Sharif Digital Repository

Rapid and selective detection of biomarkers at trace levels is a highly coveted objective in the early diagnosis of cancer. Herein, we disclose the design and synthesis of a polyhedral oligomeric silsesquioxane (POSS) substituted perylene diimide. This compound is fully characterized in solution by multi nuclear NMR, as well as in gas state by ESI-MS. Surprisingly, solid-state characterization revealed an unusual cubic morphology with particle dimensions of 80–160 nm. Fluorescence studies indicate that the bulky POSS units effectively prevent perylene's aggregation caused quenching, yielding quantum yields as high as 92%. Exposing the sensor droplet-cast on quartz to anline and o-toluidine,... 

The heterobinuclear cyclometalated PtII-AuI complexes of the type [MePt(bhq)(μ-dppy)AuL]PF6, in which, bhq = benzo{h}quinoline, dppy = 2-diphenylphosphinopyridine, L = PPh3, 5; PPh2Me, 6; PPhMe2, 7; have been prepared by reaction of the mononuclear platinum(II) complex [MePt(bhq)(dppy)], 1, with 1 equiv. [AuL]+. Also, the reaction of complex 1 with 1 equiv AuCl(SMe2) at -60 °C gave the neutral heterobinuclear complex [MePt(bhq)(μ-dppy)AuCl], 8. All of the complexes were characterized using NMR spectroscopy and elemental microanalysis and complexes 5 and 8 were further identified by single crystal X-ray structure determination. Time-dependent density functional theory (TD-DFT) is used to... 

Acidizing of carbonate oil-wet rocks saturated with oil and saline formation water is subjected failure in some cases due to acid-induced damage such as sludge and emulsion formations. This condition may also lead to mineral precipitation, oil film barrier between acid and rock and diversion chemical malfunctions. Therefore, pre-flush process has been proposed as one of the most efficient stage for oil-wells matrix acidizing to reduce these challenges significantly. Besides, the pre-flush stage would result in more clean rock as the reservoir fluids are pushed back from the near wellbore regions, restoring rock wettability to more water wet state, preventing direct acid-oil contact and... 

Trim control mechanisms such as interceptors and trim flaps have been widely used in recent years in highspeed crafts for ride and trim control. In spite of their extensive application, a few studies investigating the impact of interceptors on planing craft performance, have been published. In the present study, the impact of interceptors on planing crafts hydrodynamic quality is investigated through application of an experimental method. Two scaled-down models of high-speed planing mono-hull and catamaran are tested with and without interceptors in calm water at different heights of the interceptors to investigate the effect of interceptors on drag reduction of the models. The first one is... 

The controllable flaps and interceptors in planing crafts not only may reduce the resistance, but also could be designed to make a boat run at or near optimum attitude in various environments, which results in a reduction in both resistance and vertical motion in waves. Planing vessels suffer from porpoising instability and violent vertical motion at high forward speeds. The controllable flaps and interceptors can be used to control and reduce the vertical motion of planing crafts. In the present study, the impact of controlled interceptors on a planing craft seakeeping quality is investigated through application of experimental and theoretical methods. In the experimental part of the study,... 

Optical networks-on-chip are introduced as an alternative for electrical interconnects in many-core systems, due to their low delay and power consumptions, as well as their high bandwidths. Despite these advantages, physical characteristics of the photonic components are highly sensitive to thermal variations, which results in optical data misrouting through the optical networks at the presence of temperature fluctuation. In this paper, we propose a thermally-resilient all-optical communication approach which improves reliability, as well as performance of the optical networks. For this purpose, we take advantages of auxiliary waveguides and a novel wavelength assignment approach to avoid... 

This paper presents mathematical modeling of joint lot sizing and scheduling problem in a job shop environment under a set of realistic working conditions. One main realistic assumption of the current study is dealing with flexible machines able to change their working speeds, known as process compressibility. The production schedules should be subject to limited available time in every planning period. Also, the model assumes that periodical sequences should be determined in a way that they obey from a fixed global sequence. Another complicating aspect of the problem is about consideration of precedence relationships for the needed processes of an item type over the corresponding machines.... 

Anaerobic digestion processes and the conductive electron transfer approach were used to describe the bioenergy production processes in a microbial fuel cell (MFC), respectively. The present model is a far more completed form of conduction-based modeling which is able to predict performance of an MFC fed with complex substrates and inoculated with multi-population culture. One-dimensional spatial distributions of the different microorganisms, as biocatalysts of processes and intermediates produced in the different steps of the anaerobic digestion processes in the biofilm, as well as the dynamic behavior of the anolyte including syntropic interactions among different groups of microorganisms... 

In this study, a new model of microbial fuel cell (MFC) was obtained for the first time. The modeled MFC was made using a combination of two approaches; the conduction-based method and two-step anaerobic digestion. Performance of the MFC was based on calculations for current evolution and polarization curves with different subsequent variables of the biofilm and anolyte. The model was able to make predictions for performance of the MFC for a simple substrate to more complex ones. The model was successfully validated with a variety of substrates (acetate, glucose and dairy wastewater) and the results were compared with previously published measurements. The model polarization results showed... 

The objective of this study was to construct a novel model to be applied in a general manner to simulate microbial electrochemical cells (MXCs); for both microbial fuel cell (MFC) and microbial electrolysis cell (MEC). The liquid bulk was modeled based on the organic matters degradation to acetate via the anaerobic digestion process. Biofilm simulation was established based upon one-dimensional distribution and the dynamical electron transfer was completed by means of the conduction-based mechanism. We, for the first time, introduced biofilm local potential modeling for MEC simulation with general and simplified linear boundary conditions. The MFC-related part of the model was evaluated... 

In the present study, an attempt was made to investigate the potential of some of the major world’s crops, including wheat, corn, rice, barley, sugarcane, sugar beet, potatoes, and oats, to produce biohydrogen. The collectable amount of agricultural residues that could especially be used to produce hydrogen was estimated in Africa, Asia, Central America, Europe, Northern America, Oceania, and South America, and the potential amount of ammonia as the main nitrogen fertilizer was estimated. Double exponential smoothing method was employed to forecast the future crop production and area harvested. It was calculated that about 10.56 (in 2013) and 15.5 (in 2030) Mt of biohydrogen and 59.84 (in... 

In the present study, an attempt was made to investigate the potential of some of the major world’s crops, including wheat, corn, rice, barley, sugarcane, sugar beet, potatoes, and oats, to produce biohydrogen. The collectable amount of agricultural residues that could especially be used to produce hydrogen was estimated in Africa, Asia, Central America, Europe, Northern America, Oceania, and South America, and the potential amount of ammonia as the main nitrogen fertilizer was estimated. Double exponential smoothing method was employed to forecast the future crop production and area harvested. It was calculated that about 10.56 (in 2013) and 15.5 (in 2030) Mt of biohydrogen and 59.84 (in... 

In the present study, an attempt was made to investigate the potential of some of the major world’s crops, including wheat, corn, rice, barley, sugarcane, sugar beet, potatoes, and oats, to produce biohydrogen. The collectable amount of agricultural residues that could especially be used to produce hydrogen was estimated in Africa, Asia, Central America, Europe, Northern America, Oceania, and South America, and the potential amount of ammonia as the main nitrogen fertilizer was estimated. Double exponential smoothing method was employed to forecast the future crop production and area harvested. It was calculated that about 10.56 (in 2013) and 15.5 (in 2030) Mt of biohydrogen and 59.84 (in... 

Abstract- Benefits of PSS application for electromechanical oscillations damping is clarified. A major difficulty of PSS application is its tuning such that its damping characteristics do not fall into overcompensation facing continuously changing power systems. This paper presents an approach for wide area monitoring and control based PSS tuning. The presented approach originated from adaptive tuning based on real time power system state estimation. © 2008 IEEE  

Operation of transmission lines are usually limited by stability limits rather than thermal capacity limits. Thermal limit of transmission lines is a physical limitation of their components and not related with the overall power system characteristics, but stability limits are strictly related with power system characteristics. This paper presents an approach for increasing stability limits using PSS. © 2008 IEEE  

A multistage decoder for the internally convolutionally coded fibre-optic time-hopping code division multiple access system recently introduced is considered. In this system, the decoder consists of several stages. The first stage is implemented using one of the single-user decoders introduced. The following stages are maximum likelihood (ML) decoders each of which use the decisions made by the previous stage. The performance of the proposed decoder is evaluated by a Monte Carlo simulation. Numerical results show that a multistage decoder with only two stages greatly outperforms the single-stage decoder with negligible increase in complexity. The authors also derive the Chernoff bound for... 

In this study, a fixed-bed catalytic membrane reactor was used for the production of ethylene and cyclohexane from ethane and benzene. A two-dimensional non-isothermal mathematical model was used for estimating the performance of the membrane reactor. Furthermore, the effect of inlet temperature (720–1080 K), feed molar ratio (3–10) and the reactor spacetime (1–76 kgCat.s/mol) was studied on the conversion of ethane to ethylene and benzene to cyclohexane. The results of modeling showed that with the increase of inlet temperature the conversion of both (de)-hydrogenation reactions increased and the 95% of ethane conversion was achieved when the molar ratio of benzene/ethane was fixed on 3.... 

This paper presents mathematical modelling of joint lot sizing and scheduling problem in job shop environment under a set of working conditions. The main feature of the problem is to deal with flexible machines able to change their working speeds, known as process compressibility. Furthermore, produced items should be assembled together to make final products. In other words, the products have a multilevel structure, shown with bill of materials. As the problem is proved to be strongly NP-hard, it is solved by a memetic algorithm here. Computational experiences on the data of Mega Motor company are reported. Also, further experiences on random test data confirm the performance of the... 

In this study, the nonlinear seismic analysis of a typical three-dimensional concrete faced rockfill dam is reported. Three components of the Loma Prieta (Gilroy 1 station) earthquake acceleration time history are used as input excitation. The dam under study is considered as if it were located in a prismatic canyon with a trapezoidal cross-section. A nonlinear model for the rockfill material is used, and contact elements with Coulomb friction law are utilized at the slab-rockfill interface. Vertical joints in the face slab are also considered in the finite element model. A substructure method, in which the unbounded soil is modelled by the scaled boundary finite element method (SBFEM), is... 

In this study, the effect of surface modified nano-zirconia (nano-ZrO2) on the corrosion protection of epoxy coating on mild steel was investigated. An organosilane (trimethoxy methyl silane) was used as a surface modifier to improve the dispersability of the inorganic nanoparticles in the organic coating matrix. Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) were used to characterize the sol-gel surface modified nanoparticles. The dispersability of the modified and unmodified nano-zirconia in an epoxy coating was examined by field emission-scanning electron microscopy (FE-SEM). Electrochemical impedance spectroscopy (EIS) and salt spray were employed to...