Sharif Digital Repository

In this project the energy of rotational barrier of C-N bond in 2-cyanoethyl piperidine-1-carbodithioate has been studied by using Dynamic Nuclear Magnetic Resonance spectroscopy. Spectra were taken at various temperatures in two different solvent; acetone and chloroform. For simulation of line-shape broadening SpinWorks software was used. This with two interfaces made possible simulation with two band-shape simulator programs; DNMR and MEXICO. The rate constants obtained from simulations were used for calculation of thermodynamic activation parameters (ΔG#. ΔH#. ΔS# and Ea#). The computational calculations were done by using Gaussian03 in several level and basis sets that are in good... 

The focus of this project was on gaining the knowledge of design characteristics and manufacturing of a hydraulic servo valve. Hence, in the first stage, the model of the valve was considered. After investigating the important parameters which influence the performance of the valve, the effect of each parameter on the valve's efficiency was examined. One of the most important characteristics of the valve is the amount of lapping between the spool and sleeve. Numerical analysis was done and all the characteristic curves were elicited. Equations governing the dynamics of the plant including a servo valve, servo actuator and dynamic model of the turbine and waterway were presented. Then the... 

A mathematical model was developed to assess thermomechanical behavior of work rolls during warm rolling processes of AA2017. A combined finite element analysis-slab method was first developed to determine thermal and mechanical responses of the strip being rolled under steady-state conditions; Then, the calculated roll pressure and temperature field were utilized as the governing boundary conditions for the thermomechanical problem of the work roll. Finally, the thermomechanical stresses within the work rolls were predicted by a thermoelastic finite element approach. The results indicate that, in warm strip rolling, thermal and mechanical stresses developed in the work rolls are comparable.... 

This thesis contains four chapters. In first chapter the role of water in organic reactions as a ecofriendly solvent, computational chemistry and dynamic nuclear magnetic resonance were studied. In the second chapter synthesis of new 4-hydroxy pyrrole derivatives in water were reported. For the synthesis of these compounds arylglyoxal derivatives, 1,3-dicarbonyl compounds and ammonium acetate were used. The reaction conditions are very mild. The third chapter contains the synthesis of new (4 or 5)-Aryl-2-aryloeil-(1H)-imidazole compounds in aqueous media. We also investigated the tauto-isomerisation of isomeric imidazoles during this reaction using DNMR technique. In forth chapter a... 

Transportation systems have been impressed the humankind societies in an astonishing way. However, there are some weak points that have been accompanied with them. In order to decrease these effects, some strategies such as Transportation Demand Management (TDM) methods have been proposed in some few literatures. In this study, regarding increasing women’s role in urban trips and also some gender based differences; the effects of pricing have been applied as a management method through a Logit Model. Results show that using dummy gender based values would lead to more reliable consequences rather than some separated models with insufficient information. Moreover, it was concluded that women... 

As technology develops, the need of instruments which could be used for improving the rate and accuracy of the manufacturing increases. This makes the robots inevitable to use in most industries. Among the robots, cable-driven robots have special characteristics that increase the tendency of using them.Multi-body cable-driven robots are novel type of cable-driven robots that have advantages compared to single-body ones. Capability of use in rehabilitation applications, in which the different parts of human body have to move separately, is one of the advantages of multi-body cable-driven robots.The first aim of this thesis is to extend the tensionable workspace concept for multi-body... 

We obtain a large deviation principle describing the small time asymptotics of the solution of a stochastic evolution equation with multiplicative noise. Our assumptions are a condition on the linear drift operator that is satisfied by generators of analytic semigroups and Lipschitz continuity of the nonlinear coefficient functions. Methods originally used by Peszat.
For the small noise asymptotics problem are adapted to solve the small time asymptotics problem. The results obtained in this way improve on some results of Zhang  

Increasing need for energy, non-renewable fossil resources and environmental pollution persuaded investigators to offer hydrogen as a clean alternative fuel. One of efficient methods for producing hydrogen is the ammonia catalytic cracking reaction. The present work the most to caused on the simulation of both 1D and 2D in an assisted-membrane tapered fluidized bed reactor. In 1D simulation several tubes of membrane placed inside the reactor, but in the case of 2D simulation two membrane tubes on the reactor walls were used. In 1D and 2D simulations the compartmental and Eulerian-Eulerian approach were used, respectively. The simulation results indicate that in a constant static bed height,... 

A Loop heat pipe (LHP) is an efficient two phase heat transfer device that is widely used in cooling applications. In this research a novel LHP was designed, fabricated and its performance was investigated through various experiments. The novel LHP has a new arrangement in evaporator and reservoir configuration in comparison with conventional LHPs, which results in a different energy and fluid flow. In addition, the novel LHP has a new mechanism for active control of working temperature which was not already used. Aside from its good performance, this LHP has easier and lower cost manufacturing process compared with the conventional ones. Also the proposed temperature control method is... 

Formation damage in oil and gas wells is mainly induced by drilling operations. Filtrate and particle invasion into formation as the sources of this damage caused serious problems, e.g. reduction of production rates. Therefore numerical modeling of this phenomenon helps us to better understand the process, and as a result, control and reduce formation damage associated with this impairment. In this research, a model to estimate the invasion depth and damage of mud filtrate from water-based mud is presented. Filtrate invasion into the formation is investigated by convection-diffusion equation with regard to dispersion term. The invasion depth is obtained from mud filtrate profile in the... 

In this study, the effect of green coffee extract powder, as a green corrosion inhibitor of steel in a concrete simulation environment was investigated. In this study, the green coffee extract was obtained by the Maceration method and its performance was investigated by weight loss method, electrochemical methods including Polarization, Electrochemical Impedance Spectroscopy. Scanning Electron Microscopy images were also used to visualize the corroded areas. The results of the polarization test showed that 450 mg/lit of coffee extract powder at 25 °C has the corrosion inhibiting efficiency of about 82% and the corrosion rate of the bare sample reduced from 6 to 1.16 mpy. The dosage of 550... 

While the action in society is at stake, it seems that, I merely do something in my personal sphere, but its consequences will not remain ultimately in my personal sphere. It goes beyond of my personal realm and obviously affects other persons and their choices. This claim is one of the most central claims of Rousseau’s philosophy of right. But if it is so, or in some more technical sense, it is the case that there is some mutual dependence between individuals in social life, then my sphere of freedom would not be merely mine. Consequently, a new question would be of some central importance: What is permissible for me, meanwhile I am living in state of society? Rousseau concludes in response... 

Testing is one of the most important and time-consuming steps in the Software Development Life Cycle. Especially, in recent methodologies like agile in which change is an important feature and they take place in iterations with each iteration taking place in a limited time. Recent studies suggest approaches to automatically generate test cases for the applications. For GUI-based applications, test cases are composed of a chain of events that are activated by the user. For these applications, we can generate test cases by simulating the chain of events that get activated by the user. Semantic-based approaches use the semantic matching of the events and their related widgets, to generate test... 

This research investigates what consumers in democratized luxury markets value when purchasing luxury items. Nonetheless, these consumers have a limited budget and can not always buy luxury items, yet they are drawn back to these luxury brands. Thus, we use brand engagement in self-concept (BESC) to explain the relationship between these consumers and luxury brands within democratized luxury markets. A conceptualized model of three luxury value dimensions (experiential, symbolic, and functional) is proposed, and 488 cases were gathered through a phone survey. The data were analyzed using partial least squares structural equation modeling (PLS-SEM). The results show that the most critical...