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kamyar-khaledi--niloufar
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Synthesis and Characterization of Cyclometalated Platinum Complexes Containing 2-Vinylpyridine Ligand
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
The cyclometalated platinum(II) complex [Pt(Me)(bhq)(2-vpy)], 2, in which bhq = benzo{h}quinolone, 2-vpy = 2-vinylpyridine, has been prepared by reaction of the cyclometalated complex [Pt(Me) bhq)(SMe2)], 1 with one equiv 2-vinylpyridine. The similar complex [Pt(p-tolyl)(ppy)(2-vpy)], 3 in which ppy = 2-phenyl pyridine, has been prepared from reaction of the platinum(II) complex cis-[Pt(p-MeC6H4)2(SMe2)2] with one equiv 2-phenylpyridine and one equiv 2-vinylpyridine. Reaction of 2 with one equiv Br2 in acetone gave the cyclometalated platinum(IV) complex [Pt(bhq)Me(Br)(NC5H4CHCH2Br)], 4. The structure of the complexes 1-3 were determined using NMR Spectroscopy. The crystal structure of 3...
Three Dimensional Multi-Objective Terrain Following/Avoidance Optimization Using Heuristic Approach
, M.Sc. Thesis Sharif University of Technology ; Pourtakdoust, Hossein (Supervisor)
Abstract
Thus far, there has been a great attraction toward the optimal flight path planning problem. Terrain following/avoidance (TF/TA) flight is one of the most significant applications of this issue. To prevent from detection by the radars, fighter aircrafts, cruise missiles and helicopters often have to fly as close as possible to the surface during the operations. Such types of maneuvers are much more demanding and effortful than to be designed and implemented by human. The optimal TF/TA guidance system design comprises three phases: optimal path planning, closed-loop control system design for trajectory tracking and sensor blending to match the onboard and measured terrain data. So far, the...
Fuzzy mobility analyzer: A framework for evaluating mobility models in mobile ad-hoc networks
, Article IEEE Wireless Communications and Networking Conference, WCNC, 18 April 2010 through 21 April 2010 ; April , 2010 ; 15253511 (ISSN) ; 9781424463985 (ISBN) ; Rabiee, H. R ; Khaledi, M. H ; Sharif University of Technology
2010
Abstract
Mobility is one of the most challenging issues in mobile ad-hoc networks and has a significant impact on performance of network protocols. Different kinds of mobility models have been proposed to represent the movement pattern of mobile nodes in mobile ad-hoc networks. These models attempt to capture various mobility characteristics existing in real movement of mobile nodes. In this paper, a new framework called Fuzzy Mobility Analyzer has been proposed to evaluate mobility models. At first, our framework categorizes mobility models based on their mobility characteristics into five classes; subsequently it uses mobility metrics to capture the mobility and graph connectivity characteristics...
Mobility aware distributed topology control in mobile ad-hoc networks using mobility pattern matching
, Article WiMob 2009 - 5th IEEE International Conference on Wireless and Mobile Computing Networking and Communication, 12 October 2009 through 14 October 2009, Marrakech ; 2009 , Pages 453-458 ; 9780769538419 (ISBN) ; Mousavi, S. M ; Rabiee, H. R ; Movaghar, A ; Khaledi, MJ ; Ardakanian, O ; Sharif University of Technology
2009
Abstract
Topology control algorithms in mobile ad-hoc networks aim to reduce the power consumption while keeping the topology connected. These algorithms can preserve network resources and increase network capacity. However, few efforts have focused on the issue of topology control in presence of node mobility. One of the notable mobility aware topology control protocols is the "Mobility Aware Distributed Topology Control Protocol". The main drawback of this protocol is on its mobility prediction method. This prediction method assumes linear movements and is unable to cope with sudden changes in the mobile node movements. In this paper, we propose a pattern matching based mobility prediction method...
Comparative investigation of advanced combined cycles
, Article 2006 ASME 51st Turbo Expo, Barcelona, 6 May 2006 through 11 May 2006 ; Volume 4 , 2006 , Pages 475-485 ; 0791842398 (ISBN); 9780791842393 (ISBN) ; Sarabchi, K ; Sharif University of Technology
2006
Abstract
Combined cycles, at present, have a prominent role in the power generation and advanced combined cycles efficiencies have now reached to 60 percent. Examination of thermodynamic behavior of these cycles is still carried out to determine optimum configuration and optimum design conditions for any cycle arrangement. Actually the performance parameters of these cycles are under the influence of various parameters and therefore the recognition of the optimum conditions is quiet complicated. In this research an extensive thermodynamic model was developed for analyzing major parameters variations on gas turbine performance and different configurations of advanced steam cycles: dual and triple...
Mobility analyzer: A framework for analysis and recognition of mobility traces in mobile Ad-Hoc networks
, Article 3rd International Conference on New Technologies, Mobility and Security, 20 December 2009 through 23 December 2009 ; 2009 ; 9781424462735 (ISBN) ; Hemmatyar, A. M. A ; Rabiee, H. R ; Mousavi, S. M ; Khaledi, M. H ; Sharif University of Technology
2009
Abstract
Mobility is one of the most challenging issues in mobile Ad-Hoc networks which has a significant impact on performance of network protocols. To cope with this issue, the protocol designers should be able to analyze the movement of mobile nodes in a particular wireless network. In this paper, a new framework called Mobility Analyzer has been introduced for analysis and recognition of mobility traces. At first, the Mobility Analyzer acquires some mobility traces collected by GPS or generated with mobility simulators; then it calculates some mobility metrics which represent the movement behavior of the mobile nodes; finally it attempts to classify mobility traces into particular mobility models...
Direct conversion of inorganic complexes to platinum/thin oxide nanoparticles decorated on MOF-derived chromium oxide/nanoporous carbon composite as an efficient electrocatalyst for ethanol oxidation reaction
, Article Journal of Colloid and Interface Science ; Volume 555 , 2019 , Pages 655-666 ; 00219797 (ISSN) ; Rezaee, S ; Shahrokhian, S ; Amini, M. M ; Sharif University of Technology
Academic Press Inc
2019
Abstract
In this work, we present the design and fabrication of a novel nanocomposite based on noble metal and metal oxide nanoparticles dispersed on highly porous carbon obtained via the pyrolysis of an inorganic complex and metal-organic frameworks. This nanocomposite is prepared by a two-step procedure: first, the composite support of nanoporous carbon (NPC) is obtained by the direct carbonization of the Cr-benzene dicarboxylic ligand (BDC) MOF in an Argon atmosphere at 500 °C (Cr2O3-NPC). A mixture containing Cr2O3-NPC and [PtCl(SnCl3)(SMe2)2] is then prepared, and underflow of Argon is heated to 380 °C. Finally, Pt-SnO2 nanoparticles are loaded on the Cr2O3-NPC support, and the obtained...
Dynamic production planning model: A dynamic programming approach
, Article International Journal of Advanced Manufacturing Technology ; Volume 67, Issue 5-8 , 2013 , Pages 1675-1681 ; 02683768 (ISSN) ; Reisi Nafchi, M ; Sharif University of Technology
2013
Abstract
Production planning is one of the most important issues in manufacturing. The nature of this problem is complex and therefore researchers have studied it under several and different assumptions. In this paper, applied production planning problem is studied in a general manner and it is assumed that there exists an optimal control problem that its production planning strategy is a digital controller and must be optimized. Since this is a random problem because of stochastic values of sales in future, it is modeled as a stochastic dynamic programming and then it is transformed to a linear programming model using successive approximations. Then, it is proved that these two models are...
Optimal coupled spacecraft rendezvous and docking using multi-objective optimization
, Article ASME 2010 10th Biennial Conference on Engineering Systems Design and Analysis, ESDA2010, 12 July 2010 through 14 July 2010 ; Volume 5 , July , 2010 , Pages 299-309 ; 9780791849194 (ISBN) ; Pourtakdoust, S. H ; Kamyar, R ; ASME Turkey Section ; Sharif University of Technology
2010
Abstract
Spacecraft rendezvous and docking are two processes in which a chaser pursues and meets a leader spacecraft in order to perform several mission based tasks. Although in some preliminary design analysis, these two operations may be pursued independently there could be circumstances in which the spacecraft trajectory and attitudes are coupled and interdependent. The present study is based on the presumption that the often independent translational and rotational motions of the spacecraft are coupled as a result of thrust misalignment. So the thrusters not only contribute to the rendezvous translational motion, but also affect the docking reorientation maneuver through their disturbing effects....
Mobility Prediction in Mobile Ad-Hoc Networks
, M.Sc. Thesis Sharif University of Technology ; Movaghar, Ali (Supervisor)
Abstract
Mobile ad hoc networks (MANETs) are the dynamically reconfigurable wireless networks in which mobile nodes communicate with each other without the need for any fixed infrastructure. In these networks mobile nodes are free to move, therefore, network topology changes rapidly. These changes can lead to significant performance degradations in network protocols. To cope with this, a desired solution is to predict movements of mobile nodes. In this way, we can be prepared for changes. This thesis proposes two mobility prediction methods. In both methods, each node uses the information extracted from its own history of movements to predict its future location. Results obtained by applying two...
Geomechanical Model for Well Path Optimization Based on Inclination, Azimuth and ROP
, M.Sc. Thesis Sharif University of Technology ; Shad, Saeed (Supervisor)
Abstract
The wellbore instability increases the cost of drilling operations due to problems such as pipe sticking and lost circulation, so it is important to find the optimal well path. In this research, building a one-dimensional geomechanical model is investigated, and then the wellbore stability during drilling in different layers is evaluated. The geomechanical model is constructed using available data (well log data, mud logging unit data, and drilling reports) in a study reservoir and the optimal well path is determined by the appropriate inclination and azimuth using the geomechanical properties of the field and the stress regime, taking into account the wellbore stability and shear failure...
Effect of inlet air cooling by absorption chiller on gas turbine and combined cycle performance
, Article 2005 ASME International Mechanical Engineering Congress and Exposition, IMECE, Orlando, FL, 5 November 2005 through 11 November 2005 ; Volume 45 , 2005 , Pages 507-515 ; 10716947 (ISSN) ; Zomorodian, R ; Ghofrani, M. B ; Sharif University of Technology
2005
Abstract
Gas turbine performances are directly related to site conditions. The use of gas turbines in combined gas-steam power plants, also applied to cogeneration, increases such dependence. In recent years, inlet air cooling systems have been introduced to control air temperature at compressor inlet, resulting in an increase in plant power and efficiency. In this paper, the dependence of outside conditions for a simple gas turbine and a combined cycle plant is studied, using absorption chiller as inlet air cooling system. We used, as case study, a simple plant equipped with one frame E gas turbine and a combined cycle with a two pressure level heat recovery steam generator (HRSG). It was found that...
Combining multivariate image analysis with high-performance thin-layer chromatography for development of a reliable tool for saffron authentication and adulteration detection
, Article Journal of Chromatography A ; Volume 1628 , 2020 ; Rashidi, M ; Kamyar, M ; Amirahmadi, M ; Daraei, B ; Parastar, H ; Sharif University of Technology
Elsevier B.V
2020
Abstract
In this work, high-performance thin-layer chromatography (HPTLC) coupled with multivariate image analysis (MIA) is proposed as a fast and reliable tool for authentication and adulteration detection of Iranian saffron samples based on their HPTLC fingerprints. At first, the secondary metabolites of saffron were extracted using ultrasonic-assisted solvent extraction (UASE) which was optimized using central composite design (CCD). Next, the RGB coordinates of HPTLC images were used for estimation of saffron origin based on principal component analysis (PCA). The PCA scores plot showed that saffron samples were clustered into two clear-cut groups which was 92% matched with the geographical...
Design and Implementation of a Distributed Planning System Prototype
, M.Sc. Thesis Sharif University of Technology ; Ghassem-Sani, Gholamreza (Supervisor)
Abstract
Planning is one of the most important branches of artificial intelligence. The goal of planning is automated production of sequence of actions (plans) for some specified tasks. However the computation done by planners is very time consuming and complicated. Distributing computation is one solution to overcome such difficulties. Distribution divides the load of process between a number of agents and increases robustness. The purpose of this project is to reduce the computational overhead of planning by the means of distributing the planning process between a numbers of planners. In the proposed method, we first divide a classical planning problem to two separate subproblems by decomposition...
Flow and heat transfer analysis of turbine blade cooling passages using network method
, Article ASME 2012 Gas Turbine India Conference, GTINDIA 2012 ; 2012 , Pages 523-531 ; 9780791845165 (ISBN) ; Izadi, A ; Fathi, A ; Khaledi, H ; Sharif University of Technology
2012
Abstract
Modern turbine blades are cooled by air flowing through internal cooling passages. Three-Dimensional numerical simulation of these blade cooling passages is too time-consuming because of their complex geometries. These geometrical complexities exist as a result of using various kinds of cooling technologies such as rib turbulators (inline, staggered, or inclined ribs), pin fin, 90 and 180 degree turns (both sharp and gradual turns, with and without turbulators), finned passage, by-pass flow and tip cap impingement. One possible solution to simulate such sophisticated passages is to use the one-dimensional network method, which is presented in the current work. Turbine blade cooling channels...
Gas turbine oxidation life assessment and monitoring
, Article Oxidation of Metals ; Volume 90, Issue 5-6 , 2018 , Pages 691-711 ; 0030770X (ISSN) ; Alizadeh, M ; Akheratdoost, H ; Khaledi, H ; Sharif University of Technology
Springer New York LLC
2018
Abstract
Gas turbine hot-section parts can be very expensive components with a finite lifetime. Their durability is strongly dependent on the operating service conditions which control the maintenance intervals and associated expenses. Blade damage is the most frequent reason for failures in gas turbine engines and also oxidation is one of the most critical degradation mechanisms when the power system operates in partially loading condition. This paper describes the methodology of oxidation life assessment for uncoated and coated blades with various metallic coatings in the first stage of a typical gas turbine engine. The resultant weight-change curves were validated by comparing them with the...
Analysis of Bearing Capacity and Settlement of Piled-Raft Foundation on Clayey Soils
, M.Sc. Thesis Sharif University of Technology ; Ahmadi, Mohammad Mahdi (Supervisor)
Abstract
Investigating the behavior of piled-raft foundations is a three-dimensional problem. The shape and location of the piles in the raft as well as the complex interaction of the soil-structure in these foundations should be analyzed in a three-dimensional fashion to indicate the real behavior of this type of foundations. The soil must also be analyzed in a nonlinear state to achieve the correct bearing capacity of these foundations. In this research, a nonlinear 3D analysis was performed using FLAC3D to investigate the behavior of piled-raft foundations, and the effect of various factors such as the length, arrangement and number of the piles, the loading level and the thickness of the raft, on...
Mobility Pattern Recognition in Mobile Ad-Hoc Networks
, M.Sc. Thesis Sharif University of Technology ; Afshin Hemmatyar, Ali Mohammad (Supervisor)
Abstract
Mobility is one of the most challenging issues in mobile Ad-Hoc networks which has a significant impact on performance of network protocols. To cope with this issue, the protocol designers should be able to analyze the movement of mobile nodes in a particular wireless network. In this thesis, a new framework called Mobility Analyzer has been proposed. At first, Mobility Analyzer categorizes mobility models based on their mobility characteristics; subsequently, it uses mobility metrics for evaluating mobility traces which are collected by GPS or generated by mobility simulators. Finally, Mobility Analyzer recognizes the mobility model of mobility traces based on mobility metrics and measures...
Comparative evaluation of advanced gas turbine cycles with modified blade cooling models [electronic resource]
, Article Proceedings of the ASME Turbo Expo ; Volume 4, Pages 537-546 , 2006 ; Sharif University of Technology
2006
Abstract
Advanced gas turbine cycles use advanced blade cooling technologies to reach high turbine inlet temperature. Accurate modeling and optimization of these cycles depend on blade cooling model. In this study, different models have been used to simulate gas turbine performance. The first model is the continuous model and the second is stage-by-stage model with alternative methods for calculating coolant, stagnation pressure loss and SPR. Variation of specific heat and enthalpy with temperature are included in both models. The composition of gas stream in turbine is changed step by step due to air cooling. These models are validated by two case study gas turbine results, which show good agreement...
A one-DOF passive glove for thumb rehabilitation
, Article Scientia Iranica ; Volume 29, Issue 4 B , 2022 , Pages 1806-1816 ; 10263098 (ISSN) ; Zohoor, H ; Haghighi, S. E ; Soleimanimehr, H ; Sharif University of Technology
Sharif University of Technology
2022
Abstract
Wearable robots are becoming increasingly practical to use to rehabilitate wounded parts of the body as the number of injuries to the hand, particularly fingers, has increased. Wearable robots are designed to help people save time and money. This exoskeleton is intended to rehabilitate the thumb such that it may do an opposing movement with one Degree Of Freedom (DOF) and a cable system. Two drums, one on the thumb and the other on the tip of the assistive finger place the cables, which feature a cable adjusting screw that can be adjusted for fingers of various lengths. To choose the assistive finger from 4 intact fingers, the two perspectives of the cable length changes and finger forces...