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Government interventions and the size of the informal economy. The case of Iran (1971-2007)
, Article Journal of Economic Policy Reform ; Vol. 17, issue. 1 , 2014 , pp. 71-90 ; ISSN: 17487870 ; Nili, M ; Sharif University of Technology
2014
Abstract
Literature on the informal economy can mainly be divided into two different contrasting theories. According to the dual labor market theory (DLM), which considers the informal economy as a spare sector providing jobs for formally unemployed resources, unpleasant economic situations force people to act informally. Legalists, on the other hand, blame government interventions such as minimum wages or price control policies for pushing rent-seeking firms toward the shadows. This study using an Error-correction Multi-Indicators Multi-Causes (EMIMIC) model, a systematic method consisting of structural and measurement equations, shows that these two theories are complementary rather than...
Estimating an Index of Iran’s Informal Economy in 1350-1386 With Concentration on the Impact of Government’s Intervention by EMIMIC Model (The Multiple Indicators-Multiple Causes Model and Error-Correction Model)
, M.Sc. Thesis Sharif University of Technology ; Nili, Masoud (Supervisor)
Abstract
In this research, an Index of Iran informal economy in response to the government interventions in credit, labor and product markets is stimated by EMIMIC model. To do this, first these interventions are measured using principal components analysis. In the model, the variables GDP and employment are used as indicators and taxation rates, government distortions in credit, labor and product markets, government expenditure, per capita income, unemployment and inflation as causes of the informal economy. We conclude these government interventions have affected Iran informal economy and their influence is more than indirect interventions influence such as taxation. The estimated index of Iran...
Direct production of dimethyl ether from synthesis gas utilizing a new bifunctional catalyst
, Article 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, 28 August 2010 through 1 September 2010, Prague ; 2010 ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
2010
Abstract
A series of bifunctional catalysts Cu-ZnO-ZrO 2/Al-modified H-Mordenite were prepared by co precipitating sedimentation method and were characterized. Active sites were dispersed well. The synthesis of dimethyl ether (DME) via direct CO hydrogenation was evaluated in a three-phase slurry reactor. Cu-ZnO-ZrO 2/Al-modified H-Mordenite was a suitable catalyst for the production of dimethyl ether from synthesis gas. The appropriate ratio of methanol synthesis catalyst (Cu-ZnO-ZrO 2) to methanol dehydration catalyst (Al-modified H Mordenite) was 2:1. In this condition, CO conversion and DME selectivity were ≈ 68% and 82%, respectively. This is an abstract of a paper presented at the 7th European...
Synthesis of dimethyl ether over modified H-mordenite zeolites and bifunctional catalysts composed of Cu/ZnO/ZrO2 and modified H-mordenite zeolite in slurry phase
, Article Catalysis Letters ; Volume 129, Issue 1-2 , 2009 , Pages 111-118 ; 1011372X (ISSN) ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
2009
Abstract
Synthesis of dimethyl ether (DME) via methanol dehydration were investigated over various catalysts, and via direct CO hydrogenation over hybrid catalysts composed of Al-modified H-Mordenite zeolite and Cu/ZnO/ZrO 2. H-Mordenite zeolite exhibited the highest activity in dehydration of methanol. However, its selectivity toward dimethyl ether was rather low. For this reason, the H-Mordenite was modified. Modification of zeolites was performed by wet impregnation method and considered catalysts were characterized by AAS, XRD and NH3-TPD analyses. Results of catalytic tests indicated that H-Mordenite modified with 8 wt% aluminum oxide was the best catalyst for synthesis of dimethyl ether from...
Determining an optimum catalyst for liquid-phase dehydration of methanol to dimethyl ether
, Article Applied Catalysis A: General ; Volume 349, Issue 1-2 , 2008 , Pages 6-12 ; 0926860X (ISSN) ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
2008
Abstract
The liquid-phase dehydration of methanol to dimethyl ether was investigated over various materials including synthetic zeolites, namely, ZSM-5, Y, Mordenite, Ferrierite and Beta as well as silica and alumina. The key characters investigated were the Si/Al ratio and cation exchange. The results showed that the Mordenite zeolite exchanged with H+ exhibited the highest activity in dehydration of methanol. After finding the most active catalyst, the Mordenite zeolite was modified with Cu, Zn, Ni, Al, Zr, Mg and Na via wet-impregnation method to further improve its selectivity, and characterized by AAS, XRD, NH3-TPD, NH3-FT-IR and BET surface area techniques. It was found that these materials...
Designing a new multifunctional peptide for metal chelation and Aβ inhibition
, Article Archives of Biochemistry and Biophysics ; Volume 653 , 2018 , Pages 1-9 ; 00039861 (ISSN) ; Asadbegi, M ; Khandan, V ; Amanzadi, A ; Sharif University of Technology
Academic Press Inc
2018
Abstract
According to the Amyloid hypothesis, as the foremost scientific explanation for Alzheimer Disease (AD), the neuropathology of AD is related to toxic fragments of amyloid beta (Aβ) protein. Based on this hypothesis, an attractive therapeutic approach was demonstrated to identify multifunctional peptides able to modulate Aβ pathologies as the source of AD. On this premise, a bifunctional polypeptide based on the iAβ5p lead compound, was designed to inhibit Aβ aggregation and free metal ions. Herein, the efficacy of this novel drug in Zn2+ and Cd2+ ion chelation was examined through an integrated technique comprising combined Docking, QM, and MD simulations. MD relaxation of a set of probable...
Hydrogenation of maleic anhydride to tetrahydrofuran using bifunctional catalysts
, Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 ; Kazemeini, M ; Soltanieh, M ; Khandan, N ; Sharif University of Technology
2008
Abstract
A series of bifunctional catalysts, including Cu-ZnO-ZrO 2 and H-Y zeolite catalysts, were prepared and tested for conversion of maleic anhydride (MA) to tetrahydrofuran (THF). Cu-ZnO-ZrO 2 catalyst was used as the hydrogenating component and H-Y zeolite as the dehydrating component. The appropriate ratio of Cu/ZnO in the hydrogenation catalyst was 50:45, for which the conversion of MA and selectivity of THF reached 100 and 46%, respectively, at 50 bar and 493 K. The bifunctional catalyst of Cu-ZnOZrO 2/H-Y can produce THF from MA with high activity, selectivity, and stability. This is an abstract of a paper presented at the 18th International Congress of Chemical and Process Engineering...
Synthesis of tetrahydrofuran from maleic anhydride on Cu-ZnO-ZrO2/H-Y bifunctional catalysts
, Article Catalysis Communications ; Volume 9, Issue 13 , 2008 , Pages 2195-2200 ; 15667367 (ISSN) ; Soltanieh, M ; Kazemeini, M ; Khandan, N ; Sharif University of Technology
2008
Abstract
A series of bifunctional Cu-ZnO-ZrO2/H-Y catalysts of different compositions were prepared by coprecipitating sedimentation method and were characterized by surface area and XRD analyses. The catalytic performance in synthesis of tetrahydrofuran was evaluated and optimized in a three-phase slurry batch reactor. The experimental results showed that the appropriate ratio of Cu/ZnO in the hydrogenation catalyst was 50/45, for which the conversion of maleic anhydride (MA) and selectivity of tetrahydrofuran (THF) reached 100% and 46%, respectively, at 50 bar and 493 K after 6 h of operation. Also, according to these results, it was demonstrated that the incorporation of zirconium oxide in the...
Designing of Transition Metal Oxide Spinels and their Applications in Kinetics Study of Electrochemical Degradation of Organic Pollutants
, M.Sc. Thesis Sharif University of Technology ; Rahman Setayesh, Shahrbanoo (Supervisor)
Abstract
Metronidazole is an antibiotic which widely used in medical applications, resulting in its presence both in water and wastewater. The electro-Fenton process has shown high efficiency in the non-selective degradation of organic pollutants. In this study, CuCexFe2-xO4/CuO nanocomposites were synthesized using the hydrothermal method and utilized for the degradation of metronidazole in the electro-Fenton process. The characterization of the catalysts was performed by FT-IR, FE-SEM, XRD, and ICP techniques.The XRD patterns confirmed the formation of monoclinic copper(II) oxide structure as well as the cubic crystal structure of CuCe0.05Fe1.95O4 spinel. The FE-SEM images confirmed the formation...
Synthesis and Characterization of a Copper Catalyst for Low Temperature Water –Gas Shift Reaction
, M.Sc. Thesis Sharif University of Technology ; Khorasheh, Farhad (Supervisor) ; Khandan, Nahid (Co-Advisor)
Abstract
Water Gas Shift (WGS) reaction is an old reaction in which syngas is used for producing Hydrogen. At the present time, the major application of this reaction is in fuel cells, since the necessary Hydrogen for these cells is provided by this reaction.
The present study investigate the influence of different preparation methods on properties of Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction, which is now known as the Commercial catalyst for low temperature WGS, and its influence on performance of Cu-ZnO/Al2O3 catalyst to derive an optimal Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction. Cu-ZnO/Al2O3 catalysts was synthesized by CP, DP, DP-Ultra, IWI , CP-Urea, and...
The present study investigate the influence of different preparation methods on properties of Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction, which is now known as the Commercial catalyst for low temperature WGS, and its influence on performance of Cu-ZnO/Al2O3 catalyst to derive an optimal Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction. Cu-ZnO/Al2O3 catalysts was synthesized by CP, DP, DP-Ultra, IWI , CP-Urea, and...
Studying the Kinematics Compensation Mechanism in the Gait of Individuals with Excessive Anti-version using a Subject-Specific Musculoskeletal Model
, M.Sc. Thesis Sharif University of Technology ; Farahmand, Farzam (Supervisor) ; Narimani, Roya (Supervisor)
Abstract
In cases with excessive anteversion even after adolescence, surgeons have to choose osteotomy surgery to modify this abnormality. This surgery and modifying the anatomical problem does not necessarily lead to modify the patients’ gait cycle abnormalities; the authors’ hypothesis is the probable reason may be the persistence of the implement of the patients’ kinematics compensation mechanism even after the surgery. This mechanism is used to almost correct the gait of those with excessive anteversion. First, by using gait analysis text books, a patient’s gait cycle is analyzed; this analysis is consist of 3DGA with EMG and observational gait. Then, by using OpenSim, the patient’s patterns of...
Molecular Dynamics Simulation of Aβ42 Neurotoxicity Inhibition in Order to Alzheimer’s Disease Treatment
, M.Sc. Thesis Sharif University of Technology ; Firoozabadi, Bahar (Supervisor) ; Saeedi, Mohammad Saeed (Supervisor)
Abstract
Alzheimer’s disease (AD) is the most common type of dementia in the elderly. The neuropathology and treatment of AD is not precisely determined yet, but according to the pathological studies, AD is associated with presence of toxic soluble oligomers and insoluble senile plaques formed by amyloidosis of Amyloid Beta (Aβ) in neocortical region of brain. An attractive therapeutic approach to treat AD is to identify small ligands that are capable of binding to critical residues in order to inhibit or reverse Aβ amyloidosis process as source of neurotoxicity. In this area, therapeutic efforts designed various organic agents and most of them focused on the N-terminal sequence of Aβ. The aim of...
High Saline Water Treatment by the Process of Membrane Distillation Combined with Solar Energy
, M.Sc. Thesis Sharif University of Technology ; Rajabi, Abbas (Supervisor) ; Musavi, Abbas (Supervisor)
Abstract
In this study, membrane distillation process was used for treatment of high salinity waters. The focus of this study is to simulate and build a setup of membrane distillation process. Since the membrane distillation process is based on the driving force of the temperature difference, the required temperature is provided by both the use of heaters and the use of solar energy. To increase the feed temperature by solar energy, a black polymer coating on the main membrane is used. The main membrane used in this process is PVDF polymer and the polymer coated on the surface is the PAN polymer. After simulating and constructing the laboratory setup, the influence of a variety of parameters on the...
Compositional Modeling of Surfactant Adsorption in Chemical Flooding with Verification with Laboratory Data
, M.Sc. Thesis Sharif University of Technology ; Jamshidi, Saeed (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor)
Abstract
One of the most important EOR methods in oil reservoirs is surfactant and polymer flooding. Surfactants cause decreasing in interfacial tension between oleic and aqueous phases. However, polymers give us efficient mobility control in displacing oil by increasing the viscosity of aqueous phase. Therefore, oil is displaced in aqueous phase by viscous forces.
One of the most important challenges in surfactant flooding is adsorption. The net surface charge distributed on the rock surface depends strongly on pH. When we inject surfactant in reservoir, electrostatic charge on rock surface causes the first-layer adsorption. After that we have had second-layer adsorption.
In this thesis we...
One of the most important challenges in surfactant flooding is adsorption. The net surface charge distributed on the rock surface depends strongly on pH. When we inject surfactant in reservoir, electrostatic charge on rock surface causes the first-layer adsorption. After that we have had second-layer adsorption.
In this thesis we...
Kinetics Study and Determining an Optimum Reactor Condition for Dimethyl-ether Synthesis by Dehydration of Methanol over Nano-Crystalline γ-Al2O3
,
M.Sc. Thesis
Sharif University of Technology
;
Kazemeini , Mohammad
(Supervisor)
;
Khorashe, Farhad
(Supervisor)
;
Khandan, Nahid
(Supervisor)
Abstract
Dimethyl Ether (DME) is a pure and economic fuel which can be used as a suitable alternative for diesel fuels. Two processes are traditionally used for DME synthesis: producing methanol from synthesis gas and then dehydrating it to DME (direct process), and converting methanol into DME in a catalytic dehydration reactor over a solid-acid catalyst (indirect process), in which the indirect process seems to have economical advantage. In this research, the γ-Al2O3 catalyst was synthesized through precipitation process and then characterized by powder X-ray diffraction (XRD) and porosimetry analysis. Afterwards this catalyst was utilized in methanol dehydration reaction in a slurry reactor. Next,...
, M.Sc. Thesis Sharif University of Technology ; Akbarzadeh, Abbas (Supervisor)
Abstract
FGM sheets with component or grain size gradient in their thickness direction provide mechanical and physical gradient properties through ND direction. FGMs are fabricated by various methods including centrifugal casting, powder metallurgy, PVD and CVD,all of which suffer from some shortcomings such as porosity of the products, low rate and high cost of production and restrictions on mass production. In this study, 2 and 4 layered Al matrix FGM sheets containing SiC and Al2O3 powders were fabricated by laminating method of Accumulative Roll Bonding(ARB). Two approaches of stacking were chosen as accumulative coupled roll bonding (ACRB) and (ASRB) for initial roll bonding and subsequent...
Deposition of Ceramic Nanoparticles on Aluminum Sheet by Air Gun Spraying for ARB Processing of Nanocomposite Sheets
, M.Sc. Thesis Sharif University of Technology ; Akbarzadeh, Abbas (Supervisor)
Abstract
Particle reinforced aluminum matrix composites have considerable attraction in automotive and aerospace industries due to their special properties as light weight, high ratio of strength/density, improved elastic modulus, low coefficient of thermal expansion and high wear and corrosion resistance. Among the production processes of metal matrix composites, accumulative roll bonding process has particular importance due to producing ultrafine grained composite sheets. However, uncontrolled and undesired agglomeration of particles is the main problem in producing these composites. In this research, the Al2O3 and SiC nanoparticles were electrostatically stabilized against agglomeration by...
Make Policy for Optimizing Iran Gas Export
, M.Sc. Thesis Sharif University of Technology ; Maleki, Abbas (Supervisor)
Abstract
This project examines four alternatives such as pipelines, oil injection wells, LNG & GTL in the purpose of Iran gas utilization. In this Project four strategies using cost/benefit analysis are examined. For this purpose, at first the cost of inlet feed gas per Mmbtu are calculated. Then regarding various scenarios of average world gas prices for the following thirty years, the cost & benefit of any way will be counted. Then with the use of energy security, the project will make energy policy. For this purpose, Shannon indicator will be used as one of the most reliable indicators. Due to the of use this indicator, the popular project will be chosen accordingly as a certain amount of gas the...
Diffusion of Lipid and Protein Molecules in Cell Membranes
, Ph.D. Dissertation Sharif University of Technology ; Jalali, Abbas (Supervisor)
Abstract
Lipid membranes are fundamental constituents of cell membranes and are now used in lap-on-a-chip technology. Membranes in living cells contain a significant fraction of proteins, which undergo lateral random movements due to thermal fluctuations and shear forces imposed by the solvent fluid. Prominent natural and biotechnological systems where membranes are highly sheared include the plasma membrane of endothelial cells, and membranes used in biosensors for high throughput screening of drug candidates, and in water purification devices. In these systems membrane is in direct contact with the mainstream suspension flow, which is driven by pressure gradients. The efficiency and function of...
Hot Workability of a Free-cutting Steel with Severe Sulfur Segregation During Continuous Casting
, M.Sc. Thesis Sharif University of Technology ; Akbarzadeh, Abbas (Supervisor)
Abstract
Splitting in ingot cast structures and transverse cracks in continuous cast structures are the main problems of hot rolling of low carbon resulfurized free-cutting (LCRF) steels. Presence of high volume fraction of manganese sulfide inclusions in cast structure increases the risk of alligatoring in hot rolling. Because of high sulfur content of these steels and probability of formation of low melting point phases, minimum level of manganese and maximum level of copper and tin is necessary. Morphology of manganese sulfide is another important factor in hot forming of these steels, which can be controlled by level of deoxidation in steel making. In fact, MnS2 is present in fully killed...