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kazemian--masoud
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Direct Synthesis of Dimethyl Ether from Carbon Dioxide
, M.Sc. Thesis Sharif University of Technology ; Kazemeini, Mohammad (Supervisor) ; Aghaziarati, Mahmoud ($item.subfieldsMap.e) ; Kazemian, Masoud ($item.subfieldsMap.e)
Abstract
In this research, direct synthesis of dimethyl ether (DME) from CO2 hydrogenation in three phase slurry reactor was investigated. Bifunctional catalysts composed of Cu- ZnO-Al2O3-ZrO2 as hydrogenation component and zeolite Na-Mordenite as dehydration component, with different Al2O3 and ZrO2 contents were synthesized by coprecipitating sedimentation and influences of Al2O3 and ZrO2 on CO2 conversion and DME selectivity were evaluated. Results show, both Al2O3 and ZrO2 enhanced conversion, but Al2O3 markedly increase selectivity of DME. However, when the total contents of Al2O3 and ZrO2 was increased up to 16 wt% , CO2 conversion and DME selectivity remarkably decreased. BET and XRD analyzes...
Experimental Investigations on RC Arches Strengthened Using GFRP Sheets
, M.Sc. Thesis Sharif University of Technology ; Khaloo, Alireza (Supervisor)
Abstract
A total of twenty-four reinforced concrete arches with dimensions of 110 × 30 × 10 cm were casted, fabricated and tested. There are three variables, including: height to span ratio, longitudinal reinforcement ratio and arrangement and number of FRP layers.Based on results, with increasing height to span ratio, the efficiency of FRP strengthening method decreases. It is due to the fact that FRP materials inherently behave better in tension. From another point of view, in lower arches (L group) extrados bonding technic has better effect on increasing peak load of the arches, while in higher ones (H group) intrados bonding is discerned as the best method of strengthening. This paradoxical...
Damage assessment of RC arch structures using fractal analysis of crack patterns
, Article Nondestructive Characterization and Monitoring of Advanced Materials, Aerospace, Civil Infrastructure, and Transportation XV 2021, 22 March 2021 through 26 March 2021 ; Volume 11592 , 2021 ; 0277786X (ISSN); 9781510640139 (ISBN) ; Khaloo, A ; Sharif University of Technology
SPIE
2021
Abstract
Surface crack patterns can easily show the behavior of concrete elements and structures. However, visual damage inspection performed by experts is a subjective approach and is prone to inaccuracies. The quantification makes this process objective and more reliable. In that regards, the maximum crack width is used as a practical measurement. It has been shown that the crack width is not a good indicator of damage due to its inherent uncertainties; In fact, it might bounce back after unloading. As such, a dimensionless parameter so-called Fractal Dimension has been introduced as a robust index that can quantify the complexity of crack distribution efficiently. The present study aims to...
Permeation of single gases through TEG liquid membranes modified by Na-Y nano-zeolite particles
, Article Separation and Purification Technology ; Volume 76, Issue 2 , 2010 , Pages 120-125 ; 13835866 (ISSN) ; Bastani, D ; Kazemian, H ; Sharif University of Technology
2010
Abstract
In this research, a triethylene glycol (TEG)/nano-zeolite Na-Y liquid membrane was developed in order to investigate the effect of zeolite nanoparticles on separation performance of a liquid membrane. To do this, a high yield nano-zeolite Na-Y was synthesized using mid-synthesis addition method. The synthesized samples were characterized by XRD, FT-IR, and SEM (EDX) instrumental techniques. A supported liquid membrane was prepared by impregnating a porous hydrophilic PVDF support with TEG and nano-zeolite Na-Y. The permeation tests of single gas components of O2, N2 and CO2 were carried out at pressure differences of 0.8 and 1.8 bar. The permeances of the single gases were found to be: CO2 >...
Optimization of parameters for synthesis of mfi nanoparticles by taguchi robust design
, Article Chemical Engineering and Technology ; Volume 33, Issue 6 , 2010 , Pages 902-910 ; 09307516 (ISSN) ; Soltanieh, M ; Kazemian, H ; Sharif University of Technology
2010
Abstract
MFI-type zeolite was successfully synthesized by hydrothermal crystallization of clear synthesis mixtures. A statistical experimental design method (the Taguchi method with an L8 orthogonal array) was implemented to optimize the experimental conditions for the preparation of MFI nanocrystals with respect to particle size and distribution as the desirable properties. In the Taguchi experimental design, crystallization temperature, water content, template/silica molar ratio, aluminum content, as well as the presence of alkaline cations were chosen as significant parameters affecting the properties. It was shown that water and aluminum content of the synthesis solution were the most important...
Novel utilization of zeolited fly ash hosting cobalt nanoparticles as a catalyst applied to the Fischer-Tropsch synthesis
, Article Catalysis Letters ; Volume 127, Issue 1-2 , 2009 , Pages 204-212 ; 1011372X (ISSN) ; Kazemeini, M ; Kazemian, H ; Sharif University of Technology
2009
Abstract
In order to produce an inexpensive catalyst for the Fischer-Tropsch synthesis (FTS), zeolitized high silicon fly ash utilized as a catalytic support for cobalt nanoparticles. The ability of this new support in proper hosting of nanoparticles studied through various characterization methods such as X-ray diffraction, nitrogen sorption, transmission electron microscopy, energy-dispersive spectroscopic and temperature-programmed reduction. In addition, the catalytic properties for the FTS evaluated at 523 K and 20 MPa. The obtained results show remarkable influence of utilized support specifications upon the formation and catalytic behavior of cobalt nanoparticles in the FTS
Modified LaCoO3 nano-perovskite catalysts for the environmental application of automotive CO oxidation
, Article Chemical Engineering Journal ; Volume 148, Issue 2-3 , 2009 , Pages 306-311 ; 13858947 (ISSN) ; Baghalha, M ; Kazemian, H ; Sharif University of Technology
2009
Abstract
Modified perovskite-type oxides were synthesized through co-precipitation and conventional citrate methods. The synthesized perovskite materials had the nominal compositions of LaCoO3, LaCo0.8Cu0.2O3, La0.8Sr0.2Co0.8Cu0.2O 3, and La0.8M0.2FeO3 (where M = Ce and Sr). The catalytic activity of the perovskite samples (for low-temperature CO oxidation) was measured using a quartz reactor with an inlet gas mixture containing 97% N2, 1% O2, and 2% CO. The prepared perovskite samples were characterized by SEM, nitrogen adsorption (BET), XRF, and XRD analyses. The perovskite catalysts showed good structural and chemical stability up to 600 °C and high activity for the catalytic CO oxidation...
A year-round study of a photovoltaic thermal system integrated with phase change material in Shanghai using transient model
, Article Energy Conversion and Management ; Volume 210 , 2020 ; Salari, A ; Ma, T ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
In the study, the daily and monthly performance of a photovoltaic thermal system integrated with phase change material is investigated in Shanghai, China. A three-dimensional model of photovoltaic thermal system integrated with phase change material system is developed and numerically simulated. Water is considered as working fluid, and the fluid flow regime is laminar and incompressible. Both quasi-steady and transient models are compared together, and the transient model is selected because of its higher accuracy. Validation analysis is performed on the numerical model to show the reasonable agreement of current research compared to some other research. After obtaining the suitable...
Mass-Velocity dispersion relation by using the gaia data and its effect on interpreting short-duration and degenerate microlensing events
, Article Astronomical Journal ; Volume 164, Issue 3 , 2022 ; 00046256 (ISSN) ; Rahvar, S ; Kazemian, F ; Sharif University of Technology
American Astronomical Society
2022
Abstract
Gravitational microlensing, the lensing of stars in the Milky Way with other stars, has been used for exploring compact dark matter objects, exoplanets, and black holes. The duration of microlensing events, the so-called Einstein crossing time, is a function of distance, mass, and velocities of lens objects. Lenses with different ages and masses might have various characteristic velocities inside the Galaxy and this might lead to our misinterpretation of microlensing events. In this work, we use the Gaia archived data to find a relation between the velocity dispersion and mass, and the age of stars. This mass-velocity dispersion relation confirms the known age-velocity relation for...
Numerical Solution of 2D Incompressible Flow Using Spectral Difference Method
, M.Sc. Thesis Sharif University of Technology ; Hejranfar, Kazem (Supervisor)
Abstract
In this study, an accurate numerical solution of the two-dimensional incompressible viscous flows is performed by using the spectral difference method on structured grids. The system of equations to be solved here is the preconditioned incompressible Navier-Stokes equations in the primitive variable formulation with the artificial compressibility approach. In the spectral difference method, two sets of the structured points, namely, “solution points” and “flux points” are defined in each cell for supporting the reconstruction of desirable order of accuracy. Here, the formulation of the spectral difference method is derived and the representative form of the solution and flux points for...
Applying the Taguchi method to develop an optimized synthesis procedure for nanocrystals of T-type zeolite
, Article Chemical Engineering and Technology ; Volume 32, Issue 7 , 2009 , Pages 1042-1048 ; 09307516 (ISSN) ; Bastani, D ; Kazemian, H ; Sharif University of Technology
2009
Abstract
The effects of H2O/SiO2, TMAOH/SiO2, Na/(Na+K), and SiO2/Al2O3 ratios in the parent gels on the crystallization of nanoparticles of T-type zeolites were studied. A Taguchi orthogonal experimental design with the above-mentioned parameters (each at three levels) was used to optimize the experiment parameters by the analysis of variances (ANOVA). Applying the Taguchi method significantly reduced the time and cost required for optimization. The synthesized products were characterized by X-ray diffraction and scanning electron microscopy. As a result of the Taguchi analysis, H2O/SiO2 and TMAOH/SiO2 were the most influencing parameters for the synthesis of zeolite T. © 2009 WILEY-VCH Verlag GmbH...
Synthesis & Characterization of Nano Zeolite SAPO-34 Membranes on Alumina Supports and Evaluation of Their Performance for Gas and Vapor Separation
, M.Sc. Thesis Sharif University of Technology ; Soltanieh, Mohammad (Supervisor) ; Kazemian, Hossein (Supervisor)
Abstract
A Novel synthesis method to assemble of nano crystalline SAPO-34 molecular sieves crystalline is successfully developed at a supercritical condition. The environmental and operating conditions are investigated through a Taguchi L-9 orthogonal array and optimum synthesis conditions in order to reach highest crystallinity and smallest crystalline. The products were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), thermal method of analysis (e.g. TG-DTA), and infra red spectroscopy (FT-IR) techniques. In comparison to conventional hydrothermal methods, using a supercritical hydrothermal approach leads to the higher purity, reduced particle size, and change of...
Gas Separation by TEG and Zeolite Na-Y Nano Particles Liquid Membrane
, M.Sc. Thesis Sharif University of Technology ; Bastani, Dariuosh (Supervisor) ; Kazemian, Hossein (Supervisor)
Abstract
In this research, in order to investigate the effect of zeolites nanoparticles on the separation performance of a liquid membrane, a TEG/Nano Na-Y was developed. To do this, a high yield nano zeolite Na-Y was synthesized using mid-synthesis addition method . The synthesized samples were characterized by XRD, FT-IR, and SEM (EDX) instrumental techniques. A supported liquid membrane was prepared by impregnating a porous hydrophilic PVDF support with TEG and nano zeolite Na-Y. Permeances of single gas components of CO2, N2 and O2 were carried out at different pressures of 0.8, 1.8 and 3.7 bar. The single gases permeances were found to be: CO2 > N2 > O2. The results were shown that higher weight...
Preparation of TEG Supported Liquid Membrane with Nano Particles of LTA Type Zeolite and Investigation of The Membrane Performance in Gas Separation
, M.Sc. Thesis Sharif University of Technology ; Bastani, Daryush (Supervisor) ; Kazemian, Hossein (Supervisor)
Abstract
The purpose of this research project was to improve the performance of TEG liquid membrane in separation of gas mixtures by adding zeolite LTA nanoparticles. Therefore, the NaA zeolite particles with nano size were synthesized with hydrothermal method at optimized condition. The supported liquid membrane with hydrophilic PVDF membrane and triethylene Glycol (TEG) was prepared in two different conditions. In the first one, the pores of the supporting membrane were filled with triethylene Glycol, whereas in the second one the pores were filled with the mixture of triethylene Glycol along with the 5 wt% and 10 wt% zeolite nanoparticles. The performances of prepared membranes were investigated...
Green Flexible Supply Chain Network Design; A Genetic Algorithm Approach
, M.Sc. Thesis Sharif University of Technology ; Akbari Jokar, Mohammad Reza (Supervisor)
Abstract
This study aimed to develop a green network design for a multi-echelon multi-product supply chain with a focus on bottleneck points as the means of enhancing unutilized capacities to maintain the optimal levels of flexibility. Two different models were developed to compare different approaches of flexible capacity planning by minimizing the total cost of facility establishment as well as their utilization and transportation cost. The proposed mixed-integer linear programming model was characterized by its novelty in taking bottleneck points into account to build a platform for flexible capacity planning required for responding to uncertainties such as fluctuations in demand and new product...
Some criteria for a signed graph to have full rank
, Article Discrete Mathematics ; Volume 343, Issue 8 , 2020 ; Ghafari, A ; Kazemian, K ; Nahvi, M ; Sharif University of Technology
Elsevier B.V
2020
Abstract
A weighted graph Gω consists of a simple graph G with a weight ω, which is a mapping, ω: E(G)→Z∖{0}. A signed graph is a graph whose edges are labelled with −1 or 1. In this paper, we characterize graphs which have a sign such that their signed adjacency matrix has full rank, and graphs which have a weight such that their weighted adjacency matrix does not have full rank. We show that for any arbitrary simple graph G, there is a sign σ so that Gσ has full rank if and only if G has a {1,2}-factor. We also show that for a graph G, there is a weight ω so that Gω does not have full rank if and only if G has at least two {1,2}-factors. © 2020 Elsevier B.V
Experimental investigation on the behavior of RC arches strengthened by GFRP composites
, Article Construction and Building Materials ; Volume 235 , 28 February , 2020 ; Moradi, H ; Kazemian, A ; Shekarchi, M ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
An experimental investigation on the behavior of RC arches strengthened by glass fiber-reinforced polymer (GFRP) composites is presented. Twelve samples were tested in order to determine influence of arrangement and number of GFRP layers on RC arches having different steel reinforcement ratios. The arches were tested under centrally concentrated point load using displacement control condition. Load-deflection behavior, failure mode, GFRP debonding, angle between hinge formation and supports and crack propagation pattern are studied extensively. Based on test results, extrados strengthening is much more effective than intrados strengthening in increasing ultimate load carrying capacity which...
Optimization of a novel photovoltaic thermal module in series with a solar collector using Taguchi based grey relational analysis
, Article Solar Energy ; Volume 215 , 2021 , Pages 492-507 ; 0038092X (ISSN) ; Parcheforosh, A ; Salari, A ; Ma, T ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
The solar collectors absorb solar irradiation and then produce thermal energy; however, they cannot generate electrical power. Electricity and thermal energy can be produced by the photovoltaic thermal module, simultaneously, while the outlet temperature of the photovoltaic thermal module is not usually high enough to provide thermal requirements of a building such as hot water or space heating. This work proposes a novel compound system created by the connection of a solar collector in series with a photovoltaic thermal module to resolve the issue of low outlet temperature in the photovoltaic thermal module and lack of electrical power in solar collectors. To examine the feasibility of this...
Effects of catalyst preparation conditions on nano-gold deposited on ZSM-5 for CO oxidation
, Article International Journal of Modern Physics B ; Volume 22, Issue 18-19 , 2008 , Pages 3278-3288 ; 02179792 (ISSN) ; Kazemeini, M ; Kazemian, H ; Sharif University of Technology
World Scientific Publishing Co. Pte Ltd
2008
Abstract
Calcined Na-ZSM-5 zeolite was directly reacted with the chloroauric acid solution in different concentrations and pH for gold loading process. The synthesized Au/ZSM-5 catalyst was then characterized using XRD, BET, SEM, TEM and EDS techniques. In order to evaluate its catalytic activity, effect of temperature on CO conversion was investigated. © 2008 World Scientific Publishing Company
Application of hybrid nanofluids in a novel combined photovoltaic/thermal and solar collector system
, Article Solar Energy ; Volume 239 , 2022 , Pages 102-116 ; 0038092X (ISSN) ; Salari, A ; Ma, T ; Lu, H ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
Because of the low outflow temperature of the conventional photovoltaic thermal systems and lack of electrical production of the solar thermal collectors, a novel combined system is proposed to solve the two mentioned drawbacks. This novel system is achieved by connecting a photovoltaic thermal unit to a solar thermal collector in series. To increase the overall performance of this novel combined system, different hybrid nanofluids include (1) multiwall carbon nanotube-aluminum oxide (2) multiwall carbon nanotube-silicon carbide (3) graphene-aluminum oxide, and (4) graphene-silicon carbide are compared. The investigation is performed based on the three-dimensional simulation, and the...