Sharif Digital Repository

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

Lab-On-A-Disk, as a subfield of microfluidic systems, recently has drawn attention to being utilized in blood biomarker diagnosis, blood typing, and immunoassays because of being high-Throughput, highly precise, and easy to use. Blood plasma separation is a most vital unit for pre-processing in these systems, since the blood plasma contains a lot of proteins and enzymes that should be separated, and precisely examined. Therefore, in this paper, for the first time, a numerical model was proposed to evaluate the plasma separation in various time scales and geometries, and an appropriate design was proposed. Furthermore, because the blood plasma volume is different between patients, and the... 

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

Ideal orientations are one of the material characteristics of the applied mode of deformation. The transfer of material texture to orientations near specific ideal orientations can improve the mechanical properties of the material. In this paper, we focus on the determination of ideal orientations of BCC crystals under the equibiaxial tension mode of deformation. To do this, an Euler space scanning method based on a crystal plasticity approach is presented. In this method some initial orientations which are evenly spaced in the Euler space are selected and their evolutions into the ideal orientations are tracked. The loading is applied incrementally until all of the lattice spin components... 

The lateral response of a single degree of freedom (SDOF) structural system containing a rigid circular cylindrical liquid tank, under harmonic and earthquake excitations is considered. The governing differential equations of motion for the combined system is derived considering the first 3 liquid sloshing modes (1,1), (0,1), and (2,1), under horizontal excitation. The system is considered nonlinear due to the convective term of liquid acceleration and the nonlinear surface boundary conditions, both caused by the inertial nonlinearity. The harmonic and seismic response of the system is investigated in the neighborhood of 1:1 and 1:2 internal resonances between the SDOF system and the first... 

A high-order accurate implicit operator scheme is used to solve steady incompressible slip flow and heat transfer in 2D microchannels. The present methodology considers the solution of the Navier-Stokes equations using the artificial compressibility method with employing the Maxwell and Smoluchowski boundary conditions to model the slip flow and temperature jump on the walls in microchannels. Since the slip and temperature jump boundary conditions contain the derivatives of the velocity and temperature profiles, using the compact method the boundary conditions can be easily and accurately implemented. The computations are performed for a 2D microchannel and a 2D backward facing step in the... 

This paper addresses design of an observer-based adaptive fuzzy controller for a class of single-input-single-output (SISO) nonlinear systems with unknown dynamics subject to input nonlinearity and unknown direction. The proposed controller is singularity free. A high-gain observer is designed to estimate the unmeasured states, and the Lipschitz condition for proving boundedness of the estimated states is relaxed. The Nussbaum function is used to handle the unknown virtual control directions and the backstepping technique has been applied for controller design. It is proved that all closed loop signals are semi-globally uniformly ultimately bounded (SGUUB) and the output tracking error... 

This paper addresses the design of an observer based adaptive neural controller for a class of strict-feedback nonlinear uncertain systems subject to input delay, saturation and unknown direction. The input delay has been handled using an integral compensator term in the controller design. A neural network observer has been developed to estimate the unmeasured states. In the observer design, the Lipschitz condition has been relaxed. To solve the problem of unknown control directions, the Nussbaum gain function has been applied in the backstepping controller design. “The explosion of complexity” occurred in the traditional backstepping technique has been avoided utilizing the dynamic surface... 

This paper addresses design of an observer-based adaptive fuzzy controller for a class of single-input–single-output (SISO) nonlinear systems with unknown dynamics subject to input nonlinearity and unknown direction. The proposed controller is singularity free. A high-gain observer is designed to estimate the unmeasured states, and the Lipschitz condition for proving boundedness of the estimated states is relaxed. The Nussbaum function is used to handle the unknown virtual control directions and the backstepping technique has been applied for controller design. It is proved that all closed loop signals are semi-globally uniformly ultimately bounded (SGUUB) and the output tracking error... 

Chondroitinase ABCI (cABCI) is a drug enzyme that can be used to treat spinal cord injuries. Due to low thermal stability of cABCI, this enzyme was immobilized on Fe3O4 nanoparticle to increase its thermal stability. The size and morphology, structure and magnetic property of the Fe3O4 nanoparticles were characterized by the analyses of SEM, XRD and VSM, respectively, and FTIR spectroscopy was employed to confirm the immobilization of cABCI on the surface of Fe3O4 nanoparticles. The results indicated that the optimum conditions for pH, temperature, cABCI-to-Fe3O4 mass ratio and incubation time in immobilization process were 6.5, 15 °C, 0.75 and 4.5 h, respectively, and about 0.037 mg cABCI...