Sharif Digital Repository

A unique combination of a supported cobalt complex and the first example of supported NHPI in acetic acid gives a surprisingly stable heterogeneous catalytic system for the selective aerobic oxidation of methylaromatics to benzaldehydes at atmospheric pressure. © The Royal Society of Chemistry 2005  

A linear time-invariant (LTI) robust servomechanism controller for islanded (autonomous) operation of a distributed generation (DG) unit and its local load is proposed. The DG unit utilizes a voltage-sourced converter (VSC) as the interface medium. The controller design is obtained by introducing a new optimal controller design procedure, in conjunction with a proposed non-conservative robustness constraint. The proposed controller utilizes 1) an internal oscillator for frequency control and 2) a robust servomechanism controller (RSC) to regulate the island voltage. Despite uncertainty of the load parameters, the proposed controller guarantees robust stability and pre-specified performance... 

This paper proposes a new decentralized power management and load sharing method for a photovoltaic (PV)-based, hybrid single/three-phase-islanded microgrid consisting of various PV units, battery units, and hybrid PV/battery units. The proposed method is not limited to the systems with separate PV and battery units, and power flow among different phases is performed automatically through three-phase units. The proposed method takes into account the available PV power and battery conditions of the units to share the load among them. To cover all possible conditions of the microgrid, the operation of each unit is divided into five states in single-phase units and seven states in three-phase... 

Both the equation of state-excess Gibbs energy (EoS/GE) model and the cubic plus association (CPA) equation of state (EoS) are compared in this study with respect to their accuracy in the correlation of PVTx for systems such as water/methanol, water/ethanol, water/benzene, water/toluene, water/methane, water/n-butane, water/n-pentane, water/n-hexane, water/heptane, and water/octane, in supercritical conditions within temperature and pressure ranges of (573-698 K) and (7. 0-276. 0 MPa), respectively. In the proposed EoS/GE model, Peng-Robinson (PR) equation of state, linear combination Vidal-Michelsen (LCVM) and Wong-Sandler (WS) mixing rules in conjunction with UNIQUAC activity coefficient... 

ABSTRACT: Experimental study of the performance of a gas centrifuge can be appreciably simplified if instead of isotopic mixtures, a binary mixture of gases with large molecular weight difference is used. The current study undertook this approach by injecting a 53%–47% (w/w) mixture of “Freon12-Freon22” into a gas centrifuge. The two parameters, whose investigation was the objective of the current study were: the feed flow rate (F), and the clearance between tail scoop and the rotor wall (d). The results demonstrated that changing the scoop-wall clearance has the most significant effect on the cut (θ), so that by fixing “d”, “θ” becomes nearly invariant. The head separation factor (α)... 

Public procurement for innovation (PPI) is an assertive demand-side innovation policy. However, research is behind in understanding the know-how of designing and implementing successful PPI, particularly in developing economies. This study's primary goal is to provide a conceptual framework of influential factors in designing and implementing a successful PPI. To this aim, we did a case study on some projects under the PPI initiative, defined for Iran's oil industry. Reviewing the corresponding literature and analyzing the case materials, including interviews, observation, and documents, our findings suggest a conceptual framework that includes four categories of influential factors in the... 

This paper presents a decentralized load sharing and power management method for an islanded microgrid composed of PV units, battery units and hybrid PV/battery units. The proposed method performs all the necessary tasks such as load sharing among the units, battery charging and discharging and PV power curtailment with no need to any communication among the units. The proposed method is validated experimentally  

Adsorption of Cr (VI) from aqueous solution was studied using a continuous fixed bed column which is packed with a new micro-porous composite particle developed in this study. This composite particle is composed of silica porous particle in which acrylamide is polymerized within the pore regions of the silica particles. The composite particle was supposed to maintain the mechanical properties of polyacrylamide as efficient absorbent to serve appropriately in the continuous processes. In order to enhance the adsorption capacity of the composite particle, it was modified with ethylenediamine. Scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy (FT-IR) and... 

Current studies show a growing interest on transformation induced plasticity (TRIP) in austenitic steels. Most researches are based on inducing plasticity via tensile stresses, so it seems interesting to accomplish these researches by compressive stresses. Rolling process is a suitable choice to make compressive stresses. In present work, the effects of a wide range of rolling strains (5%-60%) at 0 and 24 °C on the austenite to martensite transformation were investigated on high-alloy austenitic steel. For this purpose, XRD, hardness test and magnetic measurements were used. Results show that by increasing the amount of rolling strain, transformation of austenite to martensite generally... 

Classical molecular dynamics simulations are used to compute the solvation free energy of two pharmaceutical solids, namely ibuprofen and acetaminophen in carbon dioxide (CO2), over the density range of interest in supercritical processes. In order to examine the influence of the solvent model on the resulting free energies, three popular CO2 models (Zhang, EPM2, and TraPPE) are studied. Relatively large discrepancies for the solvation free energy exist between these CO2 models, suggesting that the former is sensitive to the different balances between dispersive and electrostatic forces used in these models. In particular, for the solvation of the highly polar (dipole moment of ∼5.2 Debye)... 

Continuous adsorption in stirred reactors in the form of carbon in pulp (CIP) and resin in pulp (RIP) is an established process for the extraction of gold and uranium. Under the circumstance of intraparticle diffusion resistance, CIP and RIP have been accurately modeled by the Boyd's series (reversible adsorption) and shrinking core model (irreversible adsorption). The present study, in its first part, introduces an analytical formula that most closely approximates both models. Using such formula, the study addresses a basic algorithm for optimization of single-stage continuous adsorption systems through linking of the major process variables. Furthermore, this study is devoted to developing... 

This paper proposes a new decentralized power management and load sharing method for a photovoltaic based islanded microgrid consisting of various photovoltaic (PV) units, battery units and hybrid PV/battery units. Unlike the previous methods in the literature, there is no need to communication among the units and the proposed method is not limited to the systems with separate PV and battery units or systems with only one hybrid unit. The proposed method takes into account the available PV power and battery conditions of the units to share the load among them. To cover all possible conditions of the microgrid, the operation of each unit is divided into five states and modified active... 

Manufacturing sectors act as the backbone for industrial evolutions and the economic growth of countries. With more than 2000 parts in just one vehicle sourced from thousands of different suppliers worldwide, the automotive industry has become one of the most complex ones, going under ever-present changes since its invention. To maintain their competitiveness in the global market and the era of Industry 4.0, automotive companies need to adopt innovative technologies internally and cooperate with their suppliers through cyber-physical systems. The fourth industrial revolution, Industry 4.0, and its components, such as the Internet of Things (IoT), allow real-time communication and... 

Smartphones can be regarded as resource pools which are capable of communicating with their outside world using both short-range and long-range links. Such communication capabilities provide a unique opportunity for sharing resources, resulting in new possibilities for end users. In this paper, we present a new data update and processing scheme, designed for local networks of mobile devices which are formed with resource sharing in mind  

This paper presents a decentralized adaptive control design for a class of large-scale nonlinear systems with unknown subsystems. When the subsystems are modeled by affine equations, a direct adaptive controller is devised based on the Lyapunov theory, so that the stability of the closed-loop system is guaranteed by introducing a suitably driven adaptive rule. A neuro-based structure is proposed when the subsystems are nonaffine, and the stability analysis is also performed based on the Lyapunov theory. Moreover, the unknown interactions among the subsystems are considered as having a nonlinear function against the simple form considered for the affine case. The proposed controllers are... 

Rapid and selective detection of biomarkers at trace levels is a highly coveted objective in the early diagnosis of cancer. Herein, we disclose the design and synthesis of a polyhedral oligomeric silsesquioxane (POSS) substituted perylene diimide. This compound is fully characterized in solution by multi nuclear NMR, as well as in gas state by ESI-MS. Surprisingly, solid-state characterization revealed an unusual cubic morphology with particle dimensions of 80–160 nm. Fluorescence studies indicate that the bulky POSS units effectively prevent perylene's aggregation caused quenching, yielding quantum yields as high as 92%. Exposing the sensor droplet-cast on quartz to anline and o-toluidine,... 

This paper presents a method for the optimal restoration planning based on Wide Area Measurement System (WAMS). This method uses observability analysis and Power Transfer Distribution Factor (PTDF) concept. The PTDF concept is applied to decrease the overvoltages caused by energizing transmission lines with lightly load. The New England 39 bus power system is used to demonstrate the proposed algorithm and verify the results. The outcomes of the study are evaluated to show the validity and reliability of the presented approach  

In future smart grids, energy storage systems (EESs) are expected to play an indispensable role in balancing continuous load changes arising from customers' life-style as well as varying output of intermittent energy resources. This, however, needs significant investment that should be justified prior to their implementation. This paper presents a model to find the optimal capacity for ESSs in distribution systems. The model aims at maximizing system owner profit by reducing total electricity procurement costs. The model is formulated as a mixed integer non-linear programming problem. Due to the complexity and large size of the problem, a decouplebased method is proposed wherein optimal...