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PTSA catalyzed synthesis of functionalized dipyrazolo[1,5]diazocine-3,8-diones via the reaction of 3-aminopyrazolone with benzaldehyde derivatives
, Article Tetrahedron Letters ; Volume 59, Issue 51 , 2018 , Pages 4503-4508 ; 00404039 (ISSN) ; Matloubi Moghaddam, F ; Kiamehr, M ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
A simple procedure for the synthesis of dipyrazolo[1,5]diazocine-3,8-diones was developed via the one-pot reaction of 3-aminopyrazolone with substituted benzaldehydes in the presence of catalytic p-toluenesulfonic acid (PTSA). © 2018 Elsevier Ltd
Microstructure and texture development during friction stir processing of Al–Mg alloy sheets with TiO2 nanoparticles [electronic resource]
, Article Materials Science and Engineering: A ; 27 May 2014, Volume 605, Pages 108–118 ; Simchi, A. (Abdolreza) ; Kokabi, A. H ; Nosko, M ; Simancik, F ; Svec, P ; Sharif University of Technology
Abstract
Aluminum matrix nanocomposites were fabricated by friction stir processing of Al–Mg alloy sheets with pre-placed TiO2 nanoparticles at a concentration of 2 to 6 vol%. Microstructural studies showed that solid state reactions between the metal matrix and TiO2 particles caused in situ formation of MgO and Al3Ti nanophases with an average size ~50 nm. These nanophases were homogenously distributed in an ultra-fine grain structure (0.2–2 µm) of the base metal. The results of pole figures evaluation obtained by electron back scattered diffraction studies revealed that the random orientation of initial annealed sheet was changed to components near to shear and silver texture in the friction stir...
Friction stir welding of a P/M Al–Al2O3 nanocomposite: Microstructure and mechanical properties
, Article Materials Science and Engineering: A (Elsevier) ; 2014, 585, 222-232 ; Sharif University Of Technology
Abstract
Solid-state joining of powder-metallurgy processed (P/M) Al–2 vol% Al2O3 (15 nm) nanocomposite by friction stir welding (FSW) was studied. The nanocomposite was prepared via high-energy mechanical milling followed by hot consolidation processes. The microstructure, mechanical properties and fracture behavior of the welds were evaluated and compared with FSWed wrought 1050 aluminum sheets (WAS). We have found that unlike WAS that can processed at various FSW conditions, the working window for the solid-state joining of P/M nanocomposite is narrow and only feasible at relatively high heating inputs. Microstructural studies showed the formation of melted zones with high hardness at the...
Strain rate sensitivity, work hardening, and fracture behavior of an Al-Mg TiO2 nanocomposite prepared by friction stir processing [electronic resource]
, Article Journal of Metallurgical and Materials Transactions A ; August 2014, Volume 45, Issue 9, P.4073-4088 ; Simchi, A. (Abdolreza) ; Kokabi, Amirhossein ; Nosko, Martin ; Svec, Peter ; Sharif University of Technology
Abstract
Annealed and wrought AA5052 aluminum alloy was subjected to friction stir processing (FSP) without and with 3 vol pct TiO2 nanoparticles. Microstructural studies by electron backscattered diffraction and transmission electron microscopy showed the formation of an ultra-fine-grained structure with fine distribution of TiO2 nanoparticles in the metal matrix. Nanometric Al3Ti and MgO particles were also observed, revealing in-situ solid-state reactions between Al and Mg with TiO2. Tensile testing at different strain rates determined that FSP decreased the strain rate sensitivity and work hardening of annealed Al-Mg alloy without and with TiO2 nanoparticles, while opposite results were obtained...
PTSA-catalyzed cyclization of 6-aminouracils with diimines: Efficient synthesis of functionalized tetrahydropyrimido[4,5-d]pyrimidine-2,4-diones
, Article ChemistrySelect ; Volume 3, Issue 41 , 2018 , Pages 11671-11676 ; 23656549 (ISSN) ; Kiamehr, M ; Matloubi Moghaddam, F ; Villinger, A ; Langer, P ; Sharif University of Technology
Wiley-Blackwell
2018
Abstract
A new and efficient method has been developed for the synthesis of 5,7-diaryl-5,6,7,8-tetrahydropyrimido[4,5-d]pyrimidine-2,4-dione derivatives by cyclization of 6-aminouracils with N,N′-bis(arylmethylidene)arylmethanes (diimines). The products were formed in good yields and with very good anti-diastereoselectivity. The best yields were obtained when p-toluenesulfonic acid (PTSA) was used as the catalyst. The solvent also played an important role in the optimization. An amino-substituted 6-aminouracil and a corresponding sulfur analog could be successfully employed. In addition, various diimines, electron rich and neutral, could be successfully employed. The products are of relevance as...
Effects of post-annealing on the microstructure and mechanical properties of friction stir processed Al–Mg–TiO2 nanocomposites [electronic resource]
, Article Journal of Materials & Design ; November 2014, Volume 63, Pages 30–41 ; Simchi, A. (Abdolreza) ; Kokabi, A. H ; Gerlich, A. P ; Nosko, M ; Sharif University of Technology
Abstract
Aluminum matrix nanocomposites were fabricated via friction stir processing of an Al–Mg alloy with pre-inserted TiO2 nanoparticles at different volume fractions of 3%, 5% and 6%. The nanocomposites were annealed at 300–500 °C for 1–5 h in air to study the effect of annealing on the microstructural changes and mechanical properties. Microstructural studies by scanning and transmission electron microscopy showed that new phases were formed during friction stir processing due to chemical reactions at the interface of TiO2 with the aluminum matrix alloy. Reactive annealing completed the solid-state reactions, which led to a significant improvement in the ductility of the nanocomposites (more...
Reactive friction stir processing of AA 5052-TiO2 nanocomposite: process-microstructure-mechanical characteristics [electronic resource]
, Article Journal of Materials Science and Technology ; 2014, Vol.0, Issue 0 ; Simchi, A. (Abdolreza) ; Kokabi, A. H ; Sadeghahmadi, M ; Gerlich, A. P ; Sharif University of Technology
Abstract
Friction stir processing (FSP) is a solid state route with a capacity of preparing fine grained nanocomposites from metal sheets. In this work, we employed this process to finely distribute TiO2 nanoparticles throughout an Al–Mg alloy, aiming to enhance mechanical properties. Titanium dioxide particles (30 nm) were preplaced into grooves machined in the middle of the aluminium alloy sheet and multipass FSP was afforded. This process refined the grain structure of the aluminium alloy, distributed the hard nanoparticles in the matrix and promoted solid state chemical reactions at the interfaces of the metal/ceramic particles. Detailed optical and electron microscopic studies showed that the...
Spark plasma sintering of a multilayer thermal barrier coating on Inconel 738 superalloy: Microstructural development and hot corrosion behavior
, Article Ceramics International ; Volume 42, Issue 2 , 2016 , Pages 2770-2779 ; 02728842 (ISSN) ; Javadi, A. H ; Bahrami, M ; Khodabakhshi, F ; Simchi, A ; Sharif University of Technology
Elsevier Ltd
2016
Abstract
In the present work, spark plasma sintering (SPS) process was employed to prepare a nanostructured yttria-stabilized zirconia (8YSZ) coating on a nickel-based superalloy (INCONEL 738) with functionally graded structure. A stack layer of INCONEL 738/NiCrAlY powder/Al foil/NiCrAlY+YSZ powder/YSZ powder was SPSed in a graphite die at an applied pressure of 40 MPa under an vacuum atmosphere (8 Pa). The sintering temperature was ∼1040 °C. For comparison purpose, the air plasma spray (APS) technique was employed to prepare the thermal barrier coating (TBC). Microstructural studies by scanning electron microscopy showed that the SPSed coating was sound and free of interfacial cracks and large...
A Privacy-Preserving Network Communication Protocol
, M.Sc. Thesis Sharif University of Technology ; Jalili, Rasool (Supervisor)
Abstract
One important aspect of privacy, is confidentiality. A common solution to preserve the confidentiality in network communications is ”Virtual Pri- vate Network”. VPNs todays are expected to be more secure and support higher throughput for their new applications, such as Inter-Cloud VPN and Virtual Private Cloud. block cipher is an important security com- ponent employed in most VPNs.On the other hand, most block ciphers have mathematical weaknesses in their structures, so the ttacker can use these weaknesses to break them faster than brute-force attacks. This thesis proposes a new method named ”Chaos-based Selective Key (CSK) Cryptosystem”, for increasing the security of block ciphers in a much...
Differential scanning calorimetry study of constrained groove pressed low carbon steel: Recovery, recrystallisation and ferrite to austenite phase transformation
, Article Materials Science and Technology (United Kingdom) ; Vol. 30, issue. 7 , 2014 , pp. 765-773 ; ISSN: 02670836 ; Kazeminezhad, M ; Sharif University of Technology
2014
Abstract
Low carbon steel sheets are subjected to severe plastic deformation (SPD) via constrained groove pressing (CGP) up to five passes. As a result of this process, strain magnitude up to 5?8 is imposed to the sheets, which leads to grain size of 225 nm. These nanostructured steel sheets, due to their high dislocation density and ultrafine microstructure, are very sensitive to heating. In the present study, recovery, recrystallisation and ferrite to austenite phase transformation phenomena for the SPD steel are investigated using differential scanning calorimetry method. The results show that with increasing the strain in steel sheets, the deformed stored energy (released through recovery and...
The annealing phenomena and thermal stability of severely deformed steel sheet
, Article Materials Science and Engineering A ; Volume 528, Issue 15 , June , 2011 , Pages 5212-5218 ; 09215093 (ISSN) ; Kazeminezhad, M ; Sharif University of Technology
2011
Abstract
However, there are many works on annealing process of SPDed non-ferrous metals, there are limit works on annealing process of SPDed low carbon steel. Therefore, in this study the annealing responses after constrained groove pressing (CGP) of low carbon steel sheets have been investigated. The sheets are subjected to severe plastic deformation at room temperature by CGP method up to three passes. Nano-structured low carbon steel sheets produced by severe plastic deformation are annealed at temperature range of 100-600 °C for 20. min. The changes of their microstructures after deformation and annealing are studied by optical microscopy. The effects of large strain and annealing temperature on...
Optimization of the Multi-Stage Compressor Design by Developing a Software for 2D Axial-Flow Compressor Analysis
, M.Sc. Thesis Sharif University of Technology ; Mazaheri, Karim (Supervisor)
Abstract
Streamline Curvature method is one of the most commonly used methods by industry for prediction of axial flow compressors. This method analyze axial compressor by solving radial equations in the meridional plane to locate streamlines and also by using empirical models to predict total pressure loss. Despite growth of CFD models, Streamline Curvature method has been considered as most practical method for compressor preliminary design and performance assessment because of it’s high speed and good precision. In the current work a C++ code (SLC) has been developed using streamline curvature for axial flow compressor performance analysis. This code receives compressor geometry, properties of...
The effect of constrained groove pressing on grain size, dislocation density and electrical resistivity of low carbon steel
, Article Materials and Design ; Volume 32, Issue 6 , 2011 , Pages 3280-3286 ; 02641275 (ISSN) ; Kazeminezhad, M ; Sharif University of Technology
2011
Abstract
In this research, constrained groove pressing (CGP) technique is used for imposing severe plastic deformation (SPD) on the low carbon steel sheets. Using transmission electron microscopy (TEM), X-ray diffraction (XRD) and optical microscopy, the microstructural characteristics of produced sheets are investigated. The results show that CGP process can effectively refine the coarse-grained structure to an ultrafine grain range. Dislocation densities of the ultrafine grained low carbon steel sheets are quantitatively calculated and it is found that the CGP can effectively enhance the dislocation density of the sheets. Measurements of their electrical resistivity values show that microstructure...
Investigation of the Influence of Geometry and External Field on Fluid Flow Through Carbon Nanotubes by Molecular Dynamics Simulation
, M.Sc. Thesis Sharif University of Technology ; Moosavi, Ali (Supervisor)
Abstract
Water transportation through carbon nanotubes is key for designing nanodevices. The directed transport of water molecules through a rotating charged carbon nanotube (CNT) is investigated by molecular dynamics simulations. It is found that the net flux of continuous unidirectional water flow depended sensitively on the charge distribution, charge density and rotation of the CNT. we find that for a constant charge density, the water flux increases with the increase of the charge difference. Besides, we find that the water flux shows a nonlinear dependence on the angular velocity of the rotation. The rotation of the CNT with low angular velocities, can not generate a continuous water flux. The...
Unidirectional transport of water through an asymmetrically charged rotating carbon nanotube
, Article Journal of Physical Chemistry C ; Volume 121, Issue 42 , 2017 , Pages 23649-23658 ; 19327447 (ISSN) ; Moosavi, A ; Sharif University of Technology
2017
Abstract
Achieving a high speed, unidirectional water flow through carbon nanotubes (CNTs) is a key factor in designing novel nanofluidic devices. In this study, utilizing molecular dynamics (MD) simulations, we propose a novel nanoscale water pump for directed water transportation using charged rotating CNTs. Two basic conditions for stable water flow, including thermodynamic nonequilibrium and spatial asymmetry, are provided by introducing partial charges on carbon atoms of the channel with asymmetric patterns and its rotation, respectively. We demonstrate that the performance of the water pump is proportional to the gradient of a linear charge distribution and angular velocity of the rotation. Our...
The role of microstructural features on the electrical resistivity and mechanical properties of powder metallurgy Al-SiC-Al2O3 nanocomposites
, Article Materials and Design ; Volume 130 , 2017 , Pages 26-36 ; 02641275 (ISSN) ; Simchi, A ; Sharif University of Technology
2017
Abstract
There are many engineering applications in which composite materials are required to satisfy two or more criteria regarding physical and mechanical properties. In this article, Al-matrix nanocomposites reinforced with different volume fractions of SiC nanoparticles (~ 50 nm; up to 6%) were processed by powder metallurgy (P/M) routes through mechanical milling and hot consolidation techniques. Microstructural studies showed that nano-metric Al2O3 particles with a size of ~ 20 nm and volume fraction of ~ 2% were formed and distributed in the metal matrix, owing to the surface oxides breaking. Microstructural analysis also revealed that the size of cellular structure and the density of...
Seismic Performance Improvement of Reinforced Concrete Moment Resisting Frame Systems With Some Selected Prestressed Columns and Comparison with Self-Centering Systems
, M.Sc. Thesis Sharif University of Technology ; Khaloo, Alireza (Supervisor)
Abstract
In seismic regions, the construction of structures with appropriate seismic performance and re-centering capability that can reduce residual displacement and damage, are necessary. As an alternative, prestressed columns were developed in recent years which can limit the permanent deformation and structural damage effectively. After severe damage and residual displacement of bridge piers and building’s columns, extensive research was carried out on prestressed columns. Most researches have been conducted on the prestressing of bridge piers and precast columns in self-centering system but prestressed columns in common moment resisting frame and comparing their advantages and disadvantages with...
Effects of support conditions and arrangement of prestressed rocking columns on the displacement of concrete frames under dynamic loads
, Article Bulletin of Earthquake Engineering ; Volume 20, Issue 8 , 2022 , Pages 4175-4212 ; 1570761X (ISSN) ; Khaloo, A ; Sharif University of Technology
Springer Science and Business Media B.V
2022
Abstract
In this paper, the effects of rocking and fixed base prestressed columns and conventional reinforced concrete columns on the response of frames are investigated. Also, the influence of some selected rocking base prestressed columns on the response of the concrete frame was studied. Three types of a concrete frame with conventional Reinforced Concrete columns, rocking, and fixed base prestressed columns were modeled using the finite element method in Opensees software. The details of the simulation of the rocking and fixed base columns in Opensees are described precisely. The results obtained from the models were compared with those of the literature to evaluate the validity of the results....
Effects of nanometric inclusions on the microstructural characteristics and strengthening of a friction-stir processed aluminum-magnesium alloy
, Article Materials Science and Engineering A ; Volume 642 , August , 2015 , Pages 215-229 ; 09215093 (ISSN) ; Simchi, A ; Kokabi, A. H ; Švec, P ; Simančík, F ; Gerlich, A. P ; Sharif University of Technology
Elsevier Ltd
2015
Abstract
An aluminum-magnesium alloy was friction-stir processed in the presence of TiO2 nanoparticles which were pre-placed in a groove on the surface to produce a composite. Field emission-scanning and transmission electron microscopy studies show that solid state chemical reactions occur between the Al-Mg matrix and the ceramic particles upon the severe plastic deformation process. The microstructure of the aluminum alloy consists of a coarse grain structure, large complex (Fe,Mn,Cr)3 SiAl12 particles, and small Mg2 Si precipitates. After friction stir processing, a deformed grain structure containing rod-like Al-Fe-Mn-Si precipitates is attained, along...
Effects of non-isothermal annealing on microstructure and mechanical properties of severely deformed aluminum samples: Modeling and experiment
, Article Transactions of Nonferrous Metals Society of China (English Edition) ; Volume 29, Issue 6 , 2019 , Pages 1127-1137 ; 10036326 (ISSN) ; Kazeminezhad, M ; Sharif University of Technology
Nonferrous Metals Society of China
2019
Abstract
In order to investigate the evolution of microstructure and flow stress during non-isothermal annealing, aluminum samples were subjected to strain magnitudes of 1, 2 and 3 by performing 2, 4 and 6 passes of multi-directional forging. Then, the samples were non-isothermally annealed up to 150, 200, 250, 300 and 350 °C. The evolution of dislocation density and flow stress was studied via modeling of deformation and annealing stages. It was found that 2, 4 and 6 passes multi-directionally forged samples show thermal stability up to temperatures of 250, 250 and 300 °C, respectively. Modeling results and experimental data were compared and a reasonable agreement was observed. It was noticed that...