Loading...
Search for:
khalilian--faezeh
0.082 seconds
Development of Microextraction Methods
for the Trace Determination of Organic Compounds in Biological and Environmental Media
,
Ph.D. Dissertation
Sharif University of Technology
;
Bagheri, Habib
(Supervisor)
Abstract
The approach of this thesis is to develop and simplify robust microextraction techniques and apply these developed methods to real samples and complex matrices. Firstly, a modified solvent microextraction with back extraction method (SME/BE) combined with high performance liquid chromatography and fluorescence detection (HPLC-FD) was developed for the determination of citalopram in human plasma. Extraction process was performed in a home-made total glass vial without using a teflon ring, usually employed in SME/BE. The evaluation results demonstrated that the calibration curve showed linearity in the range of 1.0–130.0 ng/mL which covers therapeutic window and even lower amounts which is...
Angle Shear Connectors Capacity
, M.Sc. Thesis Sharif University of Technology ; Maleki, Shervin (Supervisor)
Abstract
The steel-concrete composite beams are increasingly used in bridge and building construction in recent years. A shear connection between the steel and concrete should be provided to effectively transfer the shear force and to make the two materials act as a single unit. The mechanical shear connectors provide this means. They are the essential component of any composite beam system. Many studies have been performed on shear connectors and many different steel shapes have been suggested for connectors. The steel studs and channels are the most popular code accepted connectors. However, economic considerations continue to motivate the development of new products.
Present knowledge of the...
Present knowledge of the...
Estimation of data hiding capacity of digital video based on human visual model in temporal domain
, Article 2nd International Conference on Signal Processing and Communication Systems, ICSPCS 2008, Gold Coast, QLD, 15 December 2008 through 17 December 2008 ; April , 2008 ; 9781424442423 (ISBN) ; Ghaemmaghami, S ; Sharif University of Technology
2008
Abstract
A new approach to evaluation of the data hiding capacity of digital video is presented in this paper. The paper reconsiders the conventional capacity estimation algorithms, in which the video signal is taken as a sequence of still images, that result in an exaggerated upper bound of hiding capacity or a much higher value than the actual embedding capacity. The proposed method for the capacity estimation is based on the human visual model in temporal domain, which leads to a more realistic, tighter bound for video capacity. In this method, according to temporal characteristic of every frame, a visibility based coefficient is extracted that is used to determine the hiding capacity. The maximum...
A Task Assignment Method to Reduce Aging in Multi-core Processors
, M.Sc. Thesis Sharif University of Technology ; Miremadi, Ghassem (Supervisor)
Abstract
Reducing the size of transistors has dramatically increased the impacts of NBTI, HCI, and EM phenomena in comparison with decade ago. These phenomena are able to have influence on properties of different parts of a chip to make it changed gradually; including threshold voltage of a transistor and electrical conductivity of interconnections. These changes are known as the aging of a transistors that diminish the performance and reliability of a chip. A common reason that plays a significant role in all these phenomena is temperature. The temperature becomes more important when the power density increases per unit area due to decreased size of transistors, which is a trend in multi-core...
Optimum Design of Air Jet Nozzle Preventing Hot Solid Particles Deposition on the Furnace Wall Using Numerical Simulation of Gas-Particle Two-Phase Flow
, M.Sc. Thesis Sharif University of Technology ; Darbandi, Masoud (Supervisor)
Abstract
Deposition of solid particles present in the process air on the walls of furnaces is one of the challenges in industries. This phenomenon has various causes. For example, in a furnace, the temperature of particles increases as they pass in front of the furnace burners, and due to the softening of the particles, their chances of deposition increase when they collide with the walls. Over time, with the growth of deposited particle layers on the combustion chamber walls, the performance of the combustion system gradually becomes impaired. present research aims to design air jets intersecting with the process air path, with the purpose of reducing the temperature of particles prone to deposition...
Video Watermarking and Capacity Analysis: Information Theoretic Approach
,
M.Sc. Thesis
Sharif University of Technology
;
Ghaemmaghami, Shahrokh
(Supervisor)
Abstract
Data hiding in digital media has been widely investigated over the past decade because of covering different crucial applications. Amongst digital multimedia signals, video has been received a special attention and data hiding in video signals has reached a significant improvement in recent years. This thesis aims at introducing an information theoretic based analysis method for calculating the capacity of data hiding in video signals, as one of most challenging issues in this area. This analysis is expected to establish a reasonable basis for the design and analysis of data hiding algorithms. We study and investigate the data hiding problems that could be specific to video signals and its...
Immersed sol-gel based amino-functionalized SPME fiber and HPLC combined with post-column photochemically induced fluorimetry derivatization and fluorescence detection of pyrethroid insecticides from water samples
, Article Journal of Separation Science ; Volume 32, Issue 17 , 2009 , Pages 2912-2918 ; 16159306 (ISSN) ; Ghanbarnejad, H ; Khalilian, F ; Sharif University of Technology
2009
Abstract
A method based on direct immersion solid-phase microextraction (DI-SPME) coupled with high performance liquid chromatography combined with post-column photochemically induced fluorimetry derivatization and fluorescence detection (HPLC-PIF-FD) was developed to extract three pyrethroid insecticides, i.e. cyfluthrin, cypermethrin, and flumethrin from water samples. A sol-gel based coating fiber using 3-(trimethoxysilyl propyl) amine as precursor was prepared and used for the extraction of the pyrethroids from groundwater samples. A post-column photochemical reactor was designed and constructed for the derivatization of these environmentally important pollutants to increase their fluorescence...
An interior needle electropolymerized pyrrole-based coating for headspace solid-phase dynamic extraction
, Article Analytica Chimica Acta ; Volume 634, Issue 2 , 2009 , Pages 209-214 ; 00032670 (ISSN) ; Babanezhad, E ; Khalilian, F ; Sharif University of Technology
2009
Abstract
A headspace solid-phase dynamic extraction (HS-SPDE) technique was developed by the use of polypyrrole (PPy) sorbent, electropolymerized inside the surface of a needle, as a possible alternative to solid-phase microextraction (SPME). Thermal desorption was subsequently, employed to transfer the extracted analytes into the injection port of a gas chromatography-mass spectrometry (GC-MS). The PPy sorbent including polypyrrole-dodecyl sulfate (PPy-DS) was deposited on the interior surface of a stainless steel needle from the corresponding aqueous electrolyte by applying a constant deposition potential. The homogeneity and the porous surface structure of the coating were examined using the...
Using self organizing map to infer communities in weblogs' social network
, Article 2007 IADIS European Conference on Data Mining, DM 2007, part of the 1st IADIS Multi Conference on Computer Science and Information Systems, MCCSIS 2007, 3 July 2007 through 8 July 2007 ; 2020 , Pages 58-64 ; Abolhassani, H ; Khalilian, M ; Sharif University of Technology
IADIS Press
2020
Abstract
Nowadays users of the Web are encouraged to generate content on the Web by themselves. Weblogs are the most popular tools to do this. In fact Weblogs are one kind of social networks and they are one of the most important components in Web 2.0. Blogs are often situated within a Blog community of similar interest. These communities can be a useful way for readers to access space slice of millions of Weblogs. In this paper we introduce a new algorithm to infer communities based on their link structure. This algorithm uses self organizing maps to identify communities among Weblogs. The link pattern of each Weblog is the input for SOM. © 2007 IADIS
Investigation of the performance of modified organic Rankine cycles (ORCs) and modified trilateral flash cycles (TFCs) assisted by a solar pond
, Article Solar Energy ; Volume 182 , 2019 , Pages 361-381 ; 0038092X (ISSN) ; Akbari, A ; Khalilian, M ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
Solar pond is a type of solar collector that stores solar energy in the form of heat. The solar pond can be used as a low-temperature heat source for electricity generation. In this paper, to find the most suitable power cycle for power generation from the solar pond, the performance of the Organic Rankine Cycle (ORC), Trilateral Flash Cycle (TFC) and their modified forms with an open feed liquid heater and an internal heat exchanger for different working fluids was investigated. Water was considered as the heat transfer fluid which transfers the stored heat from the solar pond to the working fluid of the cycle. The results indicate that in all cases, the energy and exergy efficiency of the...
A novel sol-gel-based amino-functionalized fiber for headspace solid-phase microextraction of phenol and chlorophenols from environmental samples
, Article Analytica Chimica Acta ; Volume 616, Issue 1 , 2008 , Pages 49-55 ; 00032670 (ISSN) ; Babanezhad, E ; Khalilian, F ; Sharif University of Technology
2008
Abstract
A novel amino-functionalized polymer was synthesized using 3-(trimethoxysilyl) propyl amine (TMSPA) as precursor and hydroxy-terminated polydimethylsiloxane (OH-PDMS) by sol-gel technology and coated on fused-silica fiber. The synthesis was designed in a way to impart polar moiety into the coating network. The scanning electron microscopy (SEM) images of this new coating showed the homogeneity and the porous surface structure of the film. The efficiency of new coating was investigated for headspace solid-phase microextraction (SPME) of some environmentally important chlorophenols from aqueous samples followed by gas chromatography-mass spectrometry (GC-MS) analysis. Effect of different...
An Analysis of Oil Revenues and Monetary and Financial Policies on Iran's Long-term Economic Growth
, M.Sc. Thesis Sharif University of Technology ; Kianfar, Farhad (Supervisor)
Abstract
In many papers, GDP is used as a measure of economic growth, which is shown to possess a nonlinear structure. The study focuses on the nonlinear Granger causality between liquidity, government spending, oil revenues and economic growth by markov-switching vector autoregressive and markov- switching Granger causality approach for the period of 1369-1397 for Iran. The empirical results from MSAI(2)-VAR(4) suggest that Oil revenues and government spending have a significant impact on economic growth in both regimes. Also, markov- switching Granger causality results are quite different from the traditional Granger causality results, that suggests the nonlinear Granger causality has more...
Design and Fabrication of Brain Spinal Cord Electrodes for Rehabilitation of Rats with Spinal Cord Injuries
, M.Sc. Thesis Sharif University of Technology ; Fardmanesh, Mehdi (Supervisor) ; Shanehsazzadeh, Faezeh (Co-Supervisor)
Abstract
The use of microelectrode arrays in neural networks has offered a wonderful opportunity for evaluating numerous properties and interactions with excitable tissues such as the brain and spinal cord in the laboratory. In neural network applications, microelectrode arrays can be utilized to analyze nerve impulses or interact with neurons. They are either used to record neural data or to stimulate spinal cord nerves. Previous research has revealed that stimulating the spinal epidural region can help restore after spinal cord injuries (SCIs), which is the key to using them in the rehabilitation of living beings, including humans. According to the international campaign for the treatment of SCI...
Histogram based reflection detection
, Article 2011 7th Iranian Conference on Machine Vision and Image Processing, MVIP 2011 - Proceedings, 16 November 2011 through 17 November 2011 ; November , 2011 , Page(s): 1 - 5 ; 978-1457715334 ; 9781457715358 (ISBN) ; Ahani, S ; Khalilian, H ; Gholampour, I ; Sharif University of Technology
2011
Abstract
Reflection appears as a layer that partly covers the original image. This phenomenon may cause failure in extracting information from images of reflecting objects. This work presents an automated technique for determining of reflection area as well as its severity to define reliability of extracted information. This is done by analyzing histogram and objects found in the image. We present a strong detector based on combining the results of these two procedures. We presented new reflection detection algorithm and a new method to find a good threshold value for converting any image into a binary image. The average reflection detection accuracy of the proposed algorithm is more than 95% for...
Characterization of V2O5 Spent Catalyst & Feasibility Study of its Regeneration
, M.Sc. Thesis Sharif University of Technology ; Sadrnezhaad, Khatiboleslam (Supervisor) ; Farzami, Faezeh ($item.subfieldsMap.e)
Abstract
In this study, at first the V2O5 spent catalysts were characterized. The aim was to identifying whether these catalyst may be regenerated. Then, for feasibility study of them, three methods were applied: washing, diffusion and milling the spent catalysts for their subsequent reproduction. A variety of techniques such as XRD, XRF, AAS, TPR and TPO were applied in order to identify factors contributing in vanadium pentoxide catalysts deactivation. The results showed that approximately all of pollutants caused their performance deterioration, while they still have some active phases. Then, the polluted catalysts were washed (their yield increased from 43% to 72.2%). In the underside of the...
Determination of fentanyl in human plasma by head-space solid-phase microextraction and gas chromatography-mass spectrometry
, Article Journal of Pharmaceutical and Biomedical Analysis ; Volume 43, Issue 5 , 2007 , Pages 1763-1768 ; 07317085 (ISSN) ; Es-haghi, A ; Khalilian, F ; Rouini, M. R ; Sharif University of Technology
2007
Abstract
A head-space solid-phase microextraction (HS-SPME) method coupled to GC-MS was developed to extract fentanyl from human plasma. The protein binding was reduced by acidification and, eventually, the sample was deproteinized with trichloroacetic acid. The parameters influencing adsorption (extraction time, temperature, pH and salt addition) and desorption (desorption time and temperature) of the analyte on the fibre were investigated and validated for method development. The developed method proved to be rapid, simple, easy and inexpensive and offers high sensitivity and reproducibility. Linear range was obtained from 0.1 ng/ml to 2 μg/ml. The limit of detection was 0.03 ng/ml while an...
Experimental Study of Using Cellulosic Compounds in Tissue Engineering
, M.Sc. Thesis Sharif University of Technology ; Vossoughi, Manouchehr (Supervisor) ; Karimi, Afzal (Supervisor) ; Faghihi, Faezeh (Co-Supervisor)
Abstract
Fabrication and characterization of different surface charged cellulose electrospun scaffolds including cellulose acetate, cellulose, carboxymethyl cellulose and quaternary ammonium cationic cellulose for biomedical applications have been reported in this research. We describe preparation of cellulosic nanofibers through the electrospinning following deacetylation cellulose acetate. Moreover, surface modification of electrospun cellulose nanofibers is carried out to obtain carboxymethyl cellulose and quaternized cellulose nanofibers, respectively. At last, the structural, morphological, mechanical, swelling, wettability and the cell culture properties of the scaffolds were analyzed and...
Digital video watermarking in 3-D ridgelet domain
, Article 11th International Conference on Advanced Communication Technology, ICACT 2009, Phoenix Park, 15 February 2009 through 18 February 2009 ; Volume 3 , 2009 , Pages 1643-1646 ; 17389445 (ISSN); 9788955191387 (ISBN) ; Ghaemmaghami, S ; Omidyeganeh, M ; IEEE Communications Society, IEEE ComSoc ; Sharif University of Technology
2009
Abstract
A new method for digital video watermarking is presented in this paper. For data embedding we use 3-D ridgelet domain introduced by Helbert. The redundancy of this transform is substantial, so extraction of the hidden data is impossible in this domain. To overcome this problem, we introduce a modified ridgelet transform with little redundancy, and embed watermark in this domain. Experimental results show that this scheme is robust against collusion attack, frame cropping, frame swapping, frame dropping, noise attack and the MJPEG (Motion JPEG) compression