Sharif Digital Repository

The goal of this project was study on coordination behavior of the 14-membered macrocyclic ligand of type N2O2 aza-crown while it is attached to fullerene C60 nano-particle. For this purpose, firstly the macrocyclic ligand (Fig 3-1, L1) was synthesized and then was reacted with C60 (Fig 3-1, L2) of which the product was characterized by elemental analysis. Since the product was insoluble in any solvents, further study on its coordination chemistry was impossible. In a second procedure, the macrocyclic ligand was reacted with benzylbromide. The reaction mixture gave two macrocyclic ligands with different number of benzylic pendant groups (Fig 3-1, L3-L4). The products were separated by column... 

Agriculture accounts for 70% of global freshwater consumption. However, precise data on irrigation water use (IWU) at the regional scale is often lacking, which hampers the development of effective water management plans. This study aims to estimate irrigation water use (IWU) by integrating remote sensing soil moisture (SM) and actual evapotranspiration (ET) data into a root-zone soil water model. Since irrigation influences both SM and actual ET, increases in SM and ET following irrigation events can be leveraged to frequently retrieve IWU from remotely sensed data. In this regard, we first developed an irrigation-free soil water model simulating root-zone SM dynamics during non-growing... 

Due to the data centers rapid growth and introduction of a new basic type of massive data processing platforms which requires accelerators to speedup computation and enhance the efficiency and reduce power consumption, using accelerators is inevitable. Communication and data transfer time between software and hardware is the most of time spent on the use of accelerators. By optimizing this part of the hardware / software platform, we have achieved substantial results in this area. The aim of our study is to organize a survey of real accelerator characteristics. To figure out its defects and main drawbacks, in addition to improving the overall efficiency of system. The implementation of... 

Coverage rate is a critical criterion in all of communication networks. In this regard, there are many different methods for distribution of network particles duo to attain the most efficient region of coverage. This emerges from the limited ability of each networks particle both in range of communicate and power consumption. In this thesis an evolutionary method is introduced to how Wireless Sensor Networks (WSN) particles can be dispensed to have more reliable coverage rate. Using both static and mobile sensor packages to cover the desired area and used a cost function, coverage rate, the authors tried to maximize it to have an excellent performance of network. Then proposed algorithm is... 

In this work a new innovative microfluidic system for the selection of motile sperms was developed. The novel aspect of this work is based on the fact the motile sperms follow microchannel walls. Immotile sperms are not able to follow curved paths and therefore their movement toward the outlet gets hindered and most of them could not reach to the outlet. But motile sperms, moving alongside the microchannel walls, reach to the outlet and get separated from the immotile ones. After designing, 3 microfluidic chips having curved microchannels with curvature radius of 150, 300 and 600 micrometer and one with a straight microchannel were fabricated using photolithography and soft lithography.... 

Ray-tracing method is extensively used for wave propagation analysis of indoor and outdoor environment for narrowband systems. The main goal of this research is to extend ray-tracing method for site-specific modeling of wideband electromagnetic propagation. In this thesis, Time-domain reflection and transmission coefficients have been computed for dielectric half-space and dielectric slab with frequency dependent permittivity. First, analytical form of Fresnel reflection coefficient for vertical and parallel polarizations in time-domain have been computed for dispersive half-spaces with lossy, extended Debye, two-pole Debye and multi-pole Debye models. By using these time-domain... 

Parkinson's is a disease caused by a disorder in the central nervous system of the body. There is no definite cure for this disease, but one of the ways to prevent the progress of this disease is to use movement therapy. One of the goals of designing wearable systems consisting of inertial sensors is to make it possible to perform this movement therapy from a distance. The purpose of the present study and research is to use the approach of simple and complex activities in order to increase the accuracy in the detection of activities and also to solve the problems of the previous system, with the help of creating the ability to detect complex meaningful activities for Parkinson's patients. In... 

In the recent decades, Polymer Electrolyte Membrane Fuel Cells (PEFC) have been known as an appropriate type of fuel cells, due to being electrochemical converter and clean energy generator with high power density and having low operation temperature and launch time. Palatine is one of the major materials that are used in electro-catalysts of fuel cell. Due to shortage of palatine resources and its high price, fuel cell production is not economical. To achieve economic conditions for production of fuel cell, two major methods are proposed:
1) Reduction of the employed amount of palatine in electro-catalyst
2) Full replacement of palatine with cheap materials
In the current... 

The oxidation-reduction (redox) responsive micelle system is based on a diselenide-containing triblock copolymer, poly(ε-caprolactone)-bis(diselenide-methoxy poly(ethylene glycol)/poly(ethylene glycol)-folate) [PCL-(SeSe-mPEG/PEG-FA)2]. Resulting in the development of tumor-targeted delivery for hydrophobic anticancer drugs. The diselenide bond, as redox-sensitive linkage, was designed, so it is located at the hydrophilic/hydrophobic hinge to allow complete micelles collapse and efficient drug release, in redox environments. The amphiphilic block copolymers self-assembled into micelles at concentrations above the critical micelle concentration (CMC) in an aqueous environment. Dynamic light... 

In this thesis, we give necessary and sufficient conditions for a simplicial com- plex with small codimension to satisfy the Serre’s condition (Sr) as well as the CMt property. We also give a connection between being (Sr) and being CMt. Also, we focus on the dimension of dual modules of local cohomology of Stanley– Reisner rings to obtain a new vector which contains important information on the Serre’s condition (Sr) and the CMt property as well as the depth of Stanley–Reisner rings. We prove some results in this regard including lower bounds for the depth of Stanley–Reisner rings. Further, we give a characterization of (d − 1)-dimensional simplicial complexes with codimension two which are... 

In recent years, the reductive dehalogenation of the chlorinated hydrocarbons using nanoscale zerovalent iron (nZVI) represents a promising approach for underground remediation. Regarding commercialization of this technique, instability and unknown nature of nZVI particle are still challenging tasks that should be considered.
In the current work, Nanoscale zero-valent iron (nZVI) and palladized iron (Pd/Fe) bimetallic particles were synthesized and employed to react with chlorinated compound (PCE) in water to investigate its degradation behaviors. The results show that the reactant ratio, stabilizer amount and temperature are the main parameters with the considerable effect on PCE...