Sharif Digital Repository

Octahedral crystals of Fe-Metal-organic frameworks like Fe-MIL-101, which is the most stable and active metal-organic frameworks; in combination with graphitic carbon nitride nanosheets could significantly enhance the photocatalytic activity of g-C3N4 for inorganic dye degradation under the irradiation of visible light application. This appropriate cocatalyst modifies the performance of semiconductor via suppressing the recombination of photo-induced carriers and since the synthesized composite prepared by in-situ procedure possesses close contact between each other, the migration of electrons in the photocatalytic reaction will be continued, so the degradation process via the active species... 

Volatile Organic Compounds (VOCs) have become an important source of air pollution due to their extended use as solvents in many industrial processes. Aliphatic and aromatic VOC removal from contaminated air can be achieved by a variety of methods including catalytic oxidation, adsorption, and biological treatment. Catalytic oxidation is often the preferred process due to its low cost and high efficiency. Supported transition metal catalysts are effective and inexpensive catalysts for VOC removal from contaminated air. The objective of this project was to prepare low cost transition metal catalysts (Fe, Ni, Co, and Cu) supported on alumina for catalytic oxidation of cyclohexane (as a... 

Because of the importance of purification units at the refineries, in this research the process of sulfur removing compounds from light naphtha product with 1 ppm concentration by adsorption method in a fixed bed tower was simulated by COMSOL Multiphysics software. In this work, simulation was done using two macro and micro perspectives. In the Macro-scale mass transfer takes place between the spherical particles of catalyst and in the micro-scale mass transfer takes place within the spherical particles and these two scales were coupled together by reaction rate variable. In Macro-scale one-dimensional and two-dimensional geometry were considered for model. Naturally, the result of the... 

Selective oxidation of H2S to elemental sulfur in a fixed bed reactor over seven nanocatalysts has been investigated and compared to commercial claus catalyst. Among them, Al2O3-supported sodium oxide nanocatalyst prepared with wet chemical technique and Al2O3 nanocatalyst prepared with spray pyrolysis method were the most active catalysts for selective oxidation of H2S to elemental sulfur. The remaining nanocatalysts were deactivated, mainly due to the interaction with H2S and conversion into sulfides. For synthesis of Al2O3 with spray pyrolysis method we use statistical design of experiments (box-behnken design) in order to screen the effects of significant synthesizing parameters  

Superparamagnetic core/shell nonporous (S1) and core/shell/shell mesoporous (S2 and S3) nanocomposite magnetite/silica particles with a magnetite cluster core of 130±30 nm, a nonporous silica shell of 90±10 nm thickness, and a mesoporous silica shell of 70±15 nm thickness were prepared thorough a simple method. Mesoporous particles were prepared with two BJH pore sizes (2.44 for S2 and 3.76 nm for S3 particles, respectively). The fabricated S1, S2 and S3 particles present high saturation magnetization values of 20, 13 and 17 emu/g, respectively. As a biological application, the lipase from Pseudomonas cepacia was successfully immobilized onto the amino-functionalized nanocomposite particles... 

One of the most important world issues is environmental constraints regarding the pollutants released by transportation fuels and refinery products, sulfur reduction being one of the most significant objectives. Deep hydrodesulfurization processes result in great sulfur reduction in refinery streams. However, such harsh process conditions increase undesired side reactions and facilitate coke formation as well as affecting the surfaces. More effective alternatives for hard process conditions are highly active and selective hydrodesulfurization catalysts, which enable the process to be performed at milder pressure and reaction conditions. Catalyst bases play a very important role in hydrogen... 

In this research, molybdenum and tungsten catalysts modified with cobalt and nickel on a carbon support have been synthesized and investigated in the oxidation desulfurization process. A model fuel was used to evaluate the synthesized catalysts. This model fuel was n-decane. dibenzothiophene was also used as a sulfur model. The synthesized catalysts were subjected to various analyzes such as XRD, FTIR, Raman, BET-BJH, NH3-TPD, TEM and ICP-OES for structural evaluation. On the other hand, synthetic parameters such as metal loading rate, molar or weight ratio of secondary metal (cobalt and nickel) to primary metal (molybdenum and tungsten) and molar ratio of citric acid to primary metal as... 

The primary purpose of acidizing operations in the oil and gas industry is to enhance hydrocarbon production. Acidizing has been a common and conventional method for years, especially when production engineers face issues like declining reservoir pressure leading to reduced production rates. Initially, the treatment solution is referred to as matrix acidizing. In acidizing operations, different additives are combined with the acid to control its behavior in the reservoir. These additives may include iron control agents, corrosion inhibitors, friction reducers, and more. Incompatibility among these additives, the acid, and reservoir fluids can lead to severe damage to the reservoir.... 

The goal of this research is the simulation of the annular combustion chamber of the turbine engine utilized by liquid fuel. The achievement to this goal will lead to create numerical tools for parametric study, analysis and combustion chamber designing.For this reason simple geometry has been considered. This simplicity of geometry causes to facilitate in parametric study and decrease in saving time for modeling and meshing. This combustion chamber is a simplified model of engine CF6. In recent study, the k – ε realizable model has been used for turbulence modeling. For non-adiabatic condition, chemical reaction is dissolved by utilizing probability density function along with laminar... 

During the last few years, the study of urban environment structures is considered as a research field of interest in remote sensing. In satellite observations of the earth's surface, continuous imaging in terms of time and space has caused the remote sensing technique to be proposed as a useful and efficient tool for the analysis of urban areas. Obtaining quantitative spatial information from the urban environment in fields such as determining the height of buildings plays an essential role in urban planning, monitoring damage to buildings, establishing communication bases and digital cities. During the last two decades, the use of Tomosar approach in order to reconstruct the structures of... 

In this work, the dynamic competition between firms providing internet services is studied. The framework is Markov equilibrium whereby structural parameters are obtained using two-step estimations, allowing for analyzing the situation in case of subsidies for service upgrade. The results show that such subsidy has little effect on the number of firms while increasing the number of fast firms  

Estimating the price elasticity of gas demand involves complexities depending on the gas market structure and pricing mechanisms in different countries. Distinguishing between supply and demand shocks and block pricing are among the main challenges that can cause endogeneity in elasticity estimates. Iran's domestic gas network, one of the largest and most extensive household gas markets, is divided into five climatic zones based on weather conditions. The pricing steps for these five climates during the five cold months are such that a customer in a warmer climate pays higher prices. Conversely, the pricing steps for the seven warm months are the same for all climates. This policy creates a... 

The correlation between religious adherence and voter turnout is widely studied. However, whether the relation is causal is an open question. We use Household Expenditures and Income Survey (HEIS) data in Iran, which encompasses nine distinct religious expenditures. These expenditures have low correlation with each other and represent different aspects of religious adherence. We use Imamzadeh (some historical holy shrines) as Instruments to estimate the causal effect of religious expenditures on voter turnout. The results reveal that religious expenditures influence both presidential and parliamentary voter turnout, with a notably stronger impact on presidential elections