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khandan-dezfoli--fatemeh
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Designing of Transition Metal Oxide Spinels and their Applications in Kinetics Study of Electrochemical Degradation of Organic Pollutants
, M.Sc. Thesis Sharif University of Technology ; Rahman Setayesh, Shahrbanoo (Supervisor)
Abstract
Metronidazole is an antibiotic which widely used in medical applications, resulting in its presence both in water and wastewater. The electro-Fenton process has shown high efficiency in the non-selective degradation of organic pollutants. In this study, CuCexFe2-xO4/CuO nanocomposites were synthesized using the hydrothermal method and utilized for the degradation of metronidazole in the electro-Fenton process. The characterization of the catalysts was performed by FT-IR, FE-SEM, XRD, and ICP techniques.The XRD patterns confirmed the formation of monoclinic copper(II) oxide structure as well as the cubic crystal structure of CuCe0.05Fe1.95O4 spinel. The FE-SEM images confirmed the formation...
Government interventions and the size of the informal economy. The case of Iran (1971-2007)
, Article Journal of Economic Policy Reform ; Vol. 17, issue. 1 , 2014 , pp. 71-90 ; ISSN: 17487870 ; Nili, M ; Sharif University of Technology
2014
Abstract
Literature on the informal economy can mainly be divided into two different contrasting theories. According to the dual labor market theory (DLM), which considers the informal economy as a spare sector providing jobs for formally unemployed resources, unpleasant economic situations force people to act informally. Legalists, on the other hand, blame government interventions such as minimum wages or price control policies for pushing rent-seeking firms toward the shadows. This study using an Error-correction Multi-Indicators Multi-Causes (EMIMIC) model, a systematic method consisting of structural and measurement equations, shows that these two theories are complementary rather than...
Estimating an Index of Iran’s Informal Economy in 1350-1386 With Concentration on the Impact of Government’s Intervention by EMIMIC Model (The Multiple Indicators-Multiple Causes Model and Error-Correction Model)
, M.Sc. Thesis Sharif University of Technology ; Nili, Masoud (Supervisor)
Abstract
In this research, an Index of Iran informal economy in response to the government interventions in credit, labor and product markets is stimated by EMIMIC model. To do this, first these interventions are measured using principal components analysis. In the model, the variables GDP and employment are used as indicators and taxation rates, government distortions in credit, labor and product markets, government expenditure, per capita income, unemployment and inflation as causes of the informal economy. We conclude these government interventions have affected Iran informal economy and their influence is more than indirect interventions influence such as taxation. The estimated index of Iran...
ChemInform abstract: microwave-assisted rapid ketalization/acetalization of aromatic aldehydes and ketones in aqueous media [electronic resource]
, Article Journal of Chemical Research ; September 1999, Volume -, Number 9; Page(s) 562 to 563 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent
Synthesis and characterization of poly(methacrylates) containing spiroacetal and norbornene moieties in side chain [electronic resource]
, Article Journal of Applied Polymer Science ; Volume 77, Issue 1, pages 30–38, 5 July 2000 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing...
Direct production of dimethyl ether from synthesis gas utilizing a new bifunctional catalyst
, Article 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, 28 August 2010 through 1 September 2010, Prague ; 2010 ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
2010
Abstract
A series of bifunctional catalysts Cu-ZnO-ZrO 2/Al-modified H-Mordenite were prepared by co precipitating sedimentation method and were characterized. Active sites were dispersed well. The synthesis of dimethyl ether (DME) via direct CO hydrogenation was evaluated in a three-phase slurry reactor. Cu-ZnO-ZrO 2/Al-modified H-Mordenite was a suitable catalyst for the production of dimethyl ether from synthesis gas. The appropriate ratio of methanol synthesis catalyst (Cu-ZnO-ZrO 2) to methanol dehydration catalyst (Al-modified H Mordenite) was 2:1. In this condition, CO conversion and DME selectivity were ≈ 68% and 82%, respectively. This is an abstract of a paper presented at the 7th European...
Synthesis of dimethyl ether over modified H-mordenite zeolites and bifunctional catalysts composed of Cu/ZnO/ZrO2 and modified H-mordenite zeolite in slurry phase
, Article Catalysis Letters ; Volume 129, Issue 1-2 , 2009 , Pages 111-118 ; 1011372X (ISSN) ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
2009
Abstract
Synthesis of dimethyl ether (DME) via methanol dehydration were investigated over various catalysts, and via direct CO hydrogenation over hybrid catalysts composed of Al-modified H-Mordenite zeolite and Cu/ZnO/ZrO 2. H-Mordenite zeolite exhibited the highest activity in dehydration of methanol. However, its selectivity toward dimethyl ether was rather low. For this reason, the H-Mordenite was modified. Modification of zeolites was performed by wet impregnation method and considered catalysts were characterized by AAS, XRD and NH3-TPD analyses. Results of catalytic tests indicated that H-Mordenite modified with 8 wt% aluminum oxide was the best catalyst for synthesis of dimethyl ether from...
Determining an optimum catalyst for liquid-phase dehydration of methanol to dimethyl ether
, Article Applied Catalysis A: General ; Volume 349, Issue 1-2 , 2008 , Pages 6-12 ; 0926860X (ISSN) ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
2008
Abstract
The liquid-phase dehydration of methanol to dimethyl ether was investigated over various materials including synthetic zeolites, namely, ZSM-5, Y, Mordenite, Ferrierite and Beta as well as silica and alumina. The key characters investigated were the Si/Al ratio and cation exchange. The results showed that the Mordenite zeolite exchanged with H+ exhibited the highest activity in dehydration of methanol. After finding the most active catalyst, the Mordenite zeolite was modified with Cu, Zn, Ni, Al, Zr, Mg and Na via wet-impregnation method to further improve its selectivity, and characterized by AAS, XRD, NH3-TPD, NH3-FT-IR and BET surface area techniques. It was found that these materials...
Prediction of DNA/RNA Sequence Binding Site to Protein with the Ability to Implement on GPU
, M.Sc. Thesis Sharif University of Technology ; Koohi, Sommaye (Supervisor)
Abstract
Based on the importance of DNA/RNA binding proteins in different cellular processes, finding binding sites of them play crucial role in many applications, like designing drug/vaccine, designing protein, and cancer control. Many studies target this issue and try to improve the prediction accuracy with three strategies: complex neural-network structures, various types of inputs, and ML methods to extract input features. But due to the growing volume of sequences, these methods face serious processing challenges. So, this paper presents KDeep, based on CNN-LSTM and the primary form of DNA/RNA sequences as input. As the key feature improving the prediction accuracy, we propose a new encoding...
Designing a new multifunctional peptide for metal chelation and Aβ inhibition
, Article Archives of Biochemistry and Biophysics ; Volume 653 , 2018 , Pages 1-9 ; 00039861 (ISSN) ; Asadbegi, M ; Khandan, V ; Amanzadi, A ; Sharif University of Technology
Academic Press Inc
2018
Abstract
According to the Amyloid hypothesis, as the foremost scientific explanation for Alzheimer Disease (AD), the neuropathology of AD is related to toxic fragments of amyloid beta (Aβ) protein. Based on this hypothesis, an attractive therapeutic approach was demonstrated to identify multifunctional peptides able to modulate Aβ pathologies as the source of AD. On this premise, a bifunctional polypeptide based on the iAβ5p lead compound, was designed to inhibit Aβ aggregation and free metal ions. Herein, the efficacy of this novel drug in Zn2+ and Cd2+ ion chelation was examined through an integrated technique comprising combined Docking, QM, and MD simulations. MD relaxation of a set of probable...
Hydrogenation of maleic anhydride to tetrahydrofuran using bifunctional catalysts
, Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 ; Kazemeini, M ; Soltanieh, M ; Khandan, N ; Sharif University of Technology
2008
Abstract
A series of bifunctional catalysts, including Cu-ZnO-ZrO 2 and H-Y zeolite catalysts, were prepared and tested for conversion of maleic anhydride (MA) to tetrahydrofuran (THF). Cu-ZnO-ZrO 2 catalyst was used as the hydrogenating component and H-Y zeolite as the dehydrating component. The appropriate ratio of Cu/ZnO in the hydrogenation catalyst was 50:45, for which the conversion of MA and selectivity of THF reached 100 and 46%, respectively, at 50 bar and 493 K. The bifunctional catalyst of Cu-ZnOZrO 2/H-Y can produce THF from MA with high activity, selectivity, and stability. This is an abstract of a paper presented at the 18th International Congress of Chemical and Process Engineering...
Synthesis of tetrahydrofuran from maleic anhydride on Cu-ZnO-ZrO2/H-Y bifunctional catalysts
, Article Catalysis Communications ; Volume 9, Issue 13 , 2008 , Pages 2195-2200 ; 15667367 (ISSN) ; Soltanieh, M ; Kazemeini, M ; Khandan, N ; Sharif University of Technology
2008
Abstract
A series of bifunctional Cu-ZnO-ZrO2/H-Y catalysts of different compositions were prepared by coprecipitating sedimentation method and were characterized by surface area and XRD analyses. The catalytic performance in synthesis of tetrahydrofuran was evaluated and optimized in a three-phase slurry batch reactor. The experimental results showed that the appropriate ratio of Cu/ZnO in the hydrogenation catalyst was 50/45, for which the conversion of maleic anhydride (MA) and selectivity of tetrahydrofuran (THF) reached 100% and 46%, respectively, at 50 bar and 493 K after 6 h of operation. Also, according to these results, it was demonstrated that the incorporation of zirconium oxide in the...
Cross-Lingual Speaker Adaptation for Statistical Parametric Speech Synthesis
, M.Sc. Thesis Sharif University of Technology ; Sameti, Hossein (Supervisor)
Abstract
Speech synthesis and its applications have been very attractive recently. The main purpose of this technique is to produce a speech signal with natural characteristics of human speech like prosody and emotion. Among all existing methods for speech synthesis, statistical parametric speech synthesis methods are more promising because ofhigher flexibility in comparison to other methods. One of the applications of speech synthesis is speech to speech translation. In these systems, the generated voice in target language should have the same characteristics as the input voice in source language. The main purpose of this research is to review and evaluate the cross lingual speaker adaptation...
Hydroelastic Analysis of Surface Piercing Propeller
, M.Sc. Thesis Sharif University of Technology ; Seif, Mohamad Saeed (Supervisor)
Abstract
Surface piercing propellers are particular type of supercavitating propellers that are commonly used for High-speed vessels. Most studies on this type of propellers has been investigating the hydrodynamic forces. But in recent years with increase in SPPs diameter used in vessels, structural analysis of this type of propellers is considered. For this purpose, studies on the stresses exerted on the propeller structures under load is done with the help of Hydro elastic methods. In this type of analysis, structura of propeller is intended to be flexible and Displacements under pressure checked and Tensions resulting from it are studied.
The present Thesis using ANSYS software to analyze a...
The present Thesis using ANSYS software to analyze a...
Data-Driven Pricing Based on Demand Prediction Using Machine Learning Methods
, M.Sc. Thesis Sharif University of Technology ; Sedghi, Nafiseh (Supervisor)
Abstract
Pricing plays an important and essential role in the profit and income of companies. The importance of pricing is not only related to its role in the company's profitability, but it also changes the customer's understanding and loyalty towards the company and can create the company's reputation or destroy it. Determining the right price will increase product sales and increase customer loyalty and create a competitive advantage for the company. One of the most important and influential variables in product pricing is the amount of demand. The main challenge of companies for product pricing is the uncertainty in their demand. In order to deal with this problem, data-driven pricing is used....
Design of Low-Power Zero Temperature Coefficient (ZTC) CMOS Oscillators
, M.Sc. Thesis Sharif University of Technology ; Akbar, Fatemeh (Supervisor)
Abstract
The increasing demand for autonomous vehicles and reliable communication protocols and hardware interfaces, such as CAN bus and USB, underscores the necessity for stable clock sources that maintain a low temperature coefficient (TC) over wide temperature ranges. This demand is particularly emphasized in applications such as wearables, network sensors, downhole devices, WSNs, and IoT, where long-lasting battery life and frequency-stable clock sources over a broad temperature range (e.g. -20 °C to 100 °C) are crucial. Traditionally, variations in frequency caused by temperature have been mitigated by employing off-chip components like crystals or ceramic based oscillators, but this approach...
Design of Low Power Harmonic Rejection Mixer for Wideband Application
, M.Sc. Thesis Sharif University of Technology ; Akbar, Fatemeh (Supervisor)
Abstract
The increasing demand for communication bandwidth and limited spectrum availability have heightened the complexity of radio front-end circuits in IoT applications. Achieving spectral efficiency is a key challenge, particularly for IoT devices operating at specific frequency bands such as 315 MHz, 433 MHz, 868 MHz, and 915 MHz.Due to the limited linearity of the transmit path, harmonic distortion components, known as counter intermodulation (CIM) products, are generated. These CIM products can directly fall into the receiver (RX) band or enter it via cross-modulation, thereby degrading the frequency division performance. Additionally, CIM products can interfere with protected bands, violating...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
The Impact of AV and CAV Vehicles on Capacity and Traffic Flow with Cooperative Lane changing in Mixed Traffic Environment
, M.Sc. Thesis Sharif University of Technology ; Nassiri, Habibollah (Supervisor)
Abstract
Autonomous vehicles, as an integral part of intelligent transportation systems, will play a significant role in the future of transportation services. These vehicles have a high potential to improve road traffic capacity and the efficiency of transportation systems. One type of autonomous vehicle is the connected and autonomous vehicle (CAV), which can communicate with each other, roadside units, traffic control signals, and other infrastructures or devices. This study investigates the impact of autonomous vehicles and connected and autonomous vehicles on the traffic flow of the Tehran-Karaj freeway and vice versa, under various penetration rates and in a mixed traffic environment. In this...
The Impact of Integrated Prediction and Optimization on the the Bullwhip Effect in supply chains
, M.Sc. Thesis Sharif University of Technology ; Sedghi, Nafiseh (Supervisor)
Abstract
The Bullwhip effect is a phenomenon that refers to the amplification of demand variance as one moves upstream in a supply chain. This effect imposes additional costs on the supply chain and complicates inventory planning. Several factors contribute to the emergence of this phenomenon, one of which is demand forecasting. Since the demand faced by each level of the supply chain is uncertain, every level must first forecast demand in order to plan its inventory and meet customer requirements. However, this very process of forecasting contributes to the bullwhip effect. In this study, we investigate the impact of machine learning and deep learning forecasting methods, along with their...