrete foundation and soil layer) has been presented. Precise sensors known as low frequency and high accuracy accelerometers have...
Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions [electronic resource]
, Article Journal of Chemical Research ; Volume 2002, Number 8, 1 August 2002, pp. 378-380(3) ; Bagheri Marandi, Gholam
Abstract
Free Content Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions
Selective preparation of fluorescent 1,8-naphthalimides using acidic alumina under microwave irradiation [electronic resource]
, Article Journal of Chemical Research ; 01/2001; 2001(11):485-487 ; Bagheri Marandi, Gholam
Abstract
7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one compounds were prepared in a selective manner by reaction between o-phenylenediamines and appropriate 1,8-naphthalenedicarboxylic anhydrides using acidic alumina under microwave irradiation
Comparison between Performance of Stone Columns and RAPs from the Bearing Capacity and Settlement Reduction Viewpoints
, M.Sc. Thesis Sharif University of Technology ; Pak, Ali (Supervisor)
Abstract
Out of several ground improvement techniques available, stone columns have been widely used. This technique has been successfully applied to increase the bearing capacity and to reduce the settlement for foundation of structures like liquid storage tanks, earthen embankments, raft foundations, etc., where a relatively large settlement is permissible. This technique has, generally, been proven successful in increasing the stiffness of weak soils, upgrading their safe bearing capacity, and reducing their total and differential settlements, as well as speeding up their consolidation process. The beneficial effects of stone column installation in weak deposits is manifested in the form of...
Performance of Partially Filled Mini-Channels with Porous Media
, M.Sc. Thesis Sharif University of Technology ; Nouri, Ali (Supervisor) ; Moosavi, Ali (Co-Advisor)
Abstract
Laminar forced convection flow through a channel partially filled with a porous material was numerically studied in this thesis. The Navier-Stokes and Brinkman-Forchheimer equations were used to model the fluid flow in the free and porous regions, respectively. Coupling of the pressure and velocity fields was resolved using the SIMPLEC algorithm. The local thermal equilibrium was adopted in the energy equation. The effects of the thermal conductivity ratio, Darcy number, porosity, Reynolds number and height of the porous insert on velocity and temperature field were investigated. The results show that the flow behavior and its associated heat transfer are susceptible to the variation of the...
Improvement of Stability of Haptic Force Interaction with Virtual Environments Using a Haptic Interface with a Separate Tracker
, M.Sc. Thesis Sharif University of Technology ; Meghdari, Ali (Supervisor) ; Nahvi, Ali (Supervisor)
Abstract
In the present study, a new version of haptic devices is presented in which user’s hand is in contact with the device just while collision with virtual surface. In this system, the position of user’s finger can be traced by using a camera and the haptic device follows user’s finger at the distance of about two centimeters. While the haptic device approaches to the virtual surface, gradually reduces its speed and stops about two centimeters distant of virtual plane. Then user’s hand collides with the haptic device which is static. Greater fidelity, transparency, more stability and also no need to large actuators are of the advantages of this system. In this project, first we present a new...
Simulation of the Biomolecule Imaging and Manipulation Via AFM by Molecular Dynamics Method
, M.Sc. Thesis Sharif University of Technology ; Meghdari, Ali (Supervisor) ; Moosavi, Ali (Supervisor)
Abstract
In this thesis we try to find optimized parameters for imaging and manipulation of a biosample with AFM. For this we have prepared a numerous Molecular Dynamics simulation and find some reliable result. So, first we have focused on imaging process in Non contact mode (the less harmful mode). Then we headed into the manipulation process. The main problem about manipulating a biosample is the environment. In imaging section, the process of imaging a biomolecule by AFM is modeled using molecular dynamics simulations. Since the large normal force exerted by the tip on the biosample in contact and tapping modes may damage the sample structure and produce irreversible deformation, the non-contact...
Characterzing Variation of Small Strain Shear Modulus of Unsaturated Sand During Hydraulic Hysteresis with Bender Elements
, M.Sc. Thesis Sharif University of Technology ; Pak, Ali (Supervisor) ; Khosravi, Ali (Supervisor)
Abstract
Results of previous studies on silt and clay indicated that variations in the small strain shear modulus, Gmax, during drying had a non-linear increasing trend with matric suction with greater values upon wetting. However, due to different material properties and inter-particle forces, different behaviour in Gmax is expected for sand. Although considerable research has been devoted in recent years to characterize the behaviour of Gmax of sand during drying, rather less attention has been paid to the effect of hydraulic hysteresis on Gmax and its variations during wetting. In the study presented herein, an effort was made to characterize the variation of Gmax for specimens of sand during...
Sequential Competitive Facility Location In Continuous Geometric Space
, M.Sc. Thesis Sharif University of Technology ; Abam, Mohammad Ali (Supervisor)
Abstract
Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...